Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces
Acid activation increases the protonated species on a kaolinite surface at the expense of coordinately bound NH 3 entities. The presence of NH + 4 ions on an activated sample is not proof of the presence of protonic acid centres alone since the added proton may have come from the residual water in t...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
SAGE Publishing
2001-10-01
|
| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263617011494484 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832544680459370496 |
|---|---|
| author | Tabak Ahmet Afsin Beytullah |
| author_facet | Tabak Ahmet Afsin Beytullah |
| author_sort | Tabak Ahmet |
| collection | DOAJ |
| description | Acid activation increases the protonated species on a kaolinite surface at the expense of coordinately bound NH 3 entities. The presence of NH + 4 ions on an activated sample is not proof of the presence of protonic acid centres alone since the added proton may have come from the residual water in the interlayer. Progressive dehydration of the surface results in a strong increase in chemisorbed NH 3 . However, the ‘ring frequency’ region of coordinately bound pyridine (Py) and of the pyridiniumion (Py + ) indicates that the strong acid sites on activated kaolinite are of the Lewis type. |
| format | Article |
| id | doaj-art-4d1ddec7085243ddb9cb2d1b1d546fd8 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2001-10-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-4d1ddec7085243ddb9cb2d1b1d546fd82025-02-03T10:07:34ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382001-10-011910.1260/0263617011494484Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite SurfacesTabak AhmetAfsin BeytullahAcid activation increases the protonated species on a kaolinite surface at the expense of coordinately bound NH 3 entities. The presence of NH + 4 ions on an activated sample is not proof of the presence of protonic acid centres alone since the added proton may have come from the residual water in the interlayer. Progressive dehydration of the surface results in a strong increase in chemisorbed NH 3 . However, the ‘ring frequency’ region of coordinately bound pyridine (Py) and of the pyridiniumion (Py + ) indicates that the strong acid sites on activated kaolinite are of the Lewis type.https://doi.org/10.1260/0263617011494484 |
| spellingShingle | Tabak Ahmet Afsin Beytullah Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces Adsorption Science & Technology |
| title | Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces |
| title_full | Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces |
| title_fullStr | Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces |
| title_full_unstemmed | Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces |
| title_short | Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces |
| title_sort | firmly adsorbed ammonia and pyridine species at activated kaolinite surfaces |
| url | https://doi.org/10.1260/0263617011494484 |
| work_keys_str_mv | AT tabakahmet firmlyadsorbedammoniaandpyridinespeciesatactivatedkaolinitesurfaces AT afsinbeytullah firmlyadsorbedammoniaandpyridinespeciesatactivatedkaolinitesurfaces |