Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) Extraction
We aimed to synthesize novel substituted polymers bearing functional groups to chelate heavy metals during depollution applications. Three polyamine functionalized Merrifield resins were prepared via ethylenediamine (EDA), diethylenetriamine (DETA), and triethylenetetramine (TETA) modifications name...
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| Format: | Article |
| Language: | English |
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Wiley
2015-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2015/782841 |
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| author | Mokhtar Dardouri Fayçel Ammari Faouzi Meganem |
| author_facet | Mokhtar Dardouri Fayçel Ammari Faouzi Meganem |
| author_sort | Mokhtar Dardouri |
| collection | DOAJ |
| description | We aimed to synthesize novel substituted polymers bearing functional groups to chelate heavy metals during depollution applications. Three polyamine functionalized Merrifield resins were prepared via ethylenediamine (EDA), diethylenetriamine (DETA), and triethylenetetramine (TETA) modifications named, respectively, MR-EDA, MR-DETA, and MR-TETA. The aminoalkylated polymers were subsequently reticulated by tris-(2-chloroethyl) phosphate (TCEP) to obtain new polymeric resins called, respectively, MR-EDA-TCEP, MR-DETA-TCEP, and MR-TETA-TCEP. The obtained resins were characterized via attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), elemental analysis (EA), and thermogravimetric (TGA), thermodynamic (DTA), and differential thermogravimetric (DTG) analysis. The synthesized resins were then assayed to evaluate their efficiency to extract metallic ions such as Cd2+, Cu2+, and Fe2+ from aqueous solutions. |
| format | Article |
| id | doaj-art-4b61fa5dce9b464295146ce0401df787 |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2015-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-4b61fa5dce9b464295146ce0401df7872025-02-03T07:26:10ZengWileyInternational Journal of Polymer Science1687-94221687-94302015-01-01201510.1155/2015/782841782841Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) ExtractionMokhtar Dardouri0Fayçel Ammari1Faouzi Meganem2Laboratory of Organic Synthesis, Faculty of Sciences of Bizerte, University of Carthage, Zarzouna, 7021 Bizerte, TunisiaLaboratory of Organic Synthesis, Faculty of Sciences of Bizerte, University of Carthage, Zarzouna, 7021 Bizerte, TunisiaLaboratory of Organic Synthesis, Faculty of Sciences of Bizerte, University of Carthage, Zarzouna, 7021 Bizerte, TunisiaWe aimed to synthesize novel substituted polymers bearing functional groups to chelate heavy metals during depollution applications. Three polyamine functionalized Merrifield resins were prepared via ethylenediamine (EDA), diethylenetriamine (DETA), and triethylenetetramine (TETA) modifications named, respectively, MR-EDA, MR-DETA, and MR-TETA. The aminoalkylated polymers were subsequently reticulated by tris-(2-chloroethyl) phosphate (TCEP) to obtain new polymeric resins called, respectively, MR-EDA-TCEP, MR-DETA-TCEP, and MR-TETA-TCEP. The obtained resins were characterized via attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), elemental analysis (EA), and thermogravimetric (TGA), thermodynamic (DTA), and differential thermogravimetric (DTG) analysis. The synthesized resins were then assayed to evaluate their efficiency to extract metallic ions such as Cd2+, Cu2+, and Fe2+ from aqueous solutions.http://dx.doi.org/10.1155/2015/782841 |
| spellingShingle | Mokhtar Dardouri Fayçel Ammari Faouzi Meganem Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) Extraction International Journal of Polymer Science |
| title | Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) Extraction |
| title_full | Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) Extraction |
| title_fullStr | Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) Extraction |
| title_full_unstemmed | Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) Extraction |
| title_short | Aminoalkylated Merrifield Resins Reticulated by Tris-(2-chloroethyl) Phosphate for Cadmium, Copper, and Iron (II) Extraction |
| title_sort | aminoalkylated merrifield resins reticulated by tris 2 chloroethyl phosphate for cadmium copper and iron ii extraction |
| url | http://dx.doi.org/10.1155/2015/782841 |
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