Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) Ions
Synthesis and characterization of 2-(hydroxyimino)-1-(phenyl propylidene) thiocarbonohydrazide (called ‘HPTCHOPD’) was studied. The synthesized compound having the molecular formula C10H13N5OS, where in isonitrosopropiophenone is reacted with thiocarbonohydrazide in presence of sodium acetate in eth...
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| Format: | Article |
| Language: | English |
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Wiley
2009-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2009/591353 |
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| author | A. Venkatchallam R. G. Deshmukh Dilip C. Sawant |
| author_facet | A. Venkatchallam R. G. Deshmukh Dilip C. Sawant |
| author_sort | A. Venkatchallam |
| collection | DOAJ |
| description | Synthesis and characterization of 2-(hydroxyimino)-1-(phenyl propylidene) thiocarbonohydrazide (called ‘HPTCHOPD’) was studied. The synthesized compound having the molecular formula C10H13N5OS, where in isonitrosopropiophenone is reacted with thiocarbonohydrazide in presence of sodium acetate in ethanol-water mixture. The yield which is comprises effecting the reaction in the presence of sodium acetate. Also the present work report a process for producing metal complexes having the formula ML2 and (ML)2 Cl, wherein M is the divalent metal cation, like cobalt (Co+2), nickel (Ni+2) and copper (Cu+2). The compound HPTCHOPD is admixed with a basic divalent compound that is halide, mainly chloride of Co+2, Ni+2 and Cu+2 in presence of methanol-water mixture. The metal complexes so produced are characterized on the basis of spectral, elemental and magnetic analysis; reveal interesting geometries and bonding features. The data suggested square planar geometry for Co+2 complex, a distorted tetrahedral/square planar-octahedral geometry for Ni+2 complex and a bridged structure for Cu+2 complex. |
| format | Article |
| id | doaj-art-4a3e6df0524d41839bc3a3704624f0f8 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-4a3e6df0524d41839bc3a3704624f0f82025-02-03T06:44:30ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-0164993100210.1155/2009/591353Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) IonsA. Venkatchallam0R. G. Deshmukh1Dilip C. Sawant2Deptartment of P.G. Studies & Research in Chemistry, Bhavan’s College, Andheri (w), Mumbai-58, IndiaDeptartment of P.G. Studies & Research in Chemistry, Bhavan’s College, Andheri (w), Mumbai-58, IndiaDeptartment of P.G. Studies & Research in Chemistry, Bhavan’s College, Andheri (w), Mumbai-58, IndiaSynthesis and characterization of 2-(hydroxyimino)-1-(phenyl propylidene) thiocarbonohydrazide (called ‘HPTCHOPD’) was studied. The synthesized compound having the molecular formula C10H13N5OS, where in isonitrosopropiophenone is reacted with thiocarbonohydrazide in presence of sodium acetate in ethanol-water mixture. The yield which is comprises effecting the reaction in the presence of sodium acetate. Also the present work report a process for producing metal complexes having the formula ML2 and (ML)2 Cl, wherein M is the divalent metal cation, like cobalt (Co+2), nickel (Ni+2) and copper (Cu+2). The compound HPTCHOPD is admixed with a basic divalent compound that is halide, mainly chloride of Co+2, Ni+2 and Cu+2 in presence of methanol-water mixture. The metal complexes so produced are characterized on the basis of spectral, elemental and magnetic analysis; reveal interesting geometries and bonding features. The data suggested square planar geometry for Co+2 complex, a distorted tetrahedral/square planar-octahedral geometry for Ni+2 complex and a bridged structure for Cu+2 complex.http://dx.doi.org/10.1155/2009/591353 |
| spellingShingle | A. Venkatchallam R. G. Deshmukh Dilip C. Sawant Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) Ions E-Journal of Chemistry |
| title | Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) Ions |
| title_full | Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) Ions |
| title_fullStr | Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) Ions |
| title_full_unstemmed | Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) Ions |
| title_short | Synthesis and Characterization of 2-(Hydroxyimino)-1-(phenylpropylidene)thiocarbonohydrazide and its Metal Complexes with Co(II), Ni(II) and Cu(II) Ions |
| title_sort | synthesis and characterization of 2 hydroxyimino 1 phenylpropylidene thiocarbonohydrazide and its metal complexes with co ii ni ii and cu ii ions |
| url | http://dx.doi.org/10.1155/2009/591353 |
| work_keys_str_mv | AT avenkatchallam synthesisandcharacterizationof2hydroxyimino1phenylpropylidenethiocarbonohydrazideanditsmetalcomplexeswithcoiiniiiandcuiiions AT rgdeshmukh synthesisandcharacterizationof2hydroxyimino1phenylpropylidenethiocarbonohydrazideanditsmetalcomplexeswithcoiiniiiandcuiiions AT dilipcsawant synthesisandcharacterizationof2hydroxyimino1phenylpropylidenethiocarbonohydrazideanditsmetalcomplexeswithcoiiniiiandcuiiions |