Site-specific substitution in atomically precise carboranethiol-protected nanoclusters and concomitant changes in electronic properties

Site-specific substitution in atomically precise carboranethiol-protected nanoclusters and concomitant changes in electronic properties

Abstract We report the synthesis of [Ag17(o 1-CBT)12]3- abbreviated as Ag17, a stable 8e⁻ anionic cluster with a unique Ag@Ag12@Ag4 core-shell structure, where o 1-CBT is ortho-carborane-1-thiol. By substituting Ag atoms with Au and/or Cu at specific sites we created isostructural clusters [AuAg16(o...

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Main Authors: Vivek Yadav, Arijit Jana, Swetashree Acharya, Sami Malola, Harshita Nagar, Ankit Sharma, Amoghavarsha Ramachandra Kini, Sudhadevi Antharjanam, Jan Machacek, Kumaran Nair Valsala Devi Adarsh, Tomas Base, Hannu Häkkinen, Thalappil Pradeep
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-56385-w
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