Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang Clay

The rapid development of the global alumina industry has led to a considerable increase in the production alumina and processing of alumina from non-bauxitic sources. Lampang clays comprise various minerals that contain about 22.70 wt% of extractable alumina. Local clay was ground, activated by calc...

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Main Authors: Paweena Numluk, Aphiruk Chaisena
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/758296
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author Paweena Numluk
Aphiruk Chaisena
author_facet Paweena Numluk
Aphiruk Chaisena
author_sort Paweena Numluk
collection DOAJ
description The rapid development of the global alumina industry has led to a considerable increase in the production alumina and processing of alumina from non-bauxitic sources. Lampang clays comprise various minerals that contain about 22.70 wt% of extractable alumina. Local clay was ground, activated by calcination and treated with sulfuric acid to extract alumina. In the activation step, the effects of temperature and time on the extraction of alumina and iron were investigated. The leaching experiments were performed on clay samples with particle sizes less than 200 mesh. The samples were calcined at different temperatures, ranging from 450°C to 1050°C, and for different periods, ranging from 30 to 150 min. The optimum conditions for the extraction of alumina from Lampang clay include grinding the clay to pass through a 200 mesh sieve, calcining the ground clay at 750°C for 30 min, extracting the alumina from the calcined clay by leaching with 3M sulfuric acid, and using an acid to clay ratio of 80 wt% at 100°C for 120 min. An aluminum dissolution efficiency of 95.1 % was achieved under the conditions that resulted in the maximum dissolution efficiency of iron (26.6 %).
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spelling doaj-art-4898b1d581364dd3ad237eee7cde3eec2025-02-03T00:59:48ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01931364137210.1155/2012/758296Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang ClayPaweena Numluk0Aphiruk Chaisena1Department of Applied Chemistry and Center for Innovation in Chemistry, Faculty of Science, Lampang Rajabhat University, Lampang, 52100, ThailandDepartment of Applied Chemistry and Center for Innovation in Chemistry, Faculty of Science, Lampang Rajabhat University, Lampang, 52100, ThailandThe rapid development of the global alumina industry has led to a considerable increase in the production alumina and processing of alumina from non-bauxitic sources. Lampang clays comprise various minerals that contain about 22.70 wt% of extractable alumina. Local clay was ground, activated by calcination and treated with sulfuric acid to extract alumina. In the activation step, the effects of temperature and time on the extraction of alumina and iron were investigated. The leaching experiments were performed on clay samples with particle sizes less than 200 mesh. The samples were calcined at different temperatures, ranging from 450°C to 1050°C, and for different periods, ranging from 30 to 150 min. The optimum conditions for the extraction of alumina from Lampang clay include grinding the clay to pass through a 200 mesh sieve, calcining the ground clay at 750°C for 30 min, extracting the alumina from the calcined clay by leaching with 3M sulfuric acid, and using an acid to clay ratio of 80 wt% at 100°C for 120 min. An aluminum dissolution efficiency of 95.1 % was achieved under the conditions that resulted in the maximum dissolution efficiency of iron (26.6 %).http://dx.doi.org/10.1155/2012/758296
spellingShingle Paweena Numluk
Aphiruk Chaisena
Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang Clay
E-Journal of Chemistry
title Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang Clay
title_full Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang Clay
title_fullStr Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang Clay
title_full_unstemmed Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang Clay
title_short Sulfuric Acid and Ammonium Sulfate Leaching of Alumina from Lampang Clay
title_sort sulfuric acid and ammonium sulfate leaching of alumina from lampang clay
url http://dx.doi.org/10.1155/2012/758296
work_keys_str_mv AT paweenanumluk sulfuricacidandammoniumsulfateleachingofaluminafromlampangclay
AT aphirukchaisena sulfuricacidandammoniumsulfateleachingofaluminafromlampangclay