Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis Cell

The cell voltage in alkaline water electrolysis cells remains high despite the fact that water electrolysis is a cleaner and simpler method of hydrogen production. A multiphysical model for the cell voltage of a single cell electrolyzer was realized based on a combination of current-voltage models,...

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Main Authors: Ivan Newen Aquigeh, Merlin Zacharie Ayissi, Dieudonné Bitondo
Format: Article
Language:English
Published: Wiley 2021-01-01
Series:Journal of Combustion
Online Access:http://dx.doi.org/10.1155/2021/6673494
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author Ivan Newen Aquigeh
Merlin Zacharie Ayissi
Dieudonné Bitondo
author_facet Ivan Newen Aquigeh
Merlin Zacharie Ayissi
Dieudonné Bitondo
author_sort Ivan Newen Aquigeh
collection DOAJ
description The cell voltage in alkaline water electrolysis cells remains high despite the fact that water electrolysis is a cleaner and simpler method of hydrogen production. A multiphysical model for the cell voltage of a single cell electrolyzer was realized based on a combination of current-voltage models, simulation of electrolyzers in intermittent operation (SIMELINT), existing experimental data, and data from the experiment conducted in the course of this work. The equipment used NaOH as supporting electrolyte and stainless steel as electrodes. Different electrolyte concentrations, interelectrode gaps, and electrolyte types were applied and the cell voltages recorded. Concentrations of 60 wt% NaOH produced lowest range of cell voltage (1.15–2.67 V); an interelectrode gap of 0.5 cm also presented the lowest cell voltage (1.14–2.71 V). The distilled water from air conditioning led to a minimum cell voltage (1.18–2.78 V). The water from a factory presented the highest flow rate (12.48 × 10−1cm3/min). It was found that the cell voltage of the alkaline electrolyzer was reduced considerably by reducing the interelectrode gap to 0.5 cm and using electrolytes that produce less bubbles. A maximum error of 1.5% was found between the mathematical model and experimental model, indicating that the model is reliable.
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id doaj-art-4733e07a8a2d4088b2462a29e21b9bf8
institution Kabale University
issn 2090-1968
2090-1976
language English
publishDate 2021-01-01
publisher Wiley
record_format Article
series Journal of Combustion
spelling doaj-art-4733e07a8a2d4088b2462a29e21b9bf82025-02-03T01:00:16ZengWileyJournal of Combustion2090-19682090-19762021-01-01202110.1155/2021/66734946673494Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis CellIvan Newen Aquigeh0Merlin Zacharie Ayissi1Dieudonné Bitondo2Ecole National Supérieure Polytechnique de Douala Laboratory, Energy, Materials, Modelling and Methods (E3M) University of Douala, Douala, CameroonEcole National Supérieure Polytechnique de Douala Laboratory, Energy, Materials, Modelling and Methods (E3M) University of Douala, Douala, CameroonEcole National Supérieure Polytechnique de Douala Laboratory, Energy, Materials, Modelling and Methods (E3M) University of Douala, Douala, CameroonThe cell voltage in alkaline water electrolysis cells remains high despite the fact that water electrolysis is a cleaner and simpler method of hydrogen production. A multiphysical model for the cell voltage of a single cell electrolyzer was realized based on a combination of current-voltage models, simulation of electrolyzers in intermittent operation (SIMELINT), existing experimental data, and data from the experiment conducted in the course of this work. The equipment used NaOH as supporting electrolyte and stainless steel as electrodes. Different electrolyte concentrations, interelectrode gaps, and electrolyte types were applied and the cell voltages recorded. Concentrations of 60 wt% NaOH produced lowest range of cell voltage (1.15–2.67 V); an interelectrode gap of 0.5 cm also presented the lowest cell voltage (1.14–2.71 V). The distilled water from air conditioning led to a minimum cell voltage (1.18–2.78 V). The water from a factory presented the highest flow rate (12.48 × 10−1cm3/min). It was found that the cell voltage of the alkaline electrolyzer was reduced considerably by reducing the interelectrode gap to 0.5 cm and using electrolytes that produce less bubbles. A maximum error of 1.5% was found between the mathematical model and experimental model, indicating that the model is reliable.http://dx.doi.org/10.1155/2021/6673494
spellingShingle Ivan Newen Aquigeh
Merlin Zacharie Ayissi
Dieudonné Bitondo
Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis Cell
Journal of Combustion
title Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis Cell
title_full Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis Cell
title_fullStr Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis Cell
title_full_unstemmed Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis Cell
title_short Multiphysical Models for Hydrogen Production Using NaOH and Stainless Steel Electrodes in Alkaline Electrolysis Cell
title_sort multiphysical models for hydrogen production using naoh and stainless steel electrodes in alkaline electrolysis cell
url http://dx.doi.org/10.1155/2021/6673494
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AT merlinzacharieayissi multiphysicalmodelsforhydrogenproductionusingnaohandstainlesssteelelectrodesinalkalineelectrolysiscell
AT dieudonnebitondo multiphysicalmodelsforhydrogenproductionusingnaohandstainlesssteelelectrodesinalkalineelectrolysiscell