Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value Addition

Washing of iron ore fines and slime (10% and 25% w/v, slurry concentrations) with two types of surface-active agents (sodium humate (synthesized) and AD 200 (commercial)) at varying concentrations at pH 8 was conducted for ascertaining the efficacy of dispersants in beneficiating the low-grade iron...

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Main Authors: Jyotirmoy Sarma, Sanchayita Rajkhowa, Sekh Mahiuddin
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2022/6451187
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author Jyotirmoy Sarma
Sanchayita Rajkhowa
Sekh Mahiuddin
author_facet Jyotirmoy Sarma
Sanchayita Rajkhowa
Sekh Mahiuddin
author_sort Jyotirmoy Sarma
collection DOAJ
description Washing of iron ore fines and slime (10% and 25% w/v, slurry concentrations) with two types of surface-active agents (sodium humate (synthesized) and AD 200 (commercial)) at varying concentrations at pH 8 was conducted for ascertaining the efficacy of dispersants in beneficiating the low-grade iron ores. The beneficiation process follows the “selective dispersion-cum-settling technique.” The process results in the formation of a dispersed phase rich in gangue minerals and a settled phase of predominantly active hematite mineral. The stability of dispersed phase (DP) was evaluated by determination of the percentage solid content in the DP. Settling tests were performed. First-order kinetic models have been applied to the dispersion-cum-settling behaviour of both the samples, and evaluated kinetic parameters were found to have good agreement with experimental data. Removal of gangue minerals from iron ore depends on the pH of the slurry, concentration of the slurry, and concentration of the surface-active agent used. The surface-active agents at pH 8 produce ∼1.2–1.5 times more stable suspension in the case of iron ore fines and slimes than that of without surface-active agent. They significantly remove gangue minerals and increase the iron value ∼2–7% with ∼58–74% recovery depending on the experimental conditions. The concentrates collected satisfy the required specifications (Al203/Fe < 0.05 and Al203/Si02 < 1). The gangues in the dispersed phase as characterised by “SEM-EDXA” are mostly clay-bearing minerals like kaolinite, goethite, chlorite, and alumina-silicate minerals. Heat treatment causes distortion of clay minerals present in the dispersed phase and also indicates the complex nature of the gangue minerals.
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spelling doaj-art-462c466e7d73468a9734fc6db56f07a82025-02-03T01:32:37ZengWileyJournal of Chemistry2090-90712022-01-01202210.1155/2022/6451187Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value AdditionJyotirmoy Sarma0Sanchayita Rajkhowa1Sekh Mahiuddin2Department of ChemistryDepartment of ChemistryMaterials Science DivisionWashing of iron ore fines and slime (10% and 25% w/v, slurry concentrations) with two types of surface-active agents (sodium humate (synthesized) and AD 200 (commercial)) at varying concentrations at pH 8 was conducted for ascertaining the efficacy of dispersants in beneficiating the low-grade iron ores. The beneficiation process follows the “selective dispersion-cum-settling technique.” The process results in the formation of a dispersed phase rich in gangue minerals and a settled phase of predominantly active hematite mineral. The stability of dispersed phase (DP) was evaluated by determination of the percentage solid content in the DP. Settling tests were performed. First-order kinetic models have been applied to the dispersion-cum-settling behaviour of both the samples, and evaluated kinetic parameters were found to have good agreement with experimental data. Removal of gangue minerals from iron ore depends on the pH of the slurry, concentration of the slurry, and concentration of the surface-active agent used. The surface-active agents at pH 8 produce ∼1.2–1.5 times more stable suspension in the case of iron ore fines and slimes than that of without surface-active agent. They significantly remove gangue minerals and increase the iron value ∼2–7% with ∼58–74% recovery depending on the experimental conditions. The concentrates collected satisfy the required specifications (Al203/Fe < 0.05 and Al203/Si02 < 1). The gangues in the dispersed phase as characterised by “SEM-EDXA” are mostly clay-bearing minerals like kaolinite, goethite, chlorite, and alumina-silicate minerals. Heat treatment causes distortion of clay minerals present in the dispersed phase and also indicates the complex nature of the gangue minerals.http://dx.doi.org/10.1155/2022/6451187
spellingShingle Jyotirmoy Sarma
Sanchayita Rajkhowa
Sekh Mahiuddin
Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value Addition
Journal of Chemistry
title Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value Addition
title_full Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value Addition
title_fullStr Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value Addition
title_full_unstemmed Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value Addition
title_short Upgradation of Iron Ore Fines and Slime by Selective Flocculation Using Surface-Active Agents, Settling Study, and Characterization of the Beneficiation Waste for Value Addition
title_sort upgradation of iron ore fines and slime by selective flocculation using surface active agents settling study and characterization of the beneficiation waste for value addition
url http://dx.doi.org/10.1155/2022/6451187
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AT sanchayitarajkhowa upgradationofironorefinesandslimebyselectiveflocculationusingsurfaceactiveagentssettlingstudyandcharacterizationofthebeneficiationwasteforvalueaddition
AT sekhmahiuddin upgradationofironorefinesandslimebyselectiveflocculationusingsurfaceactiveagentssettlingstudyandcharacterizationofthebeneficiationwasteforvalueaddition