Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption Data
Certain drawbacks of several of the conventional methods of analyzing Type I and II adsorption isotherms frequently used to characterize the structural properties of adsorbent materials have been demonstrated. A simple and flexible procedure, based on an equation combining the Dubinin equation to ac...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2009-02-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/026361709788921579 |
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| _version_ | 1832544609336557568 |
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| author | Antonio Marcilla Amparo Gomez-Siurana Ma Muñoz José Francisco Javier Valdés |
| author_facet | Antonio Marcilla Amparo Gomez-Siurana Ma Muñoz José Francisco Javier Valdés |
| author_sort | Antonio Marcilla |
| collection | DOAJ |
| description | Certain drawbacks of several of the conventional methods of analyzing Type I and II adsorption isotherms frequently used to characterize the structural properties of adsorbent materials have been demonstrated. A simple and flexible procedure, based on an equation combining the Dubinin equation to account for the micropore contribution and the BET equation to account for the non-porous contribution, has been proposed which is capable of simultaneously correlating the adsorption isotherm up to relative pressures of 0.4. Examples are presented showing that the suggested procedure provides a proper interpretation of the data coherent with the origin of the samples and avoids the misinterpretation that could arise from the application of the conventional methods. |
| format | Article |
| id | doaj-art-45a2b79c1c804f60a8abd765b5200bb2 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2009-02-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-45a2b79c1c804f60a8abd765b5200bb22025-02-03T10:08:00ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382009-02-012710.1260/026361709788921579Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption DataAntonio Marcilla0Amparo Gomez-Siurana1Ma Muñoz José2Francisco Javier Valdés3 Departmento Ingeniería Química, Universidad Alicante, Apd. 99.03080, Alicante, Spain Departmento Ingeniería Química, Universidad Alicante, Apd. 99.03080, Alicante, Spain Servicios Técnicos de Investigación, Universidad Alicante, Apd. 99.03080 Alicante, Spain Departmento Ingeniería Química, Universidad Alicante, Apd. 99.03080, Alicante, SpainCertain drawbacks of several of the conventional methods of analyzing Type I and II adsorption isotherms frequently used to characterize the structural properties of adsorbent materials have been demonstrated. A simple and flexible procedure, based on an equation combining the Dubinin equation to account for the micropore contribution and the BET equation to account for the non-porous contribution, has been proposed which is capable of simultaneously correlating the adsorption isotherm up to relative pressures of 0.4. Examples are presented showing that the suggested procedure provides a proper interpretation of the data coherent with the origin of the samples and avoids the misinterpretation that could arise from the application of the conventional methods.https://doi.org/10.1260/026361709788921579 |
| spellingShingle | Antonio Marcilla Amparo Gomez-Siurana Ma Muñoz José Francisco Javier Valdés Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption Data Adsorption Science & Technology |
| title | Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption Data |
| title_full | Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption Data |
| title_fullStr | Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption Data |
| title_full_unstemmed | Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption Data |
| title_short | Comments on the Methods of Characterization of Textural Properties of Solids from Gas Adsorption Data |
| title_sort | comments on the methods of characterization of textural properties of solids from gas adsorption data |
| url | https://doi.org/10.1260/026361709788921579 |
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