Controlling the Chromaticity of White-Emitting LEDs Through Solvatochromism

LEDs that emit white light are commercially available in various shades, ranging from ‘cool white’ to ‘warm white’. They employ different luminescent wavelength converting materials (phosphors) to achieve specific spectral outputs. In this work we show that solvatochromism—the ability to change the...

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Main Authors: Md. Mahmudul Hasan, Gregory Sheets, Faiz Rahman
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Photonics
Subjects:
Online Access:https://www.mdpi.com/2304-6732/12/3/189
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author Md. Mahmudul Hasan
Gregory Sheets
Faiz Rahman
author_facet Md. Mahmudul Hasan
Gregory Sheets
Faiz Rahman
author_sort Md. Mahmudul Hasan
collection DOAJ
description LEDs that emit white light are commercially available in various shades, ranging from ‘cool white’ to ‘warm white’. They employ different luminescent wavelength converting materials (phosphors) to achieve specific spectral outputs. In this work we show that solvatochromism—the ability to change the color of fluorescence emission by dissolving a soluble luminescent material in different solvents—can be used to easily set the color point of a white-emitting LED. Compared to the use of all-solid phosphors, this liquid phosphor technology allows continuous tunability of emission colors over, potentially, a broader range of color shades. Via the appropriate choice of a solute and solvent combination, any desired chromaticity point and correlated color temperature, within the bounds allowed by the particular material combination, can be achieved. By using the right manufacturing technology, such LEDs can be mass-produced because most of their other components are the same as that of traditional LEDs.
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spelling doaj-art-4500e54aba504d9583656985d1f8b3c02025-08-20T02:42:24ZengMDPI AGPhotonics2304-67322025-02-0112318910.3390/photonics12030189Controlling the Chromaticity of White-Emitting LEDs Through SolvatochromismMd. Mahmudul Hasan0Gregory Sheets1Faiz Rahman2School of Electrical Engineering and Computer Science, Russ College of Engineering and Technology, Ohio University, Athens, OH 45701, USASchool of Electrical Engineering and Computer Science, Russ College of Engineering and Technology, Ohio University, Athens, OH 45701, USASchool of Electrical Engineering and Computer Science, Russ College of Engineering and Technology, Ohio University, Athens, OH 45701, USALEDs that emit white light are commercially available in various shades, ranging from ‘cool white’ to ‘warm white’. They employ different luminescent wavelength converting materials (phosphors) to achieve specific spectral outputs. In this work we show that solvatochromism—the ability to change the color of fluorescence emission by dissolving a soluble luminescent material in different solvents—can be used to easily set the color point of a white-emitting LED. Compared to the use of all-solid phosphors, this liquid phosphor technology allows continuous tunability of emission colors over, potentially, a broader range of color shades. Via the appropriate choice of a solute and solvent combination, any desired chromaticity point and correlated color temperature, within the bounds allowed by the particular material combination, can be achieved. By using the right manufacturing technology, such LEDs can be mass-produced because most of their other components are the same as that of traditional LEDs.https://www.mdpi.com/2304-6732/12/3/189light-emitting diodesolvatochromismcharge transfer complexcoordination compound
spellingShingle Md. Mahmudul Hasan
Gregory Sheets
Faiz Rahman
Controlling the Chromaticity of White-Emitting LEDs Through Solvatochromism
Photonics
light-emitting diode
solvatochromism
charge transfer complex
coordination compound
title Controlling the Chromaticity of White-Emitting LEDs Through Solvatochromism
title_full Controlling the Chromaticity of White-Emitting LEDs Through Solvatochromism
title_fullStr Controlling the Chromaticity of White-Emitting LEDs Through Solvatochromism
title_full_unstemmed Controlling the Chromaticity of White-Emitting LEDs Through Solvatochromism
title_short Controlling the Chromaticity of White-Emitting LEDs Through Solvatochromism
title_sort controlling the chromaticity of white emitting leds through solvatochromism
topic light-emitting diode
solvatochromism
charge transfer complex
coordination compound
url https://www.mdpi.com/2304-6732/12/3/189
work_keys_str_mv AT mdmahmudulhasan controllingthechromaticityofwhiteemittingledsthroughsolvatochromism
AT gregorysheets controllingthechromaticityofwhiteemittingledsthroughsolvatochromism
AT faizrahman controllingthechromaticityofwhiteemittingledsthroughsolvatochromism