Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline
We report simple synthesis of boron trifluoride (BF3) doped defect free high performance polyaniline (HPPANI) in two step method. Firstly, HPPANI was prepared via self-stabilization dispersion polymerization method in a heterogeneous reaction medium. Second step involves doping of emeraldine base fo...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/275862 |
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| author | K. Basavaiah D. Samsonu A. V. Prasada Rao |
| author_facet | K. Basavaiah D. Samsonu A. V. Prasada Rao |
| author_sort | K. Basavaiah |
| collection | DOAJ |
| description | We report simple synthesis of boron trifluoride (BF3) doped defect free high performance polyaniline (HPPANI) in two step method. Firstly, HPPANI was prepared via self-stabilization dispersion polymerization method in a heterogeneous reaction medium. Second step involves doping of emeraldine base form of HPPANI with boron trifluoride under reduced vacuum. The resultants BF3 doped HPPANI have been well characterized by using UV-Visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetry. The spectroscopic data indicated that the interaction between HPPANI and BF3.Thermogravimetry studies revealed that the BF3 doping improved the thermal stability of defects free PANI. |
| format | Article |
| id | doaj-art-4329acceda72484e938e9e878f433f78 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-4329acceda72484e938e9e878f433f782025-02-03T01:09:11ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01942332233710.1155/2012/275862Synthesis and Characterization of Boron Trifluoride Doped High Performance PolyanilineK. Basavaiah0D. Samsonu1A. V. Prasada Rao2Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam-530003, IndiaDepartments of Organic, Foods, Drugs and Water, Andhra University, Visakhapatnam-530003, IndiaDepartment of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam-530003, IndiaWe report simple synthesis of boron trifluoride (BF3) doped defect free high performance polyaniline (HPPANI) in two step method. Firstly, HPPANI was prepared via self-stabilization dispersion polymerization method in a heterogeneous reaction medium. Second step involves doping of emeraldine base form of HPPANI with boron trifluoride under reduced vacuum. The resultants BF3 doped HPPANI have been well characterized by using UV-Visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetry. The spectroscopic data indicated that the interaction between HPPANI and BF3.Thermogravimetry studies revealed that the BF3 doping improved the thermal stability of defects free PANI.http://dx.doi.org/10.1155/2012/275862 |
| spellingShingle | K. Basavaiah D. Samsonu A. V. Prasada Rao Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline E-Journal of Chemistry |
| title | Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline |
| title_full | Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline |
| title_fullStr | Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline |
| title_full_unstemmed | Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline |
| title_short | Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline |
| title_sort | synthesis and characterization of boron trifluoride doped high performance polyaniline |
| url | http://dx.doi.org/10.1155/2012/275862 |
| work_keys_str_mv | AT kbasavaiah synthesisandcharacterizationofborontrifluoridedopedhighperformancepolyaniline AT dsamsonu synthesisandcharacterizationofborontrifluoridedopedhighperformancepolyaniline AT avprasadarao synthesisandcharacterizationofborontrifluoridedopedhighperformancepolyaniline |