Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent
Morpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions. Moreover, it is inert towards aldehydes, ketons, oximes, thiol...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/851734 |
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| author | S. Zahra Sayyed-Alangi H. Sajjadi-Ghotbabadi Mohammed T. Baei Sahar Naderi |
| author_facet | S. Zahra Sayyed-Alangi H. Sajjadi-Ghotbabadi Mohammed T. Baei Sahar Naderi |
| author_sort | S. Zahra Sayyed-Alangi |
| collection | DOAJ |
| description | Morpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions. Moreover, it is inert towards aldehydes, ketons, oximes, thiols, sulfids, phenols, pyrans, trimethylsilanes, malonates and thioacetamides. The durability, reaction rate, ease of filtration and efficiency of MFC are considerably increased upon its absorption on silica gel. |
| format | Article |
| id | doaj-art-42d388526247466a827d68d9d2571887 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-42d388526247466a827d68d9d25718872025-02-03T05:59:42ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018281581810.1155/2011/851734Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous ReagentS. Zahra Sayyed-Alangi0H. Sajjadi-Ghotbabadi1Mohammed T. Baei2Sahar Naderi3Department of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranDepartment of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranDepartment of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranDepartment of Chemistry, Azadshahr Branch, Islamic Azad University, Azadshahr, Golestan, IranMorpholinium fluorochromate(VI), MFC, is easily synthesized by reacting morpholine to an aqueous solution of CrO3 and HF. This reagent selectively oxidizes aryl alcohols to their corresponding aldehydes and ketones under mild conditions. Moreover, it is inert towards aldehydes, ketons, oximes, thiols, sulfids, phenols, pyrans, trimethylsilanes, malonates and thioacetamides. The durability, reaction rate, ease of filtration and efficiency of MFC are considerably increased upon its absorption on silica gel.http://dx.doi.org/10.1155/2011/851734 |
| spellingShingle | S. Zahra Sayyed-Alangi H. Sajjadi-Ghotbabadi Mohammed T. Baei Sahar Naderi Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent E-Journal of Chemistry |
| title | Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent |
| title_full | Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent |
| title_fullStr | Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent |
| title_full_unstemmed | Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent |
| title_short | Oxidation of Aryl Alcohols by Morpholinium Fluorochromate(VI) on Silica Gel, a Selective and Efficient Heterogeneous Reagent |
| title_sort | oxidation of aryl alcohols by morpholinium fluorochromate vi on silica gel a selective and efficient heterogeneous reagent |
| url | http://dx.doi.org/10.1155/2011/851734 |
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