Development of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substrates

The surface engineering technique evolved, making it easier to protect steel from harsh and corrosive environments. Corrosion is an enduring problem for steel that cannot be completely eliminated but can be reduced to the bare minimum. Traditional methods like galvanization and painting still exist,...

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Main Authors: Muhammad Sajid Ali Asghar, Umer Hussain, Muhammad Ovais, Shaheer Ahmed Khan, Abdul Aabid, Muneer Baig, Mohammad Abdul Malik
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/adae5b
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author Muhammad Sajid Ali Asghar
Umer Hussain
Muhammad Ovais
Shaheer Ahmed Khan
Abdul Aabid
Muneer Baig
Mohammad Abdul Malik
author_facet Muhammad Sajid Ali Asghar
Umer Hussain
Muhammad Ovais
Shaheer Ahmed Khan
Abdul Aabid
Muneer Baig
Mohammad Abdul Malik
author_sort Muhammad Sajid Ali Asghar
collection DOAJ
description The surface engineering technique evolved, making it easier to protect steel from harsh and corrosive environments. Corrosion is an enduring problem for steel that cannot be completely eliminated but can be reduced to the bare minimum. Traditional methods like galvanization and painting still exist, but hydrophobic coatings are efficient and mostly used to protect the steel from deterioration. In this work we have used nano composite hydrophobic coatings among Zn (galvanized), ZnO, and Zn/ZnO on steel samples to enhance efficiency and effectiveness in reducing corrosion rate. Electrodeposition techniques are used to incorporate the coating deposits. Spark emission spectroscopy and x-ray Fluorescence elemental analysis shows the composition of bare and galvanized steel. The x-ray Diffraction analysis (XRD) analysis proved that Zn/ZnO phases are present in coatings. The results of scratch test revealed that the bond strength increased in the hydro-Zn/ZnO-coated samples as compared to the Zn or Zn/ZnO-coated samples. Furthermore, Scanning Electron Microscopy (SEM) analysis revealed the formation of a new layer on the substrate’s surface, causing it to become rough and exhibiting growing nanostructure properties. The contact angle test proves the hydrophobic nature of composite coatings on the steel samples. The STA Zn/ZnO, coating shows the super hydrophobicity with the lowest corrosion rate, at 0.04 mm/area.
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spelling doaj-art-425b93835ece4ac585b2267518cca5d52025-02-04T05:20:00ZengIOP PublishingMaterials Research Express2053-15912025-01-0112202640110.1088/2053-1591/adae5bDevelopment of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substratesMuhammad Sajid Ali Asghar0https://orcid.org/0000-0002-4551-1299Umer Hussain1https://orcid.org/0009-0004-8293-492XMuhammad Ovais2https://orcid.org/0009-0005-3791-5487Shaheer Ahmed Khan3https://orcid.org/0000-0002-7302-0884Abdul Aabid4Muneer Baig5Mohammad Abdul Malik6Department of Materials Engineering, NED University of Engineering and Technology (NEDUET) , Karachi 75270, PakistanDepartment of Materials Engineering, NED University of Engineering and Technology (NEDUET) , Karachi 75270, PakistanDepartment of Materials Engineering, NED University of Engineering and Technology (NEDUET) , Karachi 75270, PakistanNational University of Sciences and Technology (NUST) , Islamabad, PakistanDepartment of Engineering Management, College of Engineering, Prince Sultan University , PO BOX 66833, Riyadh 11586, Saudi ArabiaDepartment of Engineering Management, College of Engineering, Prince Sultan University , PO BOX 66833, Riyadh 11586, Saudi ArabiaDepartment of Engineering Management, College of Engineering, Prince Sultan University , PO BOX 66833, Riyadh 11586, Saudi ArabiaThe surface engineering technique evolved, making it easier to protect steel from harsh and corrosive environments. Corrosion is an enduring problem for steel that cannot be completely eliminated but can be reduced to the bare minimum. Traditional methods like galvanization and painting still exist, but hydrophobic coatings are efficient and mostly used to protect the steel from deterioration. In this work we have used nano composite hydrophobic coatings among Zn (galvanized), ZnO, and Zn/ZnO on steel samples to enhance efficiency and effectiveness in reducing corrosion rate. Electrodeposition techniques are used to incorporate the coating deposits. Spark emission spectroscopy and x-ray Fluorescence elemental analysis shows the composition of bare and galvanized steel. The x-ray Diffraction analysis (XRD) analysis proved that Zn/ZnO phases are present in coatings. The results of scratch test revealed that the bond strength increased in the hydro-Zn/ZnO-coated samples as compared to the Zn or Zn/ZnO-coated samples. Furthermore, Scanning Electron Microscopy (SEM) analysis revealed the formation of a new layer on the substrate’s surface, causing it to become rough and exhibiting growing nanostructure properties. The contact angle test proves the hydrophobic nature of composite coatings on the steel samples. The STA Zn/ZnO, coating shows the super hydrophobicity with the lowest corrosion rate, at 0.04 mm/area.https://doi.org/10.1088/2053-1591/adae5bcorrosionhydrophobicZinccontact anglegalvanized steelelectrodeposition
spellingShingle Muhammad Sajid Ali Asghar
Umer Hussain
Muhammad Ovais
Shaheer Ahmed Khan
Abdul Aabid
Muneer Baig
Mohammad Abdul Malik
Development of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substrates
Materials Research Express
corrosion
hydrophobic
Zinc
contact angle
galvanized steel
electrodeposition
title Development of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substrates
title_full Development of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substrates
title_fullStr Development of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substrates
title_full_unstemmed Development of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substrates
title_short Development of corrosion-resistant hydrophobic Zn/ZnO composite coatings on steel substrates
title_sort development of corrosion resistant hydrophobic zn zno composite coatings on steel substrates
topic corrosion
hydrophobic
Zinc
contact angle
galvanized steel
electrodeposition
url https://doi.org/10.1088/2053-1591/adae5b
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