A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose Microfibrils

Wide-angle X-ray diffraction analysis is a powerful tool for investigating the structure and orientation of cellulose microfibrils in plant cell walls, but the complex relationship between diffraction patterns and underlying structural parameters remains challenging to both understand and validate....

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Main Authors: Ricardo Baettig, Ben Ingram
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Data
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Online Access:https://www.mdpi.com/2306-5729/10/4/47
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author Ricardo Baettig
Ben Ingram
author_facet Ricardo Baettig
Ben Ingram
author_sort Ricardo Baettig
collection DOAJ
description Wide-angle X-ray diffraction analysis is a powerful tool for investigating the structure and orientation of cellulose microfibrils in plant cell walls, but the complex relationship between diffraction patterns and underlying structural parameters remains challenging to both understand and validate. This study presents a comprehensive dataset of 81,906 Monte Carlo-simulated wide-angle X-ray diffraction patterns for the cellulose I<i>β</i> 200 lattice. The dataset was generated using a mechanistic, physically informed simulation procedure that incorporates realistic cell wall geometries from wood anatomy, including circular and polygonal fibers, and accounts for the full range of crystallographic and anatomical parameters influencing diffraction patterns. Each simulated pattern required multiple nested Monte Carlo iterations, totaling approximately 10 million calculations per pattern. The resulting dataset pairs each diffraction pattern with its exact generating parameter set, including mean microfibril angle (MFA), MFA variability, fiber tilt angles, and cell wall cross-sectional shape. The dataset addresses a significant barrier in the field—the lack of validated reference data with known ground truth values for testing and developing new analytical methods. It enables the development, validation, and benchmarking of novel algorithms and machine learning models for MFA prediction from diffraction patterns. The simulated data also allow for systematic investigation of the effects of geometric factors on diffraction patterns and serves as an educational resource for visualizing structure–diffraction relationships. Despite some limitations, such as assuming ideal diffraction conditions and focusing primarily on the S2 cell wall layer, this dataset provides a valuable foundation for advancing X-ray diffraction analysis methods for cellulose microfibril architecture characterization in plant cell walls.
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spelling doaj-art-424f4cb9c4894de381714d0bee8bf7b32025-08-20T02:17:25ZengMDPI AGData2306-57292025-03-011044710.3390/data10040047A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose MicrofibrilsRicardo Baettig0Ben Ingram1Facultad de Ciencias Forestales y de la Conservación de la Naturaleza, Universidad de Chile, La Pintana 8820808, Santiago, ChileDepartment of Interactive Visualization and Virtual Reality, Faculty of Engineering, Universidad de Talca, Talca 3460000, Talca, ChileWide-angle X-ray diffraction analysis is a powerful tool for investigating the structure and orientation of cellulose microfibrils in plant cell walls, but the complex relationship between diffraction patterns and underlying structural parameters remains challenging to both understand and validate. This study presents a comprehensive dataset of 81,906 Monte Carlo-simulated wide-angle X-ray diffraction patterns for the cellulose I<i>β</i> 200 lattice. The dataset was generated using a mechanistic, physically informed simulation procedure that incorporates realistic cell wall geometries from wood anatomy, including circular and polygonal fibers, and accounts for the full range of crystallographic and anatomical parameters influencing diffraction patterns. Each simulated pattern required multiple nested Monte Carlo iterations, totaling approximately 10 million calculations per pattern. The resulting dataset pairs each diffraction pattern with its exact generating parameter set, including mean microfibril angle (MFA), MFA variability, fiber tilt angles, and cell wall cross-sectional shape. The dataset addresses a significant barrier in the field—the lack of validated reference data with known ground truth values for testing and developing new analytical methods. It enables the development, validation, and benchmarking of novel algorithms and machine learning models for MFA prediction from diffraction patterns. The simulated data also allow for systematic investigation of the effects of geometric factors on diffraction patterns and serves as an educational resource for visualizing structure–diffraction relationships. Despite some limitations, such as assuming ideal diffraction conditions and focusing primarily on the S2 cell wall layer, this dataset provides a valuable foundation for advancing X-ray diffraction analysis methods for cellulose microfibril architecture characterization in plant cell walls.https://www.mdpi.com/2306-5729/10/4/47cellulose microfibrilsmicrofibril angleX-ray diffractionwide-angle X-ray diffractionMonte Carlo simulationplant cell walls
spellingShingle Ricardo Baettig
Ben Ingram
A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose Microfibrils
Data
cellulose microfibrils
microfibril angle
X-ray diffraction
wide-angle X-ray diffraction
Monte Carlo simulation
plant cell walls
title A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose Microfibrils
title_full A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose Microfibrils
title_fullStr A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose Microfibrils
title_full_unstemmed A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose Microfibrils
title_short A Comprehensive Monte Carlo-Simulated Dataset of WAXD Patterns of Wood Cellulose Microfibrils
title_sort comprehensive monte carlo simulated dataset of waxd patterns of wood cellulose microfibrils
topic cellulose microfibrils
microfibril angle
X-ray diffraction
wide-angle X-ray diffraction
Monte Carlo simulation
plant cell walls
url https://www.mdpi.com/2306-5729/10/4/47
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