Enhancing the density of silicon carbide with the addition of nitrate-based additives

Dense monolithic silicon carbide (SiC) was successfully sintered by hot pressing at 1750ºC for 1 h under an applied pressure of 20 MPa with the addition of a nitrate-based additive. With the addition of MgO-Y2O3 and Al2O3-Y2O3 in nitrate form, a relative density of more than 98% was achieved, while...

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Main Authors: Dioktyanto M., Aryanto D., Noviyanto A., Yuwono A.H., Rochman N.T.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2022-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392200020D.pdf
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author Dioktyanto M.
Aryanto D.
Noviyanto A.
Yuwono A.H.
Rochman N.T.
author_facet Dioktyanto M.
Aryanto D.
Noviyanto A.
Yuwono A.H.
Rochman N.T.
author_sort Dioktyanto M.
collection DOAJ
description Dense monolithic silicon carbide (SiC) was successfully sintered by hot pressing at 1750ºC for 1 h under an applied pressure of 20 MPa with the addition of a nitrate-based additive. With the addition of MgO-Y2O3 and Al2O3-Y2O3 in nitrate form, a relative density of more than 98% was achieved, while in the oxide form it was 85.0 and 96.0%, respectively. In fact, MgO-Y2O3 showed poor densification due to the eutectic temperature of 2110ºC, however, the addition of the nitrate form of MgO-Y2O3 greatly enhanced the densification. The sintering mechanism in the nitrate-based additive is liquid phase sintering, identified by the presence of an oxide phase, i.e., Y2O3 in the SiC with the addition of Al2O3-Y2O3 in nitrate form. Moreover, the addition of nitrate form suppressed the grain growth of SiC, which was believed to be due to the adequate rearrangement stage during sintering.
format Article
id doaj-art-4226819766bb412da9e7a07e3e5a3e57
institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2022-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-4226819766bb412da9e7a07e3e5a3e572025-02-03T07:49:32ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752022-01-0158338939510.2298/JMMB220215020D1450-53392200020DEnhancing the density of silicon carbide with the addition of nitrate-based additivesDioktyanto M.0Aryanto D.1Noviyanto A.2Yuwono A.H.3Rochman N.T.4Universitas Indonesia, Faculty of Engineering, Department of Metallurgical and Materials Engineering, Kampus UI Depok, Indonesia + Nano Center Indonesia, Jl. PUSPIPTEK, Tangerang Selatan, IndonesiaNational Research and Innovation Agency, Research Center for Advanced Materials, PUSPIPTEK, Tangerang Selatan, Indonesia Nano Center Indonesia, Jl. PUSPIPTEK, Tangerang Selatan, Indonesia + Mercu Buana University, Department of Mechanical Engineering, Jl. Meruya Selatan, Kebun Jeruk, IndonesiaUniversitas Indonesia, Faculty of Engineering, Department of Metallurgical and Materials Engineering, Kampus UI Depok, Indonesia National Research and Innovation Agency, Research Center for Advanced Materials, PUSPIPTEK, Tangerang Selatan, IndonesiaDense monolithic silicon carbide (SiC) was successfully sintered by hot pressing at 1750ºC for 1 h under an applied pressure of 20 MPa with the addition of a nitrate-based additive. With the addition of MgO-Y2O3 and Al2O3-Y2O3 in nitrate form, a relative density of more than 98% was achieved, while in the oxide form it was 85.0 and 96.0%, respectively. In fact, MgO-Y2O3 showed poor densification due to the eutectic temperature of 2110ºC, however, the addition of the nitrate form of MgO-Y2O3 greatly enhanced the densification. The sintering mechanism in the nitrate-based additive is liquid phase sintering, identified by the presence of an oxide phase, i.e., Y2O3 in the SiC with the addition of Al2O3-Y2O3 in nitrate form. Moreover, the addition of nitrate form suppressed the grain growth of SiC, which was believed to be due to the adequate rearrangement stage during sintering.http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392200020D.pdfsilicon carbidenitrateoxidesintering additivedensity
spellingShingle Dioktyanto M.
Aryanto D.
Noviyanto A.
Yuwono A.H.
Rochman N.T.
Enhancing the density of silicon carbide with the addition of nitrate-based additives
Journal of Mining and Metallurgy. Section B: Metallurgy
silicon carbide
nitrate
oxide
sintering additive
density
title Enhancing the density of silicon carbide with the addition of nitrate-based additives
title_full Enhancing the density of silicon carbide with the addition of nitrate-based additives
title_fullStr Enhancing the density of silicon carbide with the addition of nitrate-based additives
title_full_unstemmed Enhancing the density of silicon carbide with the addition of nitrate-based additives
title_short Enhancing the density of silicon carbide with the addition of nitrate-based additives
title_sort enhancing the density of silicon carbide with the addition of nitrate based additives
topic silicon carbide
nitrate
oxide
sintering additive
density
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2022/1450-53392200020D.pdf
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