Ni12P5 and Ni12P5-rGO for multifunctional electrocatalyst and supercapacitor application
Transition metal phosphides are crucial for various environmental and energy applications. In this study, porous Ni12P5 and Ni12P5-rGO were synthesized using a one-step solvothermal method. Red phosphorus served as the phosphorus source, while ethylene glycol acted as a capping agent to promote the...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-02-01
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| Series: | Heliyon |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844025007947 |
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| Summary: | Transition metal phosphides are crucial for various environmental and energy applications. In this study, porous Ni12P5 and Ni12P5-rGO were synthesized using a one-step solvothermal method. Red phosphorus served as the phosphorus source, while ethylene glycol acted as a capping agent to promote the formation of nanomaterials within a nitrogen-rich atmosphere. The catalytic performance of these materials was evaluated through their hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and capacitance properties. Notably, Ni12P5-rGO exhibited Tafel slopes of 66 mV/dec for OER and 33 mV/dec for HER, indicating enhanced charge transfer efficiency compared to Ni12P5, which showed slopes of 78 mV/dec and 102 mV/dec, respectively. This improvement suggests that Ni12P5-rGO facilitates faster electron transfer, resulting in superior catalytic performance. Additionally, the synergistic effect of reduced graphene oxide (rGO) contributes to improved charge storage capabilities. The Ni12P5-rGO demonstrated a specific capacitance of 192 F/g, significantly higher than the 110 F/g observed for Ni12P5 at a current density of 1 A/g. Remarkably, these materials maintained their capacity over 5000 cycles, achieving a commendable 98 % coulombic efficiency. These findings highlight the potential of Ni12P5-rGO as an effective material for energy conversion and storage applications, showcasing its promising role in advancing the efficiency of related technologies. |
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| ISSN: | 2405-8440 |