Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol
The 3-methyl-1H-1,2,4-triazole-5-thiol (MTH) was used as a suitable ionophore for fabrication of a new gadolinium(III) ion selective potentiometric sensor. Nitrobenzene (NB) was used as plasticizing solvent mediator and sodium tetraphenyl borate (NaTPB) as an anion excluder. It displays a Nernstian...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/239245 |
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| author | Hassan Ali Zamani Hossein Behmadi |
| author_facet | Hassan Ali Zamani Hossein Behmadi |
| author_sort | Hassan Ali Zamani |
| collection | DOAJ |
| description | The 3-methyl-1H-1,2,4-triazole-5-thiol (MTH) was used as a suitable ionophore for fabrication of a new gadolinium(III) ion selective potentiometric sensor. Nitrobenzene (NB) was used as plasticizing solvent mediator and sodium tetraphenyl borate (NaTPB) as an anion excluder. It displays a Nernstian response (19.8± 0.4 mV/decade) in the concentration range of 1.0×10-7 to 1.0×10-2 M with the detection limit of 7.3×10-8 M. The sensor has a very short response time (<10s) and can be used the pH range of 2.9-8.4. electrode was successfully applied as an indicator for gadolinium determination in titration with EDTA. |
| format | Article |
| id | doaj-art-41d3794a6dfb43a5a417529bf4cfe829 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-41d3794a6dfb43a5a417529bf4cfe8292025-02-03T05:53:44ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019130831210.1155/2012/239245Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiolHassan Ali Zamani0Hossein Behmadi1Department of Applied Chemistry, Quchan Branch, Islamic Azad University, Quchan, IranDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, IranThe 3-methyl-1H-1,2,4-triazole-5-thiol (MTH) was used as a suitable ionophore for fabrication of a new gadolinium(III) ion selective potentiometric sensor. Nitrobenzene (NB) was used as plasticizing solvent mediator and sodium tetraphenyl borate (NaTPB) as an anion excluder. It displays a Nernstian response (19.8± 0.4 mV/decade) in the concentration range of 1.0×10-7 to 1.0×10-2 M with the detection limit of 7.3×10-8 M. The sensor has a very short response time (<10s) and can be used the pH range of 2.9-8.4. electrode was successfully applied as an indicator for gadolinium determination in titration with EDTA.http://dx.doi.org/10.1155/2012/239245 |
| spellingShingle | Hassan Ali Zamani Hossein Behmadi Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol E-Journal of Chemistry |
| title | Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol |
| title_full | Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol |
| title_fullStr | Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol |
| title_full_unstemmed | Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol |
| title_short | Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol |
| title_sort | gadolinium iii ion selective electrode based on 3 methyl 1h 1 2 4 triazole 5 thiol |
| url | http://dx.doi.org/10.1155/2012/239245 |
| work_keys_str_mv | AT hassanalizamani gadoliniumiiiionselectiveelectrodebasedon3methyl1h124triazole5thiol AT hosseinbehmadi gadoliniumiiiionselectiveelectrodebasedon3methyl1h124triazole5thiol |