Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry

Study region: Verlorenvlei Catchment (∼1 890 km2) is an agriculture-dominated area (∼43 % per km2) on South Africa’s west coast. This semi-arid region has variable rainfall and high evaporation rates, affecting the three major aquifers and Verlorenvlei – a RAMSAR-listed estuarine lake. Study focus:...

Full description

Saved in:
Bibliographic Details
Main Authors: A. Welham, J. van Rooyen, A. Watson, J. Miller, R. Chow
Format: Article
Language:English
Published: Elsevier 2025-02-01
Series:Journal of Hydrology: Regional Studies
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214581824004300
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832591831959863296
author A. Welham
J. van Rooyen
A. Watson
J. Miller
R. Chow
author_facet A. Welham
J. van Rooyen
A. Watson
J. Miller
R. Chow
author_sort A. Welham
collection DOAJ
description Study region: Verlorenvlei Catchment (∼1 890 km2) is an agriculture-dominated area (∼43 % per km2) on South Africa’s west coast. This semi-arid region has variable rainfall and high evaporation rates, affecting the three major aquifers and Verlorenvlei – a RAMSAR-listed estuarine lake. Study focus: Natural processes (i.e., extended dry periods and evaporation) and anthropogenic activities (i.e., agricultural expansion and groundwater abstraction) have threatened Verlorenvlei’s ecological functions. Seasonal and spatial changes between the water sources (i.e., direct rainfall, surface water, and groundwater) supporting Verlorenvlei were determined using δ18O and δ2H isotopes and hydrochemical analyses. Inter-basin aquifer contribution was investigated to assist in explaining Verlorenvlei's slow recovery since the recent 2015 – 2018 Western Cape drought. New insights: A proportion of groundwater from outside the topographic and surface-water delineated catchment supports Verlorenvlei during the dry month of April (i.e., G30F Langvlei sub-catchment). Furthermore, Verlorenvlei experiences high evaporation (evaporation best fit line: δ2H = 12.49 x δ18O - 47.68, average δ2H value of 47.1 ‰ and average δ18O value of 7.64 ‰) compared to its feeding rivers. Two sandstone and shale-dominated sub-catchments exhibit overlapping groundwater δ18O and δ2H values and water types to the sub-catchment in the nearest vicinity of Verlorenvlei, suggesting a disproportionately high groundwater contribution from these sub-catchments to Verlorenvlei. Evaluation of Verlorenvlei’s water balance should consider both surface water and groundwater sources, particularly from inter-basin aquifer sources during prolonged droughts.
format Article
id doaj-art-411a3e56df0d4fa19cc059d0d8d5016a
institution Kabale University
issn 2214-5818
language English
publishDate 2025-02-01
publisher Elsevier
record_format Article
series Journal of Hydrology: Regional Studies
spelling doaj-art-411a3e56df0d4fa19cc059d0d8d5016a2025-01-22T05:41:57ZengElsevierJournal of Hydrology: Regional Studies2214-58182025-02-0157102081Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistryA. Welham0J. van Rooyen1A. Watson2J. Miller3R. Chow4Department of Earth Sciences, Stellenbosch University, Private Bag X1, 7602 Matieland, South Africa; Correspondence to: Department of Earth Sciences, Stellenbosch University, Matieland, Stellenbosch, South Africa.Department of Earth Sciences, Stellenbosch University, Private Bag X1, 7602 Matieland, South Africa; Eawag, Swiss Federal Institute of Aquatic Science and Technology, Überlandstrasse 133, 8600 Dübendorf, SwitzerlandSchool of Climate Studies, Stellenbosch University, Private Bag X1, 7602 Matieland, South AfricaIsotope Hydrology Section, International Atomic Energy Agency, Vienna International Centre, P.O. Box 100, A-1400 Vienna, AustriaDepartment of Earth Sciences, Stellenbosch University, Private Bag X1, 7602 Matieland, South Africa; Soil Physics and Land Management Group, Wageningen University & Research, P.O. Box 47, 6700 AA Wageningen, Netherlands; Correspondence to: Soil Physics and Land Management Group, Wageningen University & Research, Wageningen, Netherlands.Study region: Verlorenvlei Catchment (∼1 890 km2) is an agriculture-dominated area (∼43 % per km2) on South Africa’s west coast. This semi-arid region has variable rainfall and high evaporation rates, affecting the three major aquifers and Verlorenvlei – a RAMSAR-listed estuarine lake. Study focus: Natural processes (i.e., extended dry periods and evaporation) and anthropogenic activities (i.e., agricultural expansion and groundwater abstraction) have threatened Verlorenvlei’s ecological functions. Seasonal and spatial changes between the water sources (i.e., direct rainfall, surface water, and groundwater) supporting Verlorenvlei were determined using δ18O and δ2H isotopes and hydrochemical analyses. Inter-basin aquifer contribution was investigated to assist in explaining Verlorenvlei's slow recovery since the recent 2015 – 2018 Western Cape drought. New insights: A proportion of groundwater from outside the topographic and surface-water delineated catchment supports Verlorenvlei during the dry month of April (i.e., G30F Langvlei sub-catchment). Furthermore, Verlorenvlei experiences high evaporation (evaporation best fit line: δ2H = 12.49 x δ18O - 47.68, average δ2H value of 47.1 ‰ and average δ18O value of 7.64 ‰) compared to its feeding rivers. Two sandstone and shale-dominated sub-catchments exhibit overlapping groundwater δ18O and δ2H values and water types to the sub-catchment in the nearest vicinity of Verlorenvlei, suggesting a disproportionately high groundwater contribution from these sub-catchments to Verlorenvlei. Evaluation of Verlorenvlei’s water balance should consider both surface water and groundwater sources, particularly from inter-basin aquifer sources during prolonged droughts.http://www.sciencedirect.com/science/article/pii/S2214581824004300Water stable isotope (δ18O and δ2H)HydrochemistryInter-basin aquiferCatchment delineationSemi-arid environmentVerlorenvlei
spellingShingle A. Welham
J. van Rooyen
A. Watson
J. Miller
R. Chow
Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry
Journal of Hydrology: Regional Studies
Water stable isotope (δ18O and δ2H)
Hydrochemistry
Inter-basin aquifer
Catchment delineation
Semi-arid environment
Verlorenvlei
title Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry
title_full Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry
title_fullStr Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry
title_full_unstemmed Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry
title_short Assessing inter-basin groundwater input to the Verlorenvlei estuarine lake using stable isotopes and hydrochemistry
title_sort assessing inter basin groundwater input to the verlorenvlei estuarine lake using stable isotopes and hydrochemistry
topic Water stable isotope (δ18O and δ2H)
Hydrochemistry
Inter-basin aquifer
Catchment delineation
Semi-arid environment
Verlorenvlei
url http://www.sciencedirect.com/science/article/pii/S2214581824004300
work_keys_str_mv AT awelham assessinginterbasingroundwaterinputtotheverlorenvleiestuarinelakeusingstableisotopesandhydrochemistry
AT jvanrooyen assessinginterbasingroundwaterinputtotheverlorenvleiestuarinelakeusingstableisotopesandhydrochemistry
AT awatson assessinginterbasingroundwaterinputtotheverlorenvleiestuarinelakeusingstableisotopesandhydrochemistry
AT jmiller assessinginterbasingroundwaterinputtotheverlorenvleiestuarinelakeusingstableisotopesandhydrochemistry
AT rchow assessinginterbasingroundwaterinputtotheverlorenvleiestuarinelakeusingstableisotopesandhydrochemistry