Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production

MXenes have emerged as promising two-dimensional (2D) materials for catalytic applications in energy production due to their exceptional structural, electronic, and chemical properties. Their high surface area, tunable surface terminations, and excellent electrical conductivity make them ideal candi...

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Main Authors: Nur-Sultan Mussa, Kydyr Askaruly, Kalampyr Bexeitova, Seitkhan Azat, Kainaubek Toshtay
Format: Article
Language:English
Published: Elsevier 2025-08-01
Series:Carbon Trends
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Online Access:http://www.sciencedirect.com/science/article/pii/S2667056925001014
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author Nur-Sultan Mussa
Kydyr Askaruly
Kalampyr Bexeitova
Seitkhan Azat
Kainaubek Toshtay
author_facet Nur-Sultan Mussa
Kydyr Askaruly
Kalampyr Bexeitova
Seitkhan Azat
Kainaubek Toshtay
author_sort Nur-Sultan Mussa
collection DOAJ
description MXenes have emerged as promising two-dimensional (2D) materials for catalytic applications in energy production due to their exceptional structural, electronic, and chemical properties. Their high surface area, tunable surface terminations, and excellent electrical conductivity make them ideal candidates for facilitating surface reactions and enhancing charge transfer processes. Additionally, the ability to modify their composition and structure at the atomic level allows for the design of tailored MXene-based catalysts suited for various energy-related reactions. This review highlights recent advancements in MXene-based catalysts, focusing on novel synthesis techniques, including selective etching, CVD and ALD, as well as advanced characterization methods such as XRD, Raman spectroscopy, TEM, FTIR, and In-situ/Operando techniques. Their applications in key catalytic processes, including the Fischer-Tropsch synthesis of hydrocarbons, CO₂ hydrogenation to methane, and hydrogen production via electrochemical water splitting, are discussed, as these reactions play a crucial role in carbon utilization, energy storage, and the transition to sustainable fuels. Notably, Mo₂C-based catalysts favor heavier hydrocarbon formation, while NiV oxycarbide electrocatalysts exhibit high durability and hydrogen selectivity. These findings emphasize MXenes’ potential in sustainable energy conversion and highlight the need for further optimization to enhance their catalytic efficiency and stability.
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publishDate 2025-08-01
publisher Elsevier
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series Carbon Trends
spelling doaj-art-3f052f29d5754e6bba4e00ef791dffa12025-08-20T02:57:35ZengElsevierCarbon Trends2667-05692025-08-012010055110.1016/j.cartre.2025.100551Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy productionNur-Sultan Mussa0Kydyr Askaruly1Kalampyr Bexeitova2Seitkhan Azat3Kainaubek Toshtay4Lille University, Lille, 59000, FranceLaboratory of Engineering Profile, Satbayev University, Almaty, KazakhstanLaboratory of Engineering Profile, Satbayev University, Almaty, KazakhstanLaboratory of Engineering Profile, Satbayev University, Almaty, KazakhstanLaboratory of Engineering Profile, Satbayev University, Almaty, Kazakhstan; Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, Almaty, 050040, Kazakhstan; Corresponding author.MXenes have emerged as promising two-dimensional (2D) materials for catalytic applications in energy production due to their exceptional structural, electronic, and chemical properties. Their high surface area, tunable surface terminations, and excellent electrical conductivity make them ideal candidates for facilitating surface reactions and enhancing charge transfer processes. Additionally, the ability to modify their composition and structure at the atomic level allows for the design of tailored MXene-based catalysts suited for various energy-related reactions. This review highlights recent advancements in MXene-based catalysts, focusing on novel synthesis techniques, including selective etching, CVD and ALD, as well as advanced characterization methods such as XRD, Raman spectroscopy, TEM, FTIR, and In-situ/Operando techniques. Their applications in key catalytic processes, including the Fischer-Tropsch synthesis of hydrocarbons, CO₂ hydrogenation to methane, and hydrogen production via electrochemical water splitting, are discussed, as these reactions play a crucial role in carbon utilization, energy storage, and the transition to sustainable fuels. Notably, Mo₂C-based catalysts favor heavier hydrocarbon formation, while NiV oxycarbide electrocatalysts exhibit high durability and hydrogen selectivity. These findings emphasize MXenes’ potential in sustainable energy conversion and highlight the need for further optimization to enhance their catalytic efficiency and stability.http://www.sciencedirect.com/science/article/pii/S2667056925001014Selective etchingTwo-dimensional materialsMXene-based catalystsHydrocarbon fuel
spellingShingle Nur-Sultan Mussa
Kydyr Askaruly
Kalampyr Bexeitova
Seitkhan Azat
Kainaubek Toshtay
Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production
Carbon Trends
Selective etching
Two-dimensional materials
MXene-based catalysts
Hydrocarbon fuel
title Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production
title_full Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production
title_fullStr Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production
title_full_unstemmed Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production
title_short Recent advancements in MXene-based catalysts: Synthesis, characterization, and applications in sustainable energy production
title_sort recent advancements in mxene based catalysts synthesis characterization and applications in sustainable energy production
topic Selective etching
Two-dimensional materials
MXene-based catalysts
Hydrocarbon fuel
url http://www.sciencedirect.com/science/article/pii/S2667056925001014
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AT kydyraskaruly recentadvancementsinmxenebasedcatalystssynthesischaracterizationandapplicationsinsustainableenergyproduction
AT kalampyrbexeitova recentadvancementsinmxenebasedcatalystssynthesischaracterizationandapplicationsinsustainableenergyproduction
AT seitkhanazat recentadvancementsinmxenebasedcatalystssynthesischaracterizationandapplicationsinsustainableenergyproduction
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