Nitride thin films grown by thermal laser epitaxy

The growth of a wide range of binary nitride films with excellent properties is reported. These films are deposited by thermal laser epitaxy (TLE). If equipped with CO2–laser substrate heating, TLE allows growth temperatures ≫ 1000 °C combined with strong nitriding conditions, which are established...

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Main Authors: Dong Yeong Kim, Varun Harbola, Seungwon Jung, Jinjoo Lee, Sukanya Roy, Felix V. E. Hensling, Lena N. Majer, Hongguang Wang, Peter A. van Aken, Joao Marcelo J. Lopes, Neha Aggarwal, Jochen Mannhart, Wolfgang Braun
Format: Article
Language:English
Published: AIP Publishing LLC 2025-01-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/5.0238169
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author Dong Yeong Kim
Varun Harbola
Seungwon Jung
Jinjoo Lee
Sukanya Roy
Felix V. E. Hensling
Lena N. Majer
Hongguang Wang
Peter A. van Aken
Joao Marcelo J. Lopes
Neha Aggarwal
Jochen Mannhart
Wolfgang Braun
author_facet Dong Yeong Kim
Varun Harbola
Seungwon Jung
Jinjoo Lee
Sukanya Roy
Felix V. E. Hensling
Lena N. Majer
Hongguang Wang
Peter A. van Aken
Joao Marcelo J. Lopes
Neha Aggarwal
Jochen Mannhart
Wolfgang Braun
author_sort Dong Yeong Kim
collection DOAJ
description The growth of a wide range of binary nitride films with excellent properties is reported. These films are deposited by thermal laser epitaxy (TLE). If equipped with CO2–laser substrate heating, TLE allows growth temperatures ≫ 1000 °C combined with strong nitriding conditions, which are established by using ammonia (NH3) gas as a nitrogen precursor. Films deposited on c-plane sapphire substrates include semiconducting nitrides (BN, AlN, ScN, and YN), superconducting nitrides (TiN, VN, ZrN, and NbN), and magnetic nitrides (CrN and GdN). The superconducting transition temperatures of TiN, VN, ZrN, and NbN films are 5.7, 8.9, 8.9, and 16.9 K, respectively. The Néel temperature of CrN films is ≃280 K, and the Curie temperature of GdN films is 66 K; both lie within the reported ranges. The controlled fabrication of different phases of individual nitride compounds is explored, revealing that subnitride phases can be grown at lower NH3 pressures. This study also demonstrates the heteroepitaxial growth of multilayer nitride films on c-plane sapphire.
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institution Kabale University
issn 2166-532X
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publisher AIP Publishing LLC
record_format Article
series APL Materials
spelling doaj-art-3ea405339fe846c3b92e231daedcad362025-02-03T16:42:31ZengAIP Publishing LLCAPL Materials2166-532X2025-01-01131011125011125-910.1063/5.0238169Nitride thin films grown by thermal laser epitaxyDong Yeong Kim0Varun Harbola1Seungwon Jung2Jinjoo Lee3Sukanya Roy4Felix V. E. Hensling5Lena N. Majer6Hongguang Wang7Peter A. van Aken8Joao Marcelo J. Lopes9Neha Aggarwal10Jochen Mannhart11Wolfgang Braun12Max Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyPaul-Drude-Institut für Festkörperelektronik, Leibniz-Institut im Forschungsverbund Berlin e.V., Hausvogteiplatz 5-7, 10117 Berlin, GermanyPaul-Drude-Institut für Festkörperelektronik, Leibniz-Institut im Forschungsverbund Berlin e.V., Hausvogteiplatz 5-7, 10117 Berlin, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, GermanyThe growth of a wide range of binary nitride films with excellent properties is reported. These films are deposited by thermal laser epitaxy (TLE). If equipped with CO2–laser substrate heating, TLE allows growth temperatures ≫ 1000 °C combined with strong nitriding conditions, which are established by using ammonia (NH3) gas as a nitrogen precursor. Films deposited on c-plane sapphire substrates include semiconducting nitrides (BN, AlN, ScN, and YN), superconducting nitrides (TiN, VN, ZrN, and NbN), and magnetic nitrides (CrN and GdN). The superconducting transition temperatures of TiN, VN, ZrN, and NbN films are 5.7, 8.9, 8.9, and 16.9 K, respectively. The Néel temperature of CrN films is ≃280 K, and the Curie temperature of GdN films is 66 K; both lie within the reported ranges. The controlled fabrication of different phases of individual nitride compounds is explored, revealing that subnitride phases can be grown at lower NH3 pressures. This study also demonstrates the heteroepitaxial growth of multilayer nitride films on c-plane sapphire.http://dx.doi.org/10.1063/5.0238169
spellingShingle Dong Yeong Kim
Varun Harbola
Seungwon Jung
Jinjoo Lee
Sukanya Roy
Felix V. E. Hensling
Lena N. Majer
Hongguang Wang
Peter A. van Aken
Joao Marcelo J. Lopes
Neha Aggarwal
Jochen Mannhart
Wolfgang Braun
Nitride thin films grown by thermal laser epitaxy
APL Materials
title Nitride thin films grown by thermal laser epitaxy
title_full Nitride thin films grown by thermal laser epitaxy
title_fullStr Nitride thin films grown by thermal laser epitaxy
title_full_unstemmed Nitride thin films grown by thermal laser epitaxy
title_short Nitride thin films grown by thermal laser epitaxy
title_sort nitride thin films grown by thermal laser epitaxy
url http://dx.doi.org/10.1063/5.0238169
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