UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue Gas
A wet de-NOx technique based on an UV-enhanced NaClO oxidation process was investigated for simulated flue gas of a diesel engine using a bench-scale reaction chamber. The effects of UV irradiation time, initial pH value, and available chlorine concentration of NaClO solution were studied, respectiv...
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| Format: | Article |
| Language: | English |
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Wiley
2016-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2016/6065019 |
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| author | Shao-long Yang Zhi-tao Han Jing-ming Dong Zi-sheng Zheng Xin-xiang Pan |
| author_facet | Shao-long Yang Zhi-tao Han Jing-ming Dong Zi-sheng Zheng Xin-xiang Pan |
| author_sort | Shao-long Yang |
| collection | DOAJ |
| description | A wet de-NOx technique based on an UV-enhanced NaClO oxidation process was investigated for simulated flue gas of a diesel engine using a bench-scale reaction chamber. The effects of UV irradiation time, initial pH value, and available chlorine concentration of NaClO solution were studied, respectively. The results showed that when the UV irradiation time was 17.5 min and the initial pH value of NaClO solution was 6, NO removal efficiency of UV/NaClO solution was increased by 19.6% compared with that of NaClO solution. Meanwhile, when the available chlorine concentration of NaClO solution decreased from 0.1 wt% to 0.05 wt%, the enhancement in NO removal efficiency of UV/NaClO solution increased from 19.6% to 24%, compared with that of NaClO solution. The reaction pathways of NaClO solution photolysis and NO removal by UV/NaClO process were preliminarily discussed. The results suggested that HOCl might be the most active species that released many UV-induced photooxidants through photolysis reactions, which played an important role in NO removal process. |
| format | Article |
| id | doaj-art-3e74f55dd6b84a49a10bd52ce42c9369 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-3e74f55dd6b84a49a10bd52ce42c93692025-02-03T01:22:28ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/60650196065019UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue GasShao-long Yang0Zhi-tao Han1Jing-ming Dong2Zi-sheng Zheng3Xin-xiang Pan4Marine Engineering College, Dalian Maritime University, Dalian 116026, ChinaMarine Engineering College, Dalian Maritime University, Dalian 116026, ChinaMarine Engineering College, Dalian Maritime University, Dalian 116026, ChinaMarine Engineering College, Dalian Maritime University, Dalian 116026, ChinaMarine Engineering College, Dalian Maritime University, Dalian 116026, ChinaA wet de-NOx technique based on an UV-enhanced NaClO oxidation process was investigated for simulated flue gas of a diesel engine using a bench-scale reaction chamber. The effects of UV irradiation time, initial pH value, and available chlorine concentration of NaClO solution were studied, respectively. The results showed that when the UV irradiation time was 17.5 min and the initial pH value of NaClO solution was 6, NO removal efficiency of UV/NaClO solution was increased by 19.6% compared with that of NaClO solution. Meanwhile, when the available chlorine concentration of NaClO solution decreased from 0.1 wt% to 0.05 wt%, the enhancement in NO removal efficiency of UV/NaClO solution increased from 19.6% to 24%, compared with that of NaClO solution. The reaction pathways of NaClO solution photolysis and NO removal by UV/NaClO process were preliminarily discussed. The results suggested that HOCl might be the most active species that released many UV-induced photooxidants through photolysis reactions, which played an important role in NO removal process.http://dx.doi.org/10.1155/2016/6065019 |
| spellingShingle | Shao-long Yang Zhi-tao Han Jing-ming Dong Zi-sheng Zheng Xin-xiang Pan UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue Gas Journal of Chemistry |
| title | UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue Gas |
| title_full | UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue Gas |
| title_fullStr | UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue Gas |
| title_full_unstemmed | UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue Gas |
| title_short | UV-Enhanced NaClO Oxidation of Nitric Oxide from Simulated Flue Gas |
| title_sort | uv enhanced naclo oxidation of nitric oxide from simulated flue gas |
| url | http://dx.doi.org/10.1155/2016/6065019 |
| work_keys_str_mv | AT shaolongyang uvenhancednaclooxidationofnitricoxidefromsimulatedfluegas AT zhitaohan uvenhancednaclooxidationofnitricoxidefromsimulatedfluegas AT jingmingdong uvenhancednaclooxidationofnitricoxidefromsimulatedfluegas AT zishengzheng uvenhancednaclooxidationofnitricoxidefromsimulatedfluegas AT xinxiangpan uvenhancednaclooxidationofnitricoxidefromsimulatedfluegas |