Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter State

Superhydrophobic coatings are beneficial for applications like self-cleaning, anti-corrosion, and drag reduction. In this study, we investigated the impact of surface geometry on the static, dynamic, and sliding contact angles in the Cassie–Baxter state. We used fluoro-silane-treated silicon micro-p...

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Main Authors: Talya Scheff, Florence Acha, Nathalia Diaz Armas, Joey L. Mead, Jinde Zhang
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Biomimetics
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Online Access:https://www.mdpi.com/2313-7673/10/1/20
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author Talya Scheff
Florence Acha
Nathalia Diaz Armas
Joey L. Mead
Jinde Zhang
author_facet Talya Scheff
Florence Acha
Nathalia Diaz Armas
Joey L. Mead
Jinde Zhang
author_sort Talya Scheff
collection DOAJ
description Superhydrophobic coatings are beneficial for applications like self-cleaning, anti-corrosion, and drag reduction. In this study, we investigated the impact of surface geometry on the static, dynamic, and sliding contact angles in the Cassie–Baxter state. We used fluoro-silane-treated silicon micro-post patterns fabricated via lithography as model surfaces. By varying the solid fraction (ϕ<sub>s</sub>), edge-to-edge spacing (L), and the shape and arrangement of the micro-posts, we examined how these geometric factors influence wetting behavior. Our results show that the solid fraction is the key factor affecting both dynamic and sliding angles, while changes in shape and arrangement had minimal impact. The Cassie–Baxter model accurately predicted receding angles but struggled to predict advancing angles. These insights can guide the development of coatings with enhanced superhydrophobic properties, tailored to achieve higher contact angles and customized for different environmental conditions.
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institution Kabale University
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publishDate 2025-01-01
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series Biomimetics
spelling doaj-art-3e367a594fd846e49e66e8d6cff6cdaf2025-01-24T13:24:37ZengMDPI AGBiomimetics2313-76732025-01-011012010.3390/biomimetics10010020Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter StateTalya Scheff0Florence Acha1Nathalia Diaz Armas2Joey L. Mead3Jinde Zhang4Department of Plastics Engineering, University of Massachusetts Lowell, Lowell, MA 01854, USADepartment of Plastics Engineering, University of Massachusetts Lowell, Lowell, MA 01854, USADepartment of Plastics Engineering, University of Massachusetts Lowell, Lowell, MA 01854, USADepartment of Plastics Engineering, University of Massachusetts Lowell, Lowell, MA 01854, USADepartment of Plastics Engineering, University of Massachusetts Lowell, Lowell, MA 01854, USASuperhydrophobic coatings are beneficial for applications like self-cleaning, anti-corrosion, and drag reduction. In this study, we investigated the impact of surface geometry on the static, dynamic, and sliding contact angles in the Cassie–Baxter state. We used fluoro-silane-treated silicon micro-post patterns fabricated via lithography as model surfaces. By varying the solid fraction (ϕ<sub>s</sub>), edge-to-edge spacing (L), and the shape and arrangement of the micro-posts, we examined how these geometric factors influence wetting behavior. Our results show that the solid fraction is the key factor affecting both dynamic and sliding angles, while changes in shape and arrangement had minimal impact. The Cassie–Baxter model accurately predicted receding angles but struggled to predict advancing angles. These insights can guide the development of coatings with enhanced superhydrophobic properties, tailored to achieve higher contact angles and customized for different environmental conditions.https://www.mdpi.com/2313-7673/10/1/20superhydrophobicitycontact angle hysteresis (CAH)Cassie–Baxter statesilicon micro-postssurface geometrydynamic wetting
spellingShingle Talya Scheff
Florence Acha
Nathalia Diaz Armas
Joey L. Mead
Jinde Zhang
Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter State
Biomimetics
superhydrophobicity
contact angle hysteresis (CAH)
Cassie–Baxter state
silicon micro-posts
surface geometry
dynamic wetting
title Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter State
title_full Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter State
title_fullStr Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter State
title_full_unstemmed Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter State
title_short Tuning Wetting Properties Through Surface Geometry in the Cassie–Baxter State
title_sort tuning wetting properties through surface geometry in the cassie baxter state
topic superhydrophobicity
contact angle hysteresis (CAH)
Cassie–Baxter state
silicon micro-posts
surface geometry
dynamic wetting
url https://www.mdpi.com/2313-7673/10/1/20
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