Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl Alcohol
Polyvinyl alcohol (PVA) films doped with erbium chloride (ErCl3) have been prepared by casting from their aqueous solutions. The structure of the doped samples as well as the interactions between the host PVA and Er+3 was investigated using FTIR spectroscopy. The optical measurement was recorded at...
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Language: | English |
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Wiley
2015-01-01
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Series: | Journal of Spectroscopy |
Online Access: | http://dx.doi.org/10.1155/2015/204867 |
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author | Taymour A. Hamdalla Taha A. Hanafy Ashraf E. Bekheet |
author_facet | Taymour A. Hamdalla Taha A. Hanafy Ashraf E. Bekheet |
author_sort | Taymour A. Hamdalla |
collection | DOAJ |
description | Polyvinyl alcohol (PVA) films doped with erbium chloride (ErCl3) have been prepared by casting from their aqueous solutions. The structure of the doped samples as well as the interactions between the host PVA and Er+3 was investigated using FTIR spectroscopy. The optical measurement was recorded at room temperature in the range from 200 nm to 2000 nm. FTIR measurements revealed that Er+3 forms complex configuration within the PVA structure. PVA doped with 9 wt% of ErCl3 exhibits energy gap and refractive index of 5.1 eV and 1.72, respectively. The effect of the doping increment of ErCl3 on the optical parameters has been discussed. |
format | Article |
id | doaj-art-3dfe81f2a2774d45b64f9aa99f688030 |
institution | Kabale University |
issn | 2314-4920 2314-4939 |
language | English |
publishDate | 2015-01-01 |
publisher | Wiley |
record_format | Article |
series | Journal of Spectroscopy |
spelling | doaj-art-3dfe81f2a2774d45b64f9aa99f6880302025-02-03T01:26:45ZengWileyJournal of Spectroscopy2314-49202314-49392015-01-01201510.1155/2015/204867204867Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl AlcoholTaymour A. Hamdalla0Taha A. Hanafy1Ashraf E. Bekheet2Physics Department, Faculty of Science, University of Tabuk, Tabuk 71451, Saudi ArabiaPhysics Department, Faculty of Science, University of Tabuk, Tabuk 71451, Saudi ArabiaPhysics Department, Faculty of Science, University of Tabuk, Tabuk 71451, Saudi ArabiaPolyvinyl alcohol (PVA) films doped with erbium chloride (ErCl3) have been prepared by casting from their aqueous solutions. The structure of the doped samples as well as the interactions between the host PVA and Er+3 was investigated using FTIR spectroscopy. The optical measurement was recorded at room temperature in the range from 200 nm to 2000 nm. FTIR measurements revealed that Er+3 forms complex configuration within the PVA structure. PVA doped with 9 wt% of ErCl3 exhibits energy gap and refractive index of 5.1 eV and 1.72, respectively. The effect of the doping increment of ErCl3 on the optical parameters has been discussed.http://dx.doi.org/10.1155/2015/204867 |
spellingShingle | Taymour A. Hamdalla Taha A. Hanafy Ashraf E. Bekheet Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl Alcohol Journal of Spectroscopy |
title | Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl Alcohol |
title_full | Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl Alcohol |
title_fullStr | Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl Alcohol |
title_full_unstemmed | Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl Alcohol |
title_short | Influence of Erbium Ions on the Optical and Structural Properties of Polyvinyl Alcohol |
title_sort | influence of erbium ions on the optical and structural properties of polyvinyl alcohol |
url | http://dx.doi.org/10.1155/2015/204867 |
work_keys_str_mv | AT taymourahamdalla influenceoferbiumionsontheopticalandstructuralpropertiesofpolyvinylalcohol AT tahaahanafy influenceoferbiumionsontheopticalandstructuralpropertiesofpolyvinylalcohol AT ashrafebekheet influenceoferbiumionsontheopticalandstructuralpropertiesofpolyvinylalcohol |