Assessing Pollution with Heavy Metals and Its Impact on Population Health

Pollution is one of the most important issues currently affecting the global population and environment. Therefore, determining the zones where stringent measures should be taken is necessary. In this study, Principal Component Analysis (PCA), Factor Analysis (FA), and t-distributed Stochastic Neigh...

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Main Authors: Youssef Saliba, Alina Bărbulescu
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Toxics
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Online Access:https://www.mdpi.com/2305-6304/13/1/52
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author Youssef Saliba
Alina Bărbulescu
author_facet Youssef Saliba
Alina Bărbulescu
author_sort Youssef Saliba
collection DOAJ
description Pollution is one of the most important issues currently affecting the global population and environment. Therefore, determining the zones where stringent measures should be taken is necessary. In this study, Principal Component Analysis (PCA), Factor Analysis (FA), and t-distributed Stochastic Neighbor Embedding (t-SNE) were utilized for dimensionality reduction and clustering of data series containing the concentration of 10 heavy metals collected at 14 locations. The Hazard Quotient (<i>HQ</i>) and Hazard Index (<i>HI</i>) were utilized to determine the non-carcinogenic risk to the population in the studied zones. The highest concentrations of metals in the samples were those of Fe, Zn, Mn, and Cr. PCA indicated that Fe and Zn (Co and Cd) had the highest contribution on the first (second) Principal Component (PC). FA showed that the three-factor model is adequate for explaining the variability of pollutant concentrations. The factor loadings revealed the strength of association between variables and factors, e.g., 0.97 for Zn, 0.83 for Cr, and 0.99 for Co. <i>HQ</i> for ingestion, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mrow><mi>H</mi><mi>Q</mi></mrow><mrow><mi>i</mi><mi>n</mi><mi>g</mi></mrow></msub><mo>,</mo></mrow></semantics></math></inline-formula> was the highest for Fe (between 6.10 × 10<sup>−5</sup> and 2.57 × 10<sup>−4</sup>). <i>HQ</i> for inhalation, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mrow><mi>H</mi><mi>Q</mi></mrow><mrow><mi>i</mi><mi>n</mi><mi>h</mi></mrow></msub></mrow></semantics></math></inline-formula>, was the biggest for Mn (from 1.41 × 10<sup>−3</sup> to 1.95 × 10<sup>−3</sup>). <i>HI</i> varied in the interval [0.172, 0.573], indicating the absence of a non-carcinogenic risk. However, since values above 0.5 were determined at four sites, continuous monitoring of the pollution in the sampling locations is necessary.
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spelling doaj-art-3df30b7633614aa198e276395fdf2ea42025-01-24T13:51:04ZengMDPI AGToxics2305-63042025-01-011315210.3390/toxics13010052Assessing Pollution with Heavy Metals and Its Impact on Population HealthYoussef Saliba0Alina Bărbulescu1Doctoral School, Technical University of Civil Engineering of Bucharest, 122-124 Bd. Lacul Tei, 020396 Bucharest, RomaniaDepartment of Civil Engineering, Transilvania University of Brașov, 5 Turnului Str., 500152 Brașov, RomaniaPollution is one of the most important issues currently affecting the global population and environment. Therefore, determining the zones where stringent measures should be taken is necessary. In this study, Principal Component Analysis (PCA), Factor Analysis (FA), and t-distributed Stochastic Neighbor Embedding (t-SNE) were utilized for dimensionality reduction and clustering of data series containing the concentration of 10 heavy metals collected at 14 locations. The Hazard Quotient (<i>HQ</i>) and Hazard Index (<i>HI</i>) were utilized to determine the non-carcinogenic risk to the population in the studied zones. The highest concentrations of metals in the samples were those of Fe, Zn, Mn, and Cr. PCA indicated that Fe and Zn (Co and Cd) had the highest contribution on the first (second) Principal Component (PC). FA showed that the three-factor model is adequate for explaining the variability of pollutant concentrations. The factor loadings revealed the strength of association between variables and factors, e.g., 0.97 for Zn, 0.83 for Cr, and 0.99 for Co. <i>HQ</i> for ingestion, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mrow><mi>H</mi><mi>Q</mi></mrow><mrow><mi>i</mi><mi>n</mi><mi>g</mi></mrow></msub><mo>,</mo></mrow></semantics></math></inline-formula> was the highest for Fe (between 6.10 × 10<sup>−5</sup> and 2.57 × 10<sup>−4</sup>). <i>HQ</i> for inhalation, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mrow><mi>H</mi><mi>Q</mi></mrow><mrow><mi>i</mi><mi>n</mi><mi>h</mi></mrow></msub></mrow></semantics></math></inline-formula>, was the biggest for Mn (from 1.41 × 10<sup>−3</sup> to 1.95 × 10<sup>−3</sup>). <i>HI</i> varied in the interval [0.172, 0.573], indicating the absence of a non-carcinogenic risk. However, since values above 0.5 were determined at four sites, continuous monitoring of the pollution in the sampling locations is necessary.https://www.mdpi.com/2305-6304/13/1/52multivariate analysispollution indicatorPCAt-SNEFA<i>HI</i>
spellingShingle Youssef Saliba
Alina Bărbulescu
Assessing Pollution with Heavy Metals and Its Impact on Population Health
Toxics
multivariate analysis
pollution indicator
PCA
t-SNE
FA
<i>HI</i>
title Assessing Pollution with Heavy Metals and Its Impact on Population Health
title_full Assessing Pollution with Heavy Metals and Its Impact on Population Health
title_fullStr Assessing Pollution with Heavy Metals and Its Impact on Population Health
title_full_unstemmed Assessing Pollution with Heavy Metals and Its Impact on Population Health
title_short Assessing Pollution with Heavy Metals and Its Impact on Population Health
title_sort assessing pollution with heavy metals and its impact on population health
topic multivariate analysis
pollution indicator
PCA
t-SNE
FA
<i>HI</i>
url https://www.mdpi.com/2305-6304/13/1/52
work_keys_str_mv AT youssefsaliba assessingpollutionwithheavymetalsanditsimpactonpopulationhealth
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