Rheological Properties of Cement Pastes with Multiwalled Carbon Nanotubes

The evaluation of rheological properties of cement systems is getting more relevant with growing interest to self-consolidating concrete (SCC), high-performance concrete (HPC) and ultrahigh-performance concrete (UHPC). The rheology models are a perspective tool to predict and manage the properties o...

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Main Authors: Gintautas Skripkiunas, Ekaterina Karpova, Irmantas Barauskas, Joana Bendoraitiene, Grigory Yakovlev
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/8963542
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author Gintautas Skripkiunas
Ekaterina Karpova
Irmantas Barauskas
Joana Bendoraitiene
Grigory Yakovlev
author_facet Gintautas Skripkiunas
Ekaterina Karpova
Irmantas Barauskas
Joana Bendoraitiene
Grigory Yakovlev
author_sort Gintautas Skripkiunas
collection DOAJ
description The evaluation of rheological properties of cement systems is getting more relevant with growing interest to self-consolidating concrete (SCC), high-performance concrete (HPC) and ultrahigh-performance concrete (UHPC). The rheology models are a perspective tool to predict and manage the properties of cement systems in the fresh and hardened state. The current research is focused on the rheological test of cement systems modified by multiwalled carbon nanotubes (MWCNT) dispersion with and without polycarboxylate ether (PCE). The content of dispersion with 1% concentration of MWCNT in cement pastes varied from 0.125 to 0.5% by weight of cement. The dosage of PCE was taken as 0.6% by weight of cement. The cement pastes were prepared based on Portland cement without mineral additives. The rheological test was carried out at 5, 30, 60, and 120 min after mixing of cement paste. The rheological test established that modification of cement pastes by MWCNT dispersion in dosage 0.25% leads to the decrease of yield stress by 30.7% and increase of plastic viscosity by 29.6%. The combined modification by PCE and MWCNT dispersion shows the decrease in plastic viscosity of cement pastes by 9.90% in dosage of MWCNT equal to 0.5% by weight of cement, reduction of water demand by 20% for the same workability, and decrease of yield stress till 0 Pa. It gives the ability to obtain the self-compacting mixtures. The cement pastes with and without MWCNT dispersion revealed the shear-thinning behavior during 120 min after mixing. The modification of cement pastes by PCE with and without MWCNT dispersion showed the shear-thickening behavior which remains during 120 min after mixing.
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publishDate 2018-01-01
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spelling doaj-art-3d5203f0c644436c8a9370884c12d3972025-02-03T06:11:26ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/89635428963542Rheological Properties of Cement Pastes with Multiwalled Carbon NanotubesGintautas Skripkiunas0Ekaterina Karpova1Irmantas Barauskas2Joana Bendoraitiene3Grigory Yakovlev4Department of Building Materials and Fire Safety, Vilnius Gediminas Technical University, Vilnius LT-10223, LithuaniaDepartment of Building Materials and Fire Safety, Vilnius Gediminas Technical University, Vilnius LT-10223, LithuaniaDepartment of Silicate Technology, Kaunas University of Technology, Kaunas LT-44249, LithuaniaDepartment of Polymer Chemistry and Technology, Kaunas University of Technology, Kaunas LT-44249, LithuaniaDepartment of Geo-Engineering and Construction Materials, Kalashnikov Izhevsk State Technical University, Izhevsk 426069, RussiaThe evaluation of rheological properties of cement systems is getting more relevant with growing interest to self-consolidating concrete (SCC), high-performance concrete (HPC) and ultrahigh-performance concrete (UHPC). The rheology models are a perspective tool to predict and manage the properties of cement systems in the fresh and hardened state. The current research is focused on the rheological test of cement systems modified by multiwalled carbon nanotubes (MWCNT) dispersion with and without polycarboxylate ether (PCE). The content of dispersion with 1% concentration of MWCNT in cement pastes varied from 0.125 to 0.5% by weight of cement. The dosage of PCE was taken as 0.6% by weight of cement. The cement pastes were prepared based on Portland cement without mineral additives. The rheological test was carried out at 5, 30, 60, and 120 min after mixing of cement paste. The rheological test established that modification of cement pastes by MWCNT dispersion in dosage 0.25% leads to the decrease of yield stress by 30.7% and increase of plastic viscosity by 29.6%. The combined modification by PCE and MWCNT dispersion shows the decrease in plastic viscosity of cement pastes by 9.90% in dosage of MWCNT equal to 0.5% by weight of cement, reduction of water demand by 20% for the same workability, and decrease of yield stress till 0 Pa. It gives the ability to obtain the self-compacting mixtures. The cement pastes with and without MWCNT dispersion revealed the shear-thinning behavior during 120 min after mixing. The modification of cement pastes by PCE with and without MWCNT dispersion showed the shear-thickening behavior which remains during 120 min after mixing.http://dx.doi.org/10.1155/2018/8963542
spellingShingle Gintautas Skripkiunas
Ekaterina Karpova
Irmantas Barauskas
Joana Bendoraitiene
Grigory Yakovlev
Rheological Properties of Cement Pastes with Multiwalled Carbon Nanotubes
Advances in Materials Science and Engineering
title Rheological Properties of Cement Pastes with Multiwalled Carbon Nanotubes
title_full Rheological Properties of Cement Pastes with Multiwalled Carbon Nanotubes
title_fullStr Rheological Properties of Cement Pastes with Multiwalled Carbon Nanotubes
title_full_unstemmed Rheological Properties of Cement Pastes with Multiwalled Carbon Nanotubes
title_short Rheological Properties of Cement Pastes with Multiwalled Carbon Nanotubes
title_sort rheological properties of cement pastes with multiwalled carbon nanotubes
url http://dx.doi.org/10.1155/2018/8963542
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AT joanabendoraitiene rheologicalpropertiesofcementpasteswithmultiwalledcarbonnanotubes
AT grigoryyakovlev rheologicalpropertiesofcementpasteswithmultiwalledcarbonnanotubes