Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous
A synthetic method based on the postfunctionalization of a reactive homopolymer precursor, which allows for the preparation of different copolymers derived from poly(3-alkylthiophene), was studied. Although these groups decrease the solubility of the resultant material, they enable controlling the d...
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| Format: | Article |
| Language: | English |
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Wiley
2009-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2009/974307 |
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| author | F. R. Díaz-Alzamora M. A. del Valle C. M. Núñez P. P. Zamora J. P. Soto J. C. Bernède |
| author_facet | F. R. Díaz-Alzamora M. A. del Valle C. M. Núñez P. P. Zamora J. P. Soto J. C. Bernède |
| author_sort | F. R. Díaz-Alzamora |
| collection | DOAJ |
| description | A synthetic method based on the postfunctionalization of a reactive homopolymer precursor, which allows for the preparation of different copolymers derived from poly(3-alkylthiophene), was studied. Although these groups decrease the solubility of the resultant material, they enable controlling the degree of substitution to obtain a material with improved spectroscopic (absorption and emission) properties making them useful for the fabrication of electronic devices, for example, solar cells and light-emitting diodes. Furthermore, a comparative study of two halogenated (Cl and Br) reactive poly(3-ω-haloalkyl)thiophenes was carried out. |
| format | Article |
| id | doaj-art-3d1c47ca04a643239f6528ec3229fd92 |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-3d1c47ca04a643239f6528ec3229fd922025-02-03T01:26:49ZengWileyInternational Journal of Polymer Science1687-94221687-94302009-01-01200910.1155/2009/974307974307Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated AnalogousF. R. Díaz-Alzamora0M. A. del Valle1C. M. Núñez2P. P. Zamora3J. P. Soto4J. C. Bernède5Laboratorio de Polímeros, Facultad de Química, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, Macul, Santiago, ChileLaboratorio de Polímeros, Facultad de Química, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, Macul, Santiago, ChileLaboratorio de Polímeros, Facultad de Química, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, Macul, Santiago, ChileLaboratorio de Polímeros, Facultad de Química, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, Macul, Santiago, ChileLaboratorio de Polímeros, Facultad de Química, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, Macul, Santiago, ChileFaculté des Sciences et dês Techniques, Universite de Nantes Atlantique, LAMP, EA 3829, 2 rue de la Houssieniere, BP 922098, 44000 Nantes, FranceA synthetic method based on the postfunctionalization of a reactive homopolymer precursor, which allows for the preparation of different copolymers derived from poly(3-alkylthiophene), was studied. Although these groups decrease the solubility of the resultant material, they enable controlling the degree of substitution to obtain a material with improved spectroscopic (absorption and emission) properties making them useful for the fabrication of electronic devices, for example, solar cells and light-emitting diodes. Furthermore, a comparative study of two halogenated (Cl and Br) reactive poly(3-ω-haloalkyl)thiophenes was carried out.http://dx.doi.org/10.1155/2009/974307 |
| spellingShingle | F. R. Díaz-Alzamora M. A. del Valle C. M. Núñez P. P. Zamora J. P. Soto J. C. Bernède Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous International Journal of Polymer Science |
| title | Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous |
| title_full | Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous |
| title_fullStr | Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous |
| title_full_unstemmed | Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous |
| title_short | Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous |
| title_sort | synthesis of poly 3 6 9 anthracenylmethoxy hexyl thiophene co 3 6 bromohexyl thiophene postfunctionalized from poly 3 6 bromohexyl thiophene a comparative study of the base polymer with its chlorinated analogous |
| url | http://dx.doi.org/10.1155/2009/974307 |
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