Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil Shale
ABSTRACT A novel composite catalyst with readily preparation and good catalytic performance was designed and synthesized using sulfonation‐modified zeolite socony mobil‐5 (ZSM‐5) as the carrier and nano‐CoO/NiO as the active components. Compared with traditional in situ conversion, the composite cat...
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| Format: | Article |
| Language: | English |
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Wiley
2025-01-01
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| Series: | Energy Science & Engineering |
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| Online Access: | https://doi.org/10.1002/ese3.2007 |
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| author | Aibin Wu Junwen Wu Liu Chen Jianzheng Su Weichu Yu |
| author_facet | Aibin Wu Junwen Wu Liu Chen Jianzheng Su Weichu Yu |
| author_sort | Aibin Wu |
| collection | DOAJ |
| description | ABSTRACT A novel composite catalyst with readily preparation and good catalytic performance was designed and synthesized using sulfonation‐modified zeolite socony mobil‐5 (ZSM‐5) as the carrier and nano‐CoO/NiO as the active components. Compared with traditional in situ conversion, the composite catalyst could effectively reduce the activation energy of catalytic reactions, improve the efficiency of oil and gas conversion, and ameliorate the quality of oil products. When the loading amount of nano‐CoO/NiO was 20 wt% and the silicon/aluminum ratio of ZSM‐5 was 40–50, the required activation energy for oil shale cracking was as low as 43.64 kJ/mol, the yield of oil products was as high as 15.46 wt%, and the content of organic compounds in medium‐/low‐carbon hydrocarbon was as high as 71.50%. The prepared composite catalysts had low preparation cost, environmental friendliness, and significant catalytic effects, providing a feasible approach for the effective exploitation and utilization of oil shale. |
| format | Article |
| id | doaj-art-3cfd6e706ff1448e8ff9e9570f2fcdf8 |
| institution | Kabale University |
| issn | 2050-0505 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Energy Science & Engineering |
| spelling | doaj-art-3cfd6e706ff1448e8ff9e9570f2fcdf82025-01-21T11:38:24ZengWileyEnergy Science & Engineering2050-05052025-01-0113133534310.1002/ese3.2007Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil ShaleAibin Wu0Junwen Wu1Liu Chen2Jianzheng Su3Weichu Yu4State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing ChinaState Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing ChinaSchool of Chemistry and Environmental Engineering Yangtze University Jingzhou Hubei ChinaState Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing ChinaSchool of Chemistry and Environmental Engineering Yangtze University Jingzhou Hubei ChinaABSTRACT A novel composite catalyst with readily preparation and good catalytic performance was designed and synthesized using sulfonation‐modified zeolite socony mobil‐5 (ZSM‐5) as the carrier and nano‐CoO/NiO as the active components. Compared with traditional in situ conversion, the composite catalyst could effectively reduce the activation energy of catalytic reactions, improve the efficiency of oil and gas conversion, and ameliorate the quality of oil products. When the loading amount of nano‐CoO/NiO was 20 wt% and the silicon/aluminum ratio of ZSM‐5 was 40–50, the required activation energy for oil shale cracking was as low as 43.64 kJ/mol, the yield of oil products was as high as 15.46 wt%, and the content of organic compounds in medium‐/low‐carbon hydrocarbon was as high as 71.50%. The prepared composite catalysts had low preparation cost, environmental friendliness, and significant catalytic effects, providing a feasible approach for the effective exploitation and utilization of oil shale.https://doi.org/10.1002/ese3.2007catalystCoOin situ conversionNiOoil shalesulfonation‐modified ZSM‐5 |
| spellingShingle | Aibin Wu Junwen Wu Liu Chen Jianzheng Su Weichu Yu Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil Shale Energy Science & Engineering catalyst CoO in situ conversion NiO oil shale sulfonation‐modified ZSM‐5 |
| title | Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil Shale |
| title_full | Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil Shale |
| title_fullStr | Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil Shale |
| title_full_unstemmed | Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil Shale |
| title_short | Design, Synthesis, and Performance of Novel Nano‐CoO/NiO‐loaded and Sulfonation‐Modified ZSM‐5 Composite Catalyst for In Situ Conversion of Oil Shale |
| title_sort | design synthesis and performance of novel nano coo nio loaded and sulfonation modified zsm 5 composite catalyst for in situ conversion of oil shale |
| topic | catalyst CoO in situ conversion NiO oil shale sulfonation‐modified ZSM‐5 |
| url | https://doi.org/10.1002/ese3.2007 |
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