Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution
A mesoporous silica loaded with molybdenum phosphide nanoparticles (MoP@MSN) was synthesized using Pluronic F-127 as a hard template. Using the method of XRD and HRTEM, the crystallinity, the phase structure, and the morphologies of the MoP@MSN were investigated. The results showed that the MoP@MSN...
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Wiley
2018-01-01
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Series: | Advances in Materials Science and Engineering |
Online Access: | http://dx.doi.org/10.1155/2018/2940601 |
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author | Keliang Wang Chan Jiang Zhouyang Chen Shaojie Ma |
author_facet | Keliang Wang Chan Jiang Zhouyang Chen Shaojie Ma |
author_sort | Keliang Wang |
collection | DOAJ |
description | A mesoporous silica loaded with molybdenum phosphide nanoparticles (MoP@MSN) was synthesized using Pluronic F-127 as a hard template. Using the method of XRD and HRTEM, the crystallinity, the phase structure, and the morphologies of the MoP@MSN were investigated. The results showed that the MoP@MSN were composed of nanoflakes with approximately 100 nm. Through the linear sweep voltammetry (LSV), the Tafel slopes of 100 and 341 mV were yielded for MoP@MSN and pure MoP, respectively, meaning that the composite of MSN can significantly improve the conductivity of the products. Meanwhile, the mesoporous MoP@MSN presented excellent electrochemical activity and stability toward hydrogen evolution compared with those of bulk MoP nanoparticles, showing a promising prospect in hydrogen production. |
format | Article |
id | doaj-art-39e8263699e943619630ef88f6a6fdff |
institution | Kabale University |
issn | 1687-8434 1687-8442 |
language | English |
publishDate | 2018-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Materials Science and Engineering |
spelling | doaj-art-39e8263699e943619630ef88f6a6fdff2025-02-03T01:12:39ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/29406012940601Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen EvolutionKeliang Wang0Chan Jiang1Zhouyang Chen2Shaojie Ma3Guangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaGuangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaGuangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaGuangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaA mesoporous silica loaded with molybdenum phosphide nanoparticles (MoP@MSN) was synthesized using Pluronic F-127 as a hard template. Using the method of XRD and HRTEM, the crystallinity, the phase structure, and the morphologies of the MoP@MSN were investigated. The results showed that the MoP@MSN were composed of nanoflakes with approximately 100 nm. Through the linear sweep voltammetry (LSV), the Tafel slopes of 100 and 341 mV were yielded for MoP@MSN and pure MoP, respectively, meaning that the composite of MSN can significantly improve the conductivity of the products. Meanwhile, the mesoporous MoP@MSN presented excellent electrochemical activity and stability toward hydrogen evolution compared with those of bulk MoP nanoparticles, showing a promising prospect in hydrogen production.http://dx.doi.org/10.1155/2018/2940601 |
spellingShingle | Keliang Wang Chan Jiang Zhouyang Chen Shaojie Ma Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution Advances in Materials Science and Engineering |
title | Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution |
title_full | Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution |
title_fullStr | Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution |
title_full_unstemmed | Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution |
title_short | Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution |
title_sort | mesoporous silica loaded with molybdenum phosphide nanoparticles for hydrogen evolution |
url | http://dx.doi.org/10.1155/2018/2940601 |
work_keys_str_mv | AT keliangwang mesoporoussilicaloadedwithmolybdenumphosphidenanoparticlesforhydrogenevolution AT chanjiang mesoporoussilicaloadedwithmolybdenumphosphidenanoparticlesforhydrogenevolution AT zhouyangchen mesoporoussilicaloadedwithmolybdenumphosphidenanoparticlesforhydrogenevolution AT shaojiema mesoporoussilicaloadedwithmolybdenumphosphidenanoparticlesforhydrogenevolution |