Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution

A mesoporous silica loaded with molybdenum phosphide nanoparticles (MoP@MSN) was synthesized using Pluronic F-127 as a hard template. Using the method of XRD and HRTEM, the crystallinity, the phase structure, and the morphologies of the MoP@MSN were investigated. The results showed that the MoP@MSN...

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Main Authors: Keliang Wang, Chan Jiang, Zhouyang Chen, Shaojie Ma
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/2940601
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author Keliang Wang
Chan Jiang
Zhouyang Chen
Shaojie Ma
author_facet Keliang Wang
Chan Jiang
Zhouyang Chen
Shaojie Ma
author_sort Keliang Wang
collection DOAJ
description A mesoporous silica loaded with molybdenum phosphide nanoparticles (MoP@MSN) was synthesized using Pluronic F-127 as a hard template. Using the method of XRD and HRTEM, the crystallinity, the phase structure, and the morphologies of the MoP@MSN were investigated. The results showed that the MoP@MSN were composed of nanoflakes with approximately 100 nm. Through the linear sweep voltammetry (LSV), the Tafel slopes of 100 and 341 mV were yielded for MoP@MSN and pure MoP, respectively, meaning that the composite of MSN can significantly improve the conductivity of the products. Meanwhile, the mesoporous MoP@MSN presented excellent electrochemical activity and stability toward hydrogen evolution compared with those of bulk MoP nanoparticles, showing a promising prospect in hydrogen production.
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institution Kabale University
issn 1687-8434
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language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-39e8263699e943619630ef88f6a6fdff2025-02-03T01:12:39ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/29406012940601Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen EvolutionKeliang Wang0Chan Jiang1Zhouyang Chen2Shaojie Ma3Guangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaGuangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaGuangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaGuangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, ChinaA mesoporous silica loaded with molybdenum phosphide nanoparticles (MoP@MSN) was synthesized using Pluronic F-127 as a hard template. Using the method of XRD and HRTEM, the crystallinity, the phase structure, and the morphologies of the MoP@MSN were investigated. The results showed that the MoP@MSN were composed of nanoflakes with approximately 100 nm. Through the linear sweep voltammetry (LSV), the Tafel slopes of 100 and 341 mV were yielded for MoP@MSN and pure MoP, respectively, meaning that the composite of MSN can significantly improve the conductivity of the products. Meanwhile, the mesoporous MoP@MSN presented excellent electrochemical activity and stability toward hydrogen evolution compared with those of bulk MoP nanoparticles, showing a promising prospect in hydrogen production.http://dx.doi.org/10.1155/2018/2940601
spellingShingle Keliang Wang
Chan Jiang
Zhouyang Chen
Shaojie Ma
Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution
Advances in Materials Science and Engineering
title Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution
title_full Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution
title_fullStr Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution
title_full_unstemmed Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution
title_short Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution
title_sort mesoporous silica loaded with molybdenum phosphide nanoparticles for hydrogen evolution
url http://dx.doi.org/10.1155/2018/2940601
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AT chanjiang mesoporoussilicaloadedwithmolybdenumphosphidenanoparticlesforhydrogenevolution
AT zhouyangchen mesoporoussilicaloadedwithmolybdenumphosphidenanoparticlesforhydrogenevolution
AT shaojiema mesoporoussilicaloadedwithmolybdenumphosphidenanoparticlesforhydrogenevolution