Energy Analysis in Combined Reforming of Propane

Combined (steam and CO2) reforming is one of the methods to produce syngas for different applications. An energy requirement analysis of steam reforming to dry reforming with intermediate steps of steam reduction and equivalent CO2 addition to the feed fuel for syngas generation has been done to ide...

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Main Authors: K. Moon, Ganesh R. Kale
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Engineering
Online Access:http://dx.doi.org/10.1155/2013/301265
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author K. Moon
Ganesh R. Kale
author_facet K. Moon
Ganesh R. Kale
author_sort K. Moon
collection DOAJ
description Combined (steam and CO2) reforming is one of the methods to produce syngas for different applications. An energy requirement analysis of steam reforming to dry reforming with intermediate steps of steam reduction and equivalent CO2 addition to the feed fuel for syngas generation has been done to identify condition for optimum process operation. Thermodynamic equilibrium data for combined reforming was generated for temperature range of 400–1000°C at 1 bar pressure and combined oxidant (CO2 + H2O) stream to propane (fuel) ratio of 3, 6, and 9 by employing the Gibbs free energy minimization algorithm of HSC Chemistry software 5.1. Total energy requirement including preheating and reaction enthalpy calculations were done using the equilibrium product composition. Carbon and methane formation was significantly reduced in combined reforming than pure dry reforming, while the energy requirements were lower than pure steam reforming. Temperatures of minimum energy requirement were found in the data analysis of combined reforming which were optimum for the process.
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institution Kabale University
issn 2314-4904
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publishDate 2013-01-01
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spelling doaj-art-3925854fd70843e8a4c598f558a7813e2025-02-03T01:02:51ZengWileyJournal of Engineering2314-49042314-49122013-01-01201310.1155/2013/301265301265Energy Analysis in Combined Reforming of PropaneK. Moon0Ganesh R. Kale1CEPD Division, National Chemical Laboratory, Pune 411008, IndiaCEPD Division, National Chemical Laboratory, Pune 411008, IndiaCombined (steam and CO2) reforming is one of the methods to produce syngas for different applications. An energy requirement analysis of steam reforming to dry reforming with intermediate steps of steam reduction and equivalent CO2 addition to the feed fuel for syngas generation has been done to identify condition for optimum process operation. Thermodynamic equilibrium data for combined reforming was generated for temperature range of 400–1000°C at 1 bar pressure and combined oxidant (CO2 + H2O) stream to propane (fuel) ratio of 3, 6, and 9 by employing the Gibbs free energy minimization algorithm of HSC Chemistry software 5.1. Total energy requirement including preheating and reaction enthalpy calculations were done using the equilibrium product composition. Carbon and methane formation was significantly reduced in combined reforming than pure dry reforming, while the energy requirements were lower than pure steam reforming. Temperatures of minimum energy requirement were found in the data analysis of combined reforming which were optimum for the process.http://dx.doi.org/10.1155/2013/301265
spellingShingle K. Moon
Ganesh R. Kale
Energy Analysis in Combined Reforming of Propane
Journal of Engineering
title Energy Analysis in Combined Reforming of Propane
title_full Energy Analysis in Combined Reforming of Propane
title_fullStr Energy Analysis in Combined Reforming of Propane
title_full_unstemmed Energy Analysis in Combined Reforming of Propane
title_short Energy Analysis in Combined Reforming of Propane
title_sort energy analysis in combined reforming of propane
url http://dx.doi.org/10.1155/2013/301265
work_keys_str_mv AT kmoon energyanalysisincombinedreformingofpropane
AT ganeshrkale energyanalysisincombinedreformingofpropane