Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, China

Sound management of contaminated sites, particularly former manufacturing sites with potential heavy contamination, is crucial for the Parties to implement the Stockholm Convention on Persistent Organic Pollutants (POPs). Unfortunately, numerous former manufacturing sites in developing countries hav...

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Main Authors: Yiming Jiang, Ning Fang, Qiang Chen, Tao Long, Roland Weber, Jun Huang
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-06-01
Series:Emerging Contaminants
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Online Access:http://www.sciencedirect.com/science/article/pii/S2405665025000071
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author Yiming Jiang
Ning Fang
Qiang Chen
Tao Long
Roland Weber
Jun Huang
author_facet Yiming Jiang
Ning Fang
Qiang Chen
Tao Long
Roland Weber
Jun Huang
author_sort Yiming Jiang
collection DOAJ
description Sound management of contaminated sites, particularly former manufacturing sites with potential heavy contamination, is crucial for the Parties to implement the Stockholm Convention on Persistent Organic Pollutants (POPs). Unfortunately, numerous former manufacturing sites in developing countries have not been well investigated, especially for those associated with newly listed POPs such as perfluorooctane sulfonate (PFOS). Following 3M's voluntary phase-out plan in 2002, China emerged as the primary producer of PFOS and ceased production in 2021. However, little information is available about the contamination levels at these former PFOS production sites. This study focused on five specific sites located in Hubei, China. Soil and groundwater samples, both on-site and off-site, were collected for PFOS analysis. Concentrations ranging from 392 μg/kg to 7.78 × 105 μg/kg in on-site soil, 5.05 μg/kg to 83.2 μg/kg in off-site soil, and 84.1 μg/L to 1.74 × 103 μg/L in groundwater samples were found, respectively. By employing current national standards in China (i.e. GB 36600-2018 and HJ 25.3–2019), PFOS screening and management levels were established for risk assessment purposes. Preliminary risk assessments showed that 34 % and 100 % of the sampling points would pose unacceptable risks when evaluated using two distinct PFOS characteristic databases. The results highlight the significant health risk caused by PFOS at former production sites as well as the urgent need for regulatory interventions.
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spelling doaj-art-386aaea45d26418eafd2cfda9e310c802025-01-24T04:45:25ZengKeAi Communications Co., Ltd.Emerging Contaminants2405-66502025-06-01112100473Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, ChinaYiming Jiang0Ning Fang1Qiang Chen2Tao Long3Roland Weber4Jun Huang5State Key Joint Laboratory of Environment Simulation and Pollution Control (SKJLESPC), Beijing Laboratory of Environmental Frontier Technologies (BLEFT), Beijing Key Laboratory for Emerging Organic Contaminants Control (BKLEOC), School of Environment, Tsinghua University, Beijing, 100084, ChinaState Key Joint Laboratory of Environment Simulation and Pollution Control (SKJLESPC), Beijing Laboratory of Environmental Frontier Technologies (BLEFT), Beijing Key Laboratory for Emerging Organic Contaminants Control (BKLEOC), School of Environment, Tsinghua University, Beijing, 100084, ChinaState Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of China, Nanjing, 210042, Jiangsu, ChinaState Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of China, Nanjing, 210042, Jiangsu, ChinaPOPs Environmental Consulting, Lindenfrststr. 23, 73527, Schwäbisch Gmünd, GermanyState Key Joint Laboratory of Environment Simulation and Pollution Control (SKJLESPC), Beijing Laboratory of Environmental Frontier Technologies (BLEFT), Beijing Key Laboratory for Emerging Organic Contaminants Control (BKLEOC), School of Environment, Tsinghua University, Beijing, 100084, China; Corresponding author.Sound management of contaminated sites, particularly former manufacturing sites with potential heavy contamination, is crucial for the Parties to implement the Stockholm Convention on Persistent Organic Pollutants (POPs). Unfortunately, numerous former manufacturing sites in developing countries have not been well investigated, especially for those associated with newly listed POPs such as perfluorooctane sulfonate (PFOS). Following 3M's voluntary phase-out plan in 2002, China emerged as the primary producer of PFOS and ceased production in 2021. However, little information is available about the contamination levels at these former PFOS production sites. This study focused on five specific sites located in Hubei, China. Soil and groundwater samples, both on-site and off-site, were collected for PFOS analysis. Concentrations ranging from 392 μg/kg to 7.78 × 105 μg/kg in on-site soil, 5.05 μg/kg to 83.2 μg/kg in off-site soil, and 84.1 μg/L to 1.74 × 103 μg/L in groundwater samples were found, respectively. By employing current national standards in China (i.e. GB 36600-2018 and HJ 25.3–2019), PFOS screening and management levels were established for risk assessment purposes. Preliminary risk assessments showed that 34 % and 100 % of the sampling points would pose unacceptable risks when evaluated using two distinct PFOS characteristic databases. The results highlight the significant health risk caused by PFOS at former production sites as well as the urgent need for regulatory interventions.http://www.sciencedirect.com/science/article/pii/S2405665025000071PFOSGuideline valuesFormer manufacturing siteRisk assessment
spellingShingle Yiming Jiang
Ning Fang
Qiang Chen
Tao Long
Roland Weber
Jun Huang
Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, China
Emerging Contaminants
PFOS
Guideline values
Former manufacturing site
Risk assessment
title Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, China
title_full Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, China
title_fullStr Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, China
title_full_unstemmed Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, China
title_short Preliminary risk assessment of PFOS in former production sites: A case study in Hubei, China
title_sort preliminary risk assessment of pfos in former production sites a case study in hubei china
topic PFOS
Guideline values
Former manufacturing site
Risk assessment
url http://www.sciencedirect.com/science/article/pii/S2405665025000071
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