Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used
The dependence of magnetic transition on the treatment solution used in the preparation of magnetic nanoparticles was investigated using as-prepared products from paramagnetic FeOOH/Mg(OH)2 via a chemically induced transition. Treatment using FeCl3 and CuCl solutions led to a product that showed no...
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| Format: | Article |
| Language: | English |
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Wiley
2016-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2016/7604748 |
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| author | Yanshuang Chen Qin Chen Hong Mao Yueqiang Lin Jian Li |
| author_facet | Yanshuang Chen Qin Chen Hong Mao Yueqiang Lin Jian Li |
| author_sort | Yanshuang Chen |
| collection | DOAJ |
| description | The dependence of magnetic transition on the treatment solution used in the preparation of magnetic nanoparticles was investigated using as-prepared products from paramagnetic FeOOH/Mg(OH)2 via a chemically induced transition. Treatment using FeCl3 and CuCl solutions led to a product that showed no magnetic transition, whereas the product after treatment with FeSO4 or FeCl2 solutions showed ferromagnetism. Experiments revealed that the magnetism was caused by the ferrimagnetic γ-Fe2O3 phase in the nanoparticles, which had a coating of ferric compound. This observation suggests that Fe2+ in the treatment solution underwent oxidation to Fe3+, thereby inducing the magnetic transition. The magnetic nanoparticles prepared via treatment with an FeSO4 solution contained a larger amount of the nonmagnetic phase. This resulted in weaker magnetization even though these nanoparticles were larger than those prepared by treatment with an FeCl2 solution. The magnetic transition of the precursor (FeOOH/Mg(OH)2) was dependent upon treatment solutions and was essentially induced by the oxidation of Fe2+ and simultaneous dehydration of FeOOH phase. The transition was independent of the acid radical ions in the treatment solution, but the coating on the magnetic crystallites varied with changes in the acid radical ion. |
| format | Article |
| id | doaj-art-38371009aa214e8d921321f980ff7dbb |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-38371009aa214e8d921321f980ff7dbb2025-02-03T07:24:35ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/76047487604748Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution UsedYanshuang Chen0Qin Chen1Hong Mao2Yueqiang Lin3Jian Li4School of Physical Science and Technology, Southwest University, Chongqing 400715, ChinaSchool of Physical Science and Technology, Southwest University, Chongqing 400715, ChinaSchool of Physical Science and Technology, Southwest University, Chongqing 400715, ChinaSchool of Physical Science and Technology, Southwest University, Chongqing 400715, ChinaSchool of Physical Science and Technology, Southwest University, Chongqing 400715, ChinaThe dependence of magnetic transition on the treatment solution used in the preparation of magnetic nanoparticles was investigated using as-prepared products from paramagnetic FeOOH/Mg(OH)2 via a chemically induced transition. Treatment using FeCl3 and CuCl solutions led to a product that showed no magnetic transition, whereas the product after treatment with FeSO4 or FeCl2 solutions showed ferromagnetism. Experiments revealed that the magnetism was caused by the ferrimagnetic γ-Fe2O3 phase in the nanoparticles, which had a coating of ferric compound. This observation suggests that Fe2+ in the treatment solution underwent oxidation to Fe3+, thereby inducing the magnetic transition. The magnetic nanoparticles prepared via treatment with an FeSO4 solution contained a larger amount of the nonmagnetic phase. This resulted in weaker magnetization even though these nanoparticles were larger than those prepared by treatment with an FeCl2 solution. The magnetic transition of the precursor (FeOOH/Mg(OH)2) was dependent upon treatment solutions and was essentially induced by the oxidation of Fe2+ and simultaneous dehydration of FeOOH phase. The transition was independent of the acid radical ions in the treatment solution, but the coating on the magnetic crystallites varied with changes in the acid radical ion.http://dx.doi.org/10.1155/2016/7604748 |
| spellingShingle | Yanshuang Chen Qin Chen Hong Mao Yueqiang Lin Jian Li Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used Journal of Chemistry |
| title | Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used |
| title_full | Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used |
| title_fullStr | Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used |
| title_full_unstemmed | Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used |
| title_short | Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used |
| title_sort | preparation of magnetic nanoparticles via a chemically induced transition presence absence of magnetic transition on the treatment solution used |
| url | http://dx.doi.org/10.1155/2016/7604748 |
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