Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar Derivative
The synthesis of 5,6-O-isopropylidene-1,2-O-(R)-trichloroethylidene-α-D-glucofuranose (compound 1) and 5,6-O-isopropylidene-1,2-O-(R)-trichloroethylidene-3-O-(2′,3′-epoxypropan-1′-yl)-α-D-glucofuranose (compound 2) was carried out. The synthesized compounds 1 and 2 were characterized by nuclear magn...
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2014/737953 |
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| author | Selinay Y. Erişkin Fatma Ç. Telli Yeliz Yıldırım Yeşim Salman |
| author_facet | Selinay Y. Erişkin Fatma Ç. Telli Yeliz Yıldırım Yeşim Salman |
| author_sort | Selinay Y. Erişkin |
| collection | DOAJ |
| description | The synthesis of 5,6-O-isopropylidene-1,2-O-(R)-trichloroethylidene-α-D-glucofuranose (compound 1) and 5,6-O-isopropylidene-1,2-O-(R)-trichloroethylidene-3-O-(2′,3′-epoxypropan-1′-yl)-α-D-glucofuranose (compound 2) was carried out. The synthesized compounds 1 and 2 were characterized by nuclear magnetic resonance (1H-NMR), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TG). The FTIR and 1H NMR spectra showed that the epoxy group in compound 2 was attached by means of a nucleophilic substitution reaction. The activation energies for thermal degradation of compounds 1 and 2 were calculated from their TG data by using the Kissinger-Akahira-Sunose (KAS) and Tang methods. |
| format | Article |
| id | doaj-art-365ed6d15ba84577aebbbe734f84df63 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-365ed6d15ba84577aebbbe734f84df632025-02-03T05:59:21ZengWileyJournal of Chemistry2090-90632090-90712014-01-01201410.1155/2014/737953737953Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar DerivativeSelinay Y. Erişkin0Fatma Ç. Telli1Yeliz Yıldırım2Yeşim Salman3Department of Chemistry, Faculty of Science, Ege University, Bornova, 35100, İzmir, TurkeyDepartment of Chemistry, Faculty of Science, Ege University, Bornova, 35100, İzmir, TurkeyDepartment of Chemistry, Faculty of Science, Ege University, Bornova, 35100, İzmir, TurkeyDepartment of Chemistry, Faculty of Science, Ege University, Bornova, 35100, İzmir, TurkeyThe synthesis of 5,6-O-isopropylidene-1,2-O-(R)-trichloroethylidene-α-D-glucofuranose (compound 1) and 5,6-O-isopropylidene-1,2-O-(R)-trichloroethylidene-3-O-(2′,3′-epoxypropan-1′-yl)-α-D-glucofuranose (compound 2) was carried out. The synthesized compounds 1 and 2 were characterized by nuclear magnetic resonance (1H-NMR), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TG). The FTIR and 1H NMR spectra showed that the epoxy group in compound 2 was attached by means of a nucleophilic substitution reaction. The activation energies for thermal degradation of compounds 1 and 2 were calculated from their TG data by using the Kissinger-Akahira-Sunose (KAS) and Tang methods.http://dx.doi.org/10.1155/2014/737953 |
| spellingShingle | Selinay Y. Erişkin Fatma Ç. Telli Yeliz Yıldırım Yeşim Salman Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar Derivative Journal of Chemistry |
| title | Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar Derivative |
| title_full | Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar Derivative |
| title_fullStr | Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar Derivative |
| title_full_unstemmed | Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar Derivative |
| title_short | Synthesis, Characterization, and Thermokinetic Analysis of New Epoxy Sugar Derivative |
| title_sort | synthesis characterization and thermokinetic analysis of new epoxy sugar derivative |
| url | http://dx.doi.org/10.1155/2014/737953 |
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