Electrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis process
La-Mg alloys of different compositions were prepared by electrolysis of LaCl3-MgCl2-KCl melts. Different phases of La-Mg alloys were characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Energy dispersive spectrometry (EDS) and Inductively Coupled Plasma-Atomic Em...
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| Format: | Article |
| Language: | English |
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University of Belgrade, Technical Faculty, Bor
2014-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2014/1450-53391400013K.pdf |
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| author | Sahoo Kumar D. Singh H. Krishnamurthy N. |
| author_facet | Sahoo Kumar D. Singh H. Krishnamurthy N. |
| author_sort | Sahoo Kumar D. |
| collection | DOAJ |
| description | La-Mg alloys of different compositions were prepared by electrolysis of
LaCl3-MgCl2-KCl melts. Different phases of La-Mg alloys were characterized by
X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Energy
dispersive spectrometry (EDS) and Inductively Coupled Plasma-Atomic Emission
Spectroscopy (ICP-AES) analyses showed that chemical compositions of La-Mg
alloys were consistent with phase structures of XRD pattern, and magnesium
content in the alloy could be controlled by electrolysis parameters. The
effects of various process parameters such as concentration of magnesium
chloride in the bath, temperature of electrolysis and cathode current density
on the current efficiency have been investigated. A maximum current
efficiency of 85% and yield of 80% was obtained from the bath at 12.5A/cm2
current density at an operating temp 850°C. |
| format | Article |
| id | doaj-art-35eb985337694ed399cc237b6ffa5748 |
| institution | Kabale University |
| issn | 1450-5339 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | University of Belgrade, Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj-art-35eb985337694ed399cc237b6ffa57482025-02-02T20:05:26ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392014-01-0150210911410.2298/JMMB130214013K1450-53391400013KElectrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis processSahoo Kumar D.0Singh H.1Krishnamurthy N.2Rare Earths Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai, IndiaRare Earths Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai, IndiaFusion Reactor Materials Section, Bhabha Atomic Research Centre, Trombay, Mumbai, IndiaLa-Mg alloys of different compositions were prepared by electrolysis of LaCl3-MgCl2-KCl melts. Different phases of La-Mg alloys were characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Energy dispersive spectrometry (EDS) and Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) analyses showed that chemical compositions of La-Mg alloys were consistent with phase structures of XRD pattern, and magnesium content in the alloy could be controlled by electrolysis parameters. The effects of various process parameters such as concentration of magnesium chloride in the bath, temperature of electrolysis and cathode current density on the current efficiency have been investigated. A maximum current efficiency of 85% and yield of 80% was obtained from the bath at 12.5A/cm2 current density at an operating temp 850°C.http://www.doiserbia.nb.rs/img/doi/1450-5339/2014/1450-53391400013K.pdffused salt electrolysisLa-Mg alloys |
| spellingShingle | Sahoo Kumar D. Singh H. Krishnamurthy N. Electrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis process Journal of Mining and Metallurgy. Section B: Metallurgy fused salt electrolysis La-Mg alloys |
| title | Electrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis process |
| title_full | Electrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis process |
| title_fullStr | Electrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis process |
| title_full_unstemmed | Electrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis process |
| title_short | Electrochemical deposition of La-Mg alloys in LaCl3-MgCl2-KCl system with molten salt electrolysis process |
| title_sort | electrochemical deposition of la mg alloys in lacl3 mgcl2 kcl system with molten salt electrolysis process |
| topic | fused salt electrolysis La-Mg alloys |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2014/1450-53391400013K.pdf |
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