Di-tert-butyldiisothiocyanatotin(IV)
The title compound, [Sn(C4H9)2(NCS)2], which crystallizes with one and a half molecules in the asymmetric unit, represents a new structure type for intermolecular sulfur...tin interactions, which is characterized by an antiparallel (A) arrangement of the dipole moments of the individual molecules. I...
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| Language: | English |
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International Union of Crystallography
2025-01-01
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| Online Access: | https://journals.iucr.org/paper?S2414314624012446 |
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| author | Anne Kamrowski Hans Reuter |
| author_facet | Anne Kamrowski Hans Reuter |
| author_sort | Anne Kamrowski |
| collection | DOAJ |
| description | The title compound, [Sn(C4H9)2(NCS)2], which crystallizes with one and a half molecules in the asymmetric unit, represents a new structure type for intermolecular sulfur...tin interactions, which is characterized by an antiparallel (A) arrangement of the dipole moments of the individual molecules. In the resulting zigzag chains, the molecules are related to each other by mirror planes (m) and twofold rotation axes (2), both perpendicular to the propagation plane, while translation is realized via a glide plane in direction of the crystallographic c axis, a combination of symmetry elements unique in the structural chemistry of diorganotin(IV) dihalides and pseudohalides, R2SnX2 with X = Hal or NCS. Its characteristics are subsumed in the term Am2c for this kind of intermolecular association pattern. The tilting of the NSnN-planes in relation to the propagation plane is described in terms of spherical coordinates. |
| format | Article |
| id | doaj-art-3568ae0761834be69b1409ebad925017 |
| institution | Kabale University |
| issn | 2414-3146 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-3568ae0761834be69b1409ebad9250172025-02-06T07:26:56ZengInternational Union of CrystallographyIUCrData2414-31462025-01-01101x24124410.1107/S2414314624012446hb4502Di-tert-butyldiisothiocyanatotin(IV)Anne Kamrowski0Hans Reuter1Chemistry, Osnabrück University, Barabarstr. 7, 49069 Osnabrück, GermanyChemistry, Osnabrück University, Barabarstr. 7, 49069 Osnabrück, GermanyThe title compound, [Sn(C4H9)2(NCS)2], which crystallizes with one and a half molecules in the asymmetric unit, represents a new structure type for intermolecular sulfur...tin interactions, which is characterized by an antiparallel (A) arrangement of the dipole moments of the individual molecules. In the resulting zigzag chains, the molecules are related to each other by mirror planes (m) and twofold rotation axes (2), both perpendicular to the propagation plane, while translation is realized via a glide plane in direction of the crystallographic c axis, a combination of symmetry elements unique in the structural chemistry of diorganotin(IV) dihalides and pseudohalides, R2SnX2 with X = Hal or NCS. Its characteristics are subsumed in the term Am2c for this kind of intermolecular association pattern. The tilting of the NSnN-planes in relation to the propagation plane is described in terms of spherical coordinates.https://journals.iucr.org/paper?S2414314624012446crystal structureisothiocyanateintermolecular interactionsspherical coordinatestitling |
| spellingShingle | Anne Kamrowski Hans Reuter Di-tert-butyldiisothiocyanatotin(IV) IUCrData crystal structure isothiocyanate intermolecular interactions spherical coordinates titling |
| title | Di-tert-butyldiisothiocyanatotin(IV) |
| title_full | Di-tert-butyldiisothiocyanatotin(IV) |
| title_fullStr | Di-tert-butyldiisothiocyanatotin(IV) |
| title_full_unstemmed | Di-tert-butyldiisothiocyanatotin(IV) |
| title_short | Di-tert-butyldiisothiocyanatotin(IV) |
| title_sort | di tert butyldiisothiocyanatotin iv |
| topic | crystal structure isothiocyanate intermolecular interactions spherical coordinates titling |
| url | https://journals.iucr.org/paper?S2414314624012446 |
| work_keys_str_mv | AT annekamrowski ditertbutyldiisothiocyanatotiniv AT hansreuter ditertbutyldiisothiocyanatotiniv |