Electrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazole
Electrochemical behavior of an alloy AgCu50, pure copper, and pure silver, respectively, was investigated by measuring the open circuit potentials using anodic potentiodynamic polarization and potentiostatic method in 0.1 moldm-3 NaOH + 0.02 moldm-3 NaCl solution, without and with adding...
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| Format: | Article |
| Language: | English |
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University of Belgrade, Technical Faculty, Bor
2017-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700044G.pdf |
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| author | Grekulović V. Rajčić-Vujasinović M. Mitovski A. |
| author_facet | Grekulović V. Rajčić-Vujasinović M. Mitovski A. |
| author_sort | Grekulović V. |
| collection | DOAJ |
| description | Electrochemical behavior of an alloy AgCu50, pure copper, and pure silver,
respectively, was investigated by measuring the open circuit potentials using
anodic potentiodynamic polarization and potentiostatic method in 0.1 moldm-3
NaOH + 0.02 moldm-3 NaCl solution, without and with adding
2-mercaptobenzothiazole in various concentrations (0.00001 - 0.001 moldm-3).
Anodic polarization curves for AgCu50 alloy, showed four current peaks.
Potentiostatic curves showed that values of the stationary current densities
drop down with the increase of 2-mercaptobenzothiazole concentration in the
electrolyte. The electrode surface was analyzed by optical microscopy after
the potentiostatic oxidation. Micrographs confirmed that
2-mercaptobenzothiazole has got the inhibitory effect by forming the film of
CuMBT and AgMBT which protect the electrode surface from corrosion. [Project
of the Serbian Ministry of Education, Science and Technological Development,
Grant no. ON.172060] |
| format | Article |
| id | doaj-art-3507d6df15c945e3a639427748ad7b73 |
| institution | Kabale University |
| issn | 1450-5339 2217-7175 |
| language | English |
| publishDate | 2017-01-01 |
| publisher | University of Belgrade, Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj-art-3507d6df15c945e3a639427748ad7b732025-02-02T10:48:13ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752017-01-0153334935610.2298/JMMB170623044G1450-53391700044GElectrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazoleGrekulović V.0Rajčić-Vujasinović M.1Mitovski A.2Technical Faculty, BorTechnical Faculty, BorTechnical Faculty, BorElectrochemical behavior of an alloy AgCu50, pure copper, and pure silver, respectively, was investigated by measuring the open circuit potentials using anodic potentiodynamic polarization and potentiostatic method in 0.1 moldm-3 NaOH + 0.02 moldm-3 NaCl solution, without and with adding 2-mercaptobenzothiazole in various concentrations (0.00001 - 0.001 moldm-3). Anodic polarization curves for AgCu50 alloy, showed four current peaks. Potentiostatic curves showed that values of the stationary current densities drop down with the increase of 2-mercaptobenzothiazole concentration in the electrolyte. The electrode surface was analyzed by optical microscopy after the potentiostatic oxidation. Micrographs confirmed that 2-mercaptobenzothiazole has got the inhibitory effect by forming the film of CuMBT and AgMBT which protect the electrode surface from corrosion. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. ON.172060]http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700044G.pdfSilverCopperAlloy AgCu50Potentiodynamic polarization2-mercaptobenzothiazole |
| spellingShingle | Grekulović V. Rajčić-Vujasinović M. Mitovski A. Electrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazole Journal of Mining and Metallurgy. Section B: Metallurgy Silver Copper Alloy AgCu50 Potentiodynamic polarization 2-mercaptobenzothiazole |
| title | Electrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazole |
| title_full | Electrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazole |
| title_fullStr | Electrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazole |
| title_full_unstemmed | Electrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazole |
| title_short | Electrochemical behavior of AgCu50 in alkaline media in the presence of chlorides and 2-mercaptobenzothiazole |
| title_sort | electrochemical behavior of agcu50 in alkaline media in the presence of chlorides and 2 mercaptobenzothiazole |
| topic | Silver Copper Alloy AgCu50 Potentiodynamic polarization 2-mercaptobenzothiazole |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700044G.pdf |
| work_keys_str_mv | AT grekulovicv electrochemicalbehaviorofagcu50inalkalinemediainthepresenceofchloridesand2mercaptobenzothiazole AT rajcicvujasinovicm electrochemicalbehaviorofagcu50inalkalinemediainthepresenceofchloridesand2mercaptobenzothiazole AT mitovskia electrochemicalbehaviorofagcu50inalkalinemediainthepresenceofchloridesand2mercaptobenzothiazole |