Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization

Producing large-grained polycrystalline Si (poly-Si) film on glass substrates coated with conducting layers is essential for fabricating Si thin-film solar cells with high efficiency and low cost. We investigated how the choice of conducting underlayer affected the poly-Si layer formed on it by low-...

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Main Authors: Kaoru Toko, Mitsuki Nakata, Atsushi Okada, Masato Sasase, Noritaka Usami, Takashi Suemasu
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2015/790242
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author Kaoru Toko
Mitsuki Nakata
Atsushi Okada
Masato Sasase
Noritaka Usami
Takashi Suemasu
author_facet Kaoru Toko
Mitsuki Nakata
Atsushi Okada
Masato Sasase
Noritaka Usami
Takashi Suemasu
author_sort Kaoru Toko
collection DOAJ
description Producing large-grained polycrystalline Si (poly-Si) film on glass substrates coated with conducting layers is essential for fabricating Si thin-film solar cells with high efficiency and low cost. We investigated how the choice of conducting underlayer affected the poly-Si layer formed on it by low-temperature (500°C) Al-induced crystallization (AIC). The crystal orientation of the resulting poly-Si layer strongly depended on the underlayer material: (100) was preferred for Al-doped-ZnO (AZO) and indium-tin-oxide (ITO); (111) was preferred for TiN. This result suggests Si heterogeneously nucleated on the underlayer. The average grain size of the poly-Si layer reached nearly 20 µm for the AZO and ITO samples and no less than 60 µm for the TiN sample. Thus, properly electing the underlayer material is essential in AIC and allows large-grained Si films to be formed at low temperatures with a set crystal orientation. These highly oriented Si layers with large grains appear promising for use as seed layers for Si light-absorption layers as well as for advanced functional materials.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-33ceb1f2b5e04571b51e8ff43000d5c32025-02-03T05:59:21ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2015-01-01201510.1155/2015/790242790242Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced CrystallizationKaoru Toko0Mitsuki Nakata1Atsushi Okada2Masato Sasase3Noritaka Usami4Takashi Suemasu5Institute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanInstitute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanInstitute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanThe Wakasa Wan Energy Research Center, Tsuruga, Fukui 914-0192, JapanMaterials, Physics and Energy Engineering, Nagoya University, Aichi 464-8603, JapanInstitute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573, JapanProducing large-grained polycrystalline Si (poly-Si) film on glass substrates coated with conducting layers is essential for fabricating Si thin-film solar cells with high efficiency and low cost. We investigated how the choice of conducting underlayer affected the poly-Si layer formed on it by low-temperature (500°C) Al-induced crystallization (AIC). The crystal orientation of the resulting poly-Si layer strongly depended on the underlayer material: (100) was preferred for Al-doped-ZnO (AZO) and indium-tin-oxide (ITO); (111) was preferred for TiN. This result suggests Si heterogeneously nucleated on the underlayer. The average grain size of the poly-Si layer reached nearly 20 µm for the AZO and ITO samples and no less than 60 µm for the TiN sample. Thus, properly electing the underlayer material is essential in AIC and allows large-grained Si films to be formed at low temperatures with a set crystal orientation. These highly oriented Si layers with large grains appear promising for use as seed layers for Si light-absorption layers as well as for advanced functional materials.http://dx.doi.org/10.1155/2015/790242
spellingShingle Kaoru Toko
Mitsuki Nakata
Atsushi Okada
Masato Sasase
Noritaka Usami
Takashi Suemasu
Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization
International Journal of Photoenergy
title Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization
title_full Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization
title_fullStr Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization
title_full_unstemmed Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization
title_short Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization
title_sort influence of substrate on crystal orientation of large grained si thin films formed by metal induced crystallization
url http://dx.doi.org/10.1155/2015/790242
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