Study on the Miscibility of Polypyrrole and Polyaniline Polymer Blends

We report on the miscibility and phase behaviour of polypyrrole-polyaniline (PPy/PANI) as a function of blend composition. The PPy/PANI blends were prepared by solution processing method, using dimethyl sulfoxide (DMSO) solvent. Characterization of the polymer blends was carried out based on the dat...

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Main Authors: Tekalign A. Tikish, Ashok Kumar, Jung Yong Kim
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/3890637
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author Tekalign A. Tikish
Ashok Kumar
Jung Yong Kim
author_facet Tekalign A. Tikish
Ashok Kumar
Jung Yong Kim
author_sort Tekalign A. Tikish
collection DOAJ
description We report on the miscibility and phase behaviour of polypyrrole-polyaniline (PPy/PANI) as a function of blend composition. The PPy/PANI blends were prepared by solution processing method, using dimethyl sulfoxide (DMSO) solvent. Characterization of the polymer blends was carried out based on the data analysis from Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and differential scanning calorimetry (DSC). The PPy/PANI system was successfully formed blends in DMSO solvent. The polymer blends showed almost amorphous nature in XRD spectra because of intermolecular interaction between PPy and PANI macromolecules, which was confirmed by FT-IR data. Specifically, the DSC result for the PPY : PANI = 50 : 50 wt.% blend showed only one glass transition temperature (Tg), which indicates that the two polymers are well miscible without undergoing any phase separation.
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spelling doaj-art-32dc61e9411f41a2b37d22cc156191b52025-02-03T06:13:36ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/38906373890637Study on the Miscibility of Polypyrrole and Polyaniline Polymer BlendsTekalign A. Tikish0Ashok Kumar1Jung Yong Kim2School of Materials Science and Engineering, Jimma Institute Technology, Jimma University, P.O. Box 378, Jimma, EthiopiaDepartment of Physics, Tezpur University, Napaam, Sonitpur, Assam 784028, IndiaSchool of Materials Science and Engineering, Jimma Institute Technology, Jimma University, P.O. Box 378, Jimma, EthiopiaWe report on the miscibility and phase behaviour of polypyrrole-polyaniline (PPy/PANI) as a function of blend composition. The PPy/PANI blends were prepared by solution processing method, using dimethyl sulfoxide (DMSO) solvent. Characterization of the polymer blends was carried out based on the data analysis from Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and differential scanning calorimetry (DSC). The PPy/PANI system was successfully formed blends in DMSO solvent. The polymer blends showed almost amorphous nature in XRD spectra because of intermolecular interaction between PPy and PANI macromolecules, which was confirmed by FT-IR data. Specifically, the DSC result for the PPY : PANI = 50 : 50 wt.% blend showed only one glass transition temperature (Tg), which indicates that the two polymers are well miscible without undergoing any phase separation.http://dx.doi.org/10.1155/2018/3890637
spellingShingle Tekalign A. Tikish
Ashok Kumar
Jung Yong Kim
Study on the Miscibility of Polypyrrole and Polyaniline Polymer Blends
Advances in Materials Science and Engineering
title Study on the Miscibility of Polypyrrole and Polyaniline Polymer Blends
title_full Study on the Miscibility of Polypyrrole and Polyaniline Polymer Blends
title_fullStr Study on the Miscibility of Polypyrrole and Polyaniline Polymer Blends
title_full_unstemmed Study on the Miscibility of Polypyrrole and Polyaniline Polymer Blends
title_short Study on the Miscibility of Polypyrrole and Polyaniline Polymer Blends
title_sort study on the miscibility of polypyrrole and polyaniline polymer blends
url http://dx.doi.org/10.1155/2018/3890637
work_keys_str_mv AT tekalignatikish studyonthemiscibilityofpolypyrroleandpolyanilinepolymerblends
AT ashokkumar studyonthemiscibilityofpolypyrroleandpolyanilinepolymerblends
AT jungyongkim studyonthemiscibilityofpolypyrroleandpolyanilinepolymerblends