Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline Solution

To study the swelling characteristics of bentonite eroded by alkaline solutions, swelling deformation (δs) tests on the bentonite subjected to immersion conditions of NaOH and KOH solutions were conducted. It is found that the δs of bentonite decreases with the increase in the concentration of alkal...

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Main Authors: Guosheng Xiang, Weimin Ye, Zhijie Hu, Lei Ge, Yinkang Zhou
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2022/9100822
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author Guosheng Xiang
Weimin Ye
Zhijie Hu
Lei Ge
Yinkang Zhou
author_facet Guosheng Xiang
Weimin Ye
Zhijie Hu
Lei Ge
Yinkang Zhou
author_sort Guosheng Xiang
collection DOAJ
description To study the swelling characteristics of bentonite eroded by alkaline solutions, swelling deformation (δs) tests on the bentonite subjected to immersion conditions of NaOH and KOH solutions were conducted. It is found that the δs of bentonite decreases with the increase in the concentration of alkaline solution. The swelling deformation δs of bentonite eroded by NaOH solution exceeds than that in the KOH solution for the same level of concentration. Moreover, by performing XRD tests, it is revealed that the reduced swelling performance of bentonite in alkaline solutions is mainly attributed to the dissolution of the swelling mineral, i.e., montmorillonite (Mt.). The higher the concentration of alkali solution, the stronger the dissolution of Mt., thus leading to more significant attenuation of the swelling properties. Besides, the K+ exhibits low hydration energies, which tends to fit into the silicon-oxygen tetrahedral cavity of smectite, forming a stronger K-linkage which leads to closely spaced crystal layers. The e-pe fractal relation can be calculated using the δs of bentonite eroded by alkaline solution. The e-pe fitting relation of the experimental data depicts that the dissolution of Mt. minerals in alkaline solution reduces the swelling coefficient κ, however, it increases the surface fractal dimension (Ds).
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series Advances in Civil Engineering
spelling doaj-art-324ddb6c492e4abbae550f8c8a36b46a2025-02-03T05:59:39ZengWileyAdvances in Civil Engineering1687-80942022-01-01202210.1155/2022/9100822Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline SolutionGuosheng Xiang0Weimin Ye1Zhijie Hu2Lei Ge3Yinkang Zhou4Department of Geotechnical EngineeringDepartment of Geotechnical EngineeringDepartment of Civil EngineeringDepartment of Civil EngineeringDepartment of Civil EngineeringTo study the swelling characteristics of bentonite eroded by alkaline solutions, swelling deformation (δs) tests on the bentonite subjected to immersion conditions of NaOH and KOH solutions were conducted. It is found that the δs of bentonite decreases with the increase in the concentration of alkaline solution. The swelling deformation δs of bentonite eroded by NaOH solution exceeds than that in the KOH solution for the same level of concentration. Moreover, by performing XRD tests, it is revealed that the reduced swelling performance of bentonite in alkaline solutions is mainly attributed to the dissolution of the swelling mineral, i.e., montmorillonite (Mt.). The higher the concentration of alkali solution, the stronger the dissolution of Mt., thus leading to more significant attenuation of the swelling properties. Besides, the K+ exhibits low hydration energies, which tends to fit into the silicon-oxygen tetrahedral cavity of smectite, forming a stronger K-linkage which leads to closely spaced crystal layers. The e-pe fractal relation can be calculated using the δs of bentonite eroded by alkaline solution. The e-pe fitting relation of the experimental data depicts that the dissolution of Mt. minerals in alkaline solution reduces the swelling coefficient κ, however, it increases the surface fractal dimension (Ds).http://dx.doi.org/10.1155/2022/9100822
spellingShingle Guosheng Xiang
Weimin Ye
Zhijie Hu
Lei Ge
Yinkang Zhou
Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline Solution
Advances in Civil Engineering
title Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline Solution
title_full Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline Solution
title_fullStr Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline Solution
title_full_unstemmed Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline Solution
title_short Swelling Characteristics of Fractal-Textured Bentonite Eroded by Alkaline Solution
title_sort swelling characteristics of fractal textured bentonite eroded by alkaline solution
url http://dx.doi.org/10.1155/2022/9100822
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