Effects of Surfactants on the Rate of Chemical Reactions
Surfactants are self-assembled compounds that depend on their structure and electric charge can interact as monomer or micelle with other compounds (substrates). These interactions which may catalyze or inhibit the reaction rates are studied with pseudophase, cooperativity, and stoichiometric (class...
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Format: | Article |
Language: | English |
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Wiley
2014-01-01
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Series: | Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2014/908476 |
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author | B. Samiey C.-H. Cheng J. Wu |
author_facet | B. Samiey C.-H. Cheng J. Wu |
author_sort | B. Samiey |
collection | DOAJ |
description | Surfactants are self-assembled compounds that depend on their structure and electric charge can interact as monomer or micelle with other compounds (substrates). These interactions which may catalyze or inhibit the reaction rates are studied with pseudophase, cooperativity, and stoichiometric (classical) models. In this review, we discuss applying these models to study surfactant-substrate interactions and their effects on Diels-Alder, redox, photochemical, decomposition, enzymatic, isomerization, ligand exchange, radical, and nucleophilic reactions. |
format | Article |
id | doaj-art-31429d42a0924a99b8c6b26ad21e57c5 |
institution | Kabale University |
issn | 2090-9063 2090-9071 |
language | English |
publishDate | 2014-01-01 |
publisher | Wiley |
record_format | Article |
series | Journal of Chemistry |
spelling | doaj-art-31429d42a0924a99b8c6b26ad21e57c52025-02-03T01:20:28ZengWileyJournal of Chemistry2090-90632090-90712014-01-01201410.1155/2014/908476908476Effects of Surfactants on the Rate of Chemical ReactionsB. Samiey0C.-H. Cheng1J. Wu2Department of Chemistry, Faculty of Science, Lorestan University, 68137-17133 Khoramabad, IranDepartment of Chemical Engineering, Ryerson University, Toronto, ON, M5B 2K3, CanadaDepartment of Chemical Engineering, Ryerson University, Toronto, ON, M5B 2K3, CanadaSurfactants are self-assembled compounds that depend on their structure and electric charge can interact as monomer or micelle with other compounds (substrates). These interactions which may catalyze or inhibit the reaction rates are studied with pseudophase, cooperativity, and stoichiometric (classical) models. In this review, we discuss applying these models to study surfactant-substrate interactions and their effects on Diels-Alder, redox, photochemical, decomposition, enzymatic, isomerization, ligand exchange, radical, and nucleophilic reactions.http://dx.doi.org/10.1155/2014/908476 |
spellingShingle | B. Samiey C.-H. Cheng J. Wu Effects of Surfactants on the Rate of Chemical Reactions Journal of Chemistry |
title | Effects of Surfactants on the Rate of Chemical Reactions |
title_full | Effects of Surfactants on the Rate of Chemical Reactions |
title_fullStr | Effects of Surfactants on the Rate of Chemical Reactions |
title_full_unstemmed | Effects of Surfactants on the Rate of Chemical Reactions |
title_short | Effects of Surfactants on the Rate of Chemical Reactions |
title_sort | effects of surfactants on the rate of chemical reactions |
url | http://dx.doi.org/10.1155/2014/908476 |
work_keys_str_mv | AT bsamiey effectsofsurfactantsontherateofchemicalreactions AT chcheng effectsofsurfactantsontherateofchemicalreactions AT jwu effectsofsurfactantsontherateofchemicalreactions |