ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes

ITO-free semitransparent organic solar cells (OSCs) based on MoO3/Ag anodes with poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester films as the active layer are investigated in this work. To obtain the optimal transparent (MoO3)/Ag anode, ITO-free reference OSCs are firstly fabri...

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Main Authors: Zhizhe Wang, Chunfu Zhang, Dazheng Chen, Shi Tang, Jincheng Zhang, Li Sun, Ting Heng, Yue Hao
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2014/209206
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author Zhizhe Wang
Chunfu Zhang
Dazheng Chen
Shi Tang
Jincheng Zhang
Li Sun
Ting Heng
Yue Hao
author_facet Zhizhe Wang
Chunfu Zhang
Dazheng Chen
Shi Tang
Jincheng Zhang
Li Sun
Ting Heng
Yue Hao
author_sort Zhizhe Wang
collection DOAJ
description ITO-free semitransparent organic solar cells (OSCs) based on MoO3/Ag anodes with poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester films as the active layer are investigated in this work. To obtain the optimal transparent (MoO3)/Ag anode, ITO-free reference OSCs are firstly fabricated. The power conversion efficiency (PCE) of 2.71% is obtained for OSCs based on the optimal MoO3 (2 nm)/Ag (9 nm) anode, comparable to that of ITO-based reference OSCs (PCE of 2.85%). Then based on MoO3 (2 nm)/Ag (9 nm) anode, ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes are investigated. It is observed from our results that OSCs with Ca (15 nm)/Ag (15 nm) cathode have the optimal transparency. Meanwhile, the PCE of 1.79% and 0.67% is obtained for illumination from the anode and cathode side, respectively, comparable to that of similar ITO-based semitransparent OSCs (PCE of 1.59% and 0.75% for illumination from the anode and cathode side, resp.) (Sol. Energy Mater. Sol. Cells, 95, pp. 877–880, 2011). The transparency and PCE of ITO-free semitransparent OSCs can be further improved by introducing a light couple layer. The developed method is compatible with various substrates, which is instructive for further research of ITO-free semitransparent OSCs.
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institution Kabale University
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language English
publishDate 2014-01-01
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series International Journal of Photoenergy
spelling doaj-art-30c8e5cb8f6d45459101bc4dcc8ea6372025-02-03T05:44:49ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2014-01-01201410.1155/2014/209206209206ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film ElectrodesZhizhe Wang0Chunfu Zhang1Dazheng Chen2Shi Tang3Jincheng Zhang4Li Sun5Ting Heng6Yue Hao7State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaState Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, School Of Microelectronics, Xidian University, 2 South Taibai Road, Xi’an 710071, ChinaITO-free semitransparent organic solar cells (OSCs) based on MoO3/Ag anodes with poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester films as the active layer are investigated in this work. To obtain the optimal transparent (MoO3)/Ag anode, ITO-free reference OSCs are firstly fabricated. The power conversion efficiency (PCE) of 2.71% is obtained for OSCs based on the optimal MoO3 (2 nm)/Ag (9 nm) anode, comparable to that of ITO-based reference OSCs (PCE of 2.85%). Then based on MoO3 (2 nm)/Ag (9 nm) anode, ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes are investigated. It is observed from our results that OSCs with Ca (15 nm)/Ag (15 nm) cathode have the optimal transparency. Meanwhile, the PCE of 1.79% and 0.67% is obtained for illumination from the anode and cathode side, respectively, comparable to that of similar ITO-based semitransparent OSCs (PCE of 1.59% and 0.75% for illumination from the anode and cathode side, resp.) (Sol. Energy Mater. Sol. Cells, 95, pp. 877–880, 2011). The transparency and PCE of ITO-free semitransparent OSCs can be further improved by introducing a light couple layer. The developed method is compatible with various substrates, which is instructive for further research of ITO-free semitransparent OSCs.http://dx.doi.org/10.1155/2014/209206
spellingShingle Zhizhe Wang
Chunfu Zhang
Dazheng Chen
Shi Tang
Jincheng Zhang
Li Sun
Ting Heng
Yue Hao
ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes
International Journal of Photoenergy
title ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes
title_full ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes
title_fullStr ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes
title_full_unstemmed ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes
title_short ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes
title_sort ito free semitransparent organic solar cells based on silver thin film electrodes
url http://dx.doi.org/10.1155/2014/209206
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