Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing

The reliability of GaN-based devices operating under high temperatures is crucial for their application in extreme environments. To identify the fundamental mechanisms behind high-temperature degradation, we investigated GaN-on-sapphire Schottky barrier diodes (SBDs) under simultaneous heating and e...

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Main Authors: Nahid Sultan Al-Mamun, Yuxin Du, Jianan Song, Rongming Chu, Aman Haque
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Micromachines
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Online Access:https://www.mdpi.com/2072-666X/16/3/242
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author Nahid Sultan Al-Mamun
Yuxin Du
Jianan Song
Rongming Chu
Aman Haque
author_facet Nahid Sultan Al-Mamun
Yuxin Du
Jianan Song
Rongming Chu
Aman Haque
author_sort Nahid Sultan Al-Mamun
collection DOAJ
description The reliability of GaN-based devices operating under high temperatures is crucial for their application in extreme environments. To identify the fundamental mechanisms behind high-temperature degradation, we investigated GaN-on-sapphire Schottky barrier diodes (SBDs) under simultaneous heating and electrical biasing. We observed the degradation mechanisms in situ inside a transmission electron microscope (TEM) using a custom-fabricated chip for simultaneous thermal and electrical control. The pristine device exhibited a high density of extended defects, primarily due to lattice mismatch and thermal expansion differences between the GaN and sapphire. TEM and STEM imaging, coupled with energy-dispersive X-ray spectroscopy (EDS), revealed the progressive degradation of the diode with increasing bias and temperature. At higher bias levels (4–5 V) and elevated temperatures (300–455 °C), the interdiffusion and alloying of the Au/Pd Schottky metal stack with GaN, along with defect generation near the interface, resulted in Schottky contact failure and catastrophic device degradation. A geometric phase analysis further identified strain localization and lattice distortions induced by thermal and electrical stresses, which facilitated diffusion pathways for rapid metal atom migration. These findings highlight that defect-mediated electrothermal degradation and interfacial chemical reactions are critical elements in the high-temperature failure physics of GaN Schottky diodes.
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spelling doaj-art-2f973a8cedd24f3db99c1b241bc633e32025-08-20T01:48:57ZengMDPI AGMicromachines2072-666X2025-02-0116324210.3390/mi16030242Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward BiasingNahid Sultan Al-Mamun0Yuxin Du1Jianan Song2Rongming Chu3Aman Haque4Department of Mechanical Engineering, Penn State University, University Park, PA 16802, USADepartment of Electrical Engineering, Penn State University, University Park, PA 16802, USADepartment of Electrical Engineering, Penn State University, University Park, PA 16802, USADepartment of Electrical Engineering, Penn State University, University Park, PA 16802, USADepartment of Mechanical Engineering, Penn State University, University Park, PA 16802, USAThe reliability of GaN-based devices operating under high temperatures is crucial for their application in extreme environments. To identify the fundamental mechanisms behind high-temperature degradation, we investigated GaN-on-sapphire Schottky barrier diodes (SBDs) under simultaneous heating and electrical biasing. We observed the degradation mechanisms in situ inside a transmission electron microscope (TEM) using a custom-fabricated chip for simultaneous thermal and electrical control. The pristine device exhibited a high density of extended defects, primarily due to lattice mismatch and thermal expansion differences between the GaN and sapphire. TEM and STEM imaging, coupled with energy-dispersive X-ray spectroscopy (EDS), revealed the progressive degradation of the diode with increasing bias and temperature. At higher bias levels (4–5 V) and elevated temperatures (300–455 °C), the interdiffusion and alloying of the Au/Pd Schottky metal stack with GaN, along with defect generation near the interface, resulted in Schottky contact failure and catastrophic device degradation. A geometric phase analysis further identified strain localization and lattice distortions induced by thermal and electrical stresses, which facilitated diffusion pathways for rapid metal atom migration. These findings highlight that defect-mediated electrothermal degradation and interfacial chemical reactions are critical elements in the high-temperature failure physics of GaN Schottky diodes.https://www.mdpi.com/2072-666X/16/3/242GaN Schottky diodein situ TEMhigh-temperature operation of GaNelectrothermal degradation of GaNreliability of GaN
spellingShingle Nahid Sultan Al-Mamun
Yuxin Du
Jianan Song
Rongming Chu
Aman Haque
Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing
Micromachines
GaN Schottky diode
in situ TEM
high-temperature operation of GaN
electrothermal degradation of GaN
reliability of GaN
title Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing
title_full Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing
title_fullStr Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing
title_full_unstemmed Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing
title_short Electrothermal Failure Physics of GaN Schottky Diodes Under High-Temperature Forward Biasing
title_sort electrothermal failure physics of gan schottky diodes under high temperature forward biasing
topic GaN Schottky diode
in situ TEM
high-temperature operation of GaN
electrothermal degradation of GaN
reliability of GaN
url https://www.mdpi.com/2072-666X/16/3/242
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AT jianansong electrothermalfailurephysicsofganschottkydiodesunderhightemperatureforwardbiasing
AT rongmingchu electrothermalfailurephysicsofganschottkydiodesunderhightemperatureforwardbiasing
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