Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian Federation

Elevated contents of hazardous elements in natural ecosystems are often associated with human activities. Significant quantities of these elements, including heavy metals, are concentrated in tailings. The goal of the study was to assess the mineralogical and geochemical features of the old tailings...

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Main Authors: Irina A. Tarasenko, Alexander V. Zin’kov, Aleksei S. Kholodov, Muhammad Riaz, Valeriy I. Petukhov, Nikita Y. Popov, Aristidis Tsatsakis, Kirill S. Golokhvast
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2020/6570126
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author Irina A. Tarasenko
Alexander V. Zin’kov
Aleksei S. Kholodov
Muhammad Riaz
Valeriy I. Petukhov
Nikita Y. Popov
Aristidis Tsatsakis
Kirill S. Golokhvast
author_facet Irina A. Tarasenko
Alexander V. Zin’kov
Aleksei S. Kholodov
Muhammad Riaz
Valeriy I. Petukhov
Nikita Y. Popov
Aristidis Tsatsakis
Kirill S. Golokhvast
author_sort Irina A. Tarasenko
collection DOAJ
description Elevated contents of hazardous elements in natural ecosystems are often associated with human activities. Significant quantities of these elements, including heavy metals, are concentrated in tailings. The goal of the study was to assess the mineralogical and geochemical features of the old tailings of the decommissioned Krasnorechenskaya concentrating mill (located in Primorsky Krai, Russian Federation), which was processing complex tin-polymetallic and silver-lead-zinc ores, the chemical features of tailings pond waters, and the extent of environmental impact on the nearby Rudnaya river. In addition to the analysis of rock and water samples, the software modeling of the water-rock-gas system was carried out. In the study area, the minerals and rocks undergo changes that lead to the formation of highly mineralized, acidic waters saturated with various elements. In the tailings ponds, the maximum permissible concentrations were exceeded for Zn, Cd, Cu, Mg, Fetotal, Pb, Mn, Al, As, Co, Be, Sr, Ni, and Ba. The drainage from the tailings pond tripled the total mineralization of the Rudnaya river relative to the background values. However, the intoxication of the ecosystem by tailing products is partially inhibited by the secondary minerals in the tailings ponds. The negative impact is of a local nature, and 500 m downstream the concentration of many of the above elements is reduced. Despite this, the system that forms the chemical composition of highly mineralized waters is far from the equilibrium state. The oxidation of sulfides, dissolution of other minerals, and migration of oxidation and hydrolysis products will continue affecting the environment. In this regard, it is necessary to conduct environmental monitoring and undertake activities aimed at the recovery of mature concentration tailings or at suppressing the activity of hazardous elements by the conservation of tailings ponds.
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spelling doaj-art-2f5252e7f05c433ebf83e603ceb32a7d2025-02-03T06:06:27ZengWileyJournal of Chemistry2090-90632090-90712020-01-01202010.1155/2020/65701266570126Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian FederationIrina A. Tarasenko0Alexander V. Zin’kov1Aleksei S. Kholodov2Muhammad Riaz3Valeriy I. Petukhov4Nikita Y. Popov5Aristidis Tsatsakis6Kirill S. Golokhvast7Far East Geological Institute of the Far Eastern Branch of the Russian Academy of Sciences, Vladivostok 690022, RussiaFar Eastern Federal University, Vladivostok 690950, RussiaFar East Geological Institute of the Far Eastern Branch of the Russian Academy of Sciences, Vladivostok 690022, RussiaDepartment of Environmental Sciences and Engineering, Government College University, Faisalabad 38000, PakistanFar Eastern Federal University, Vladivostok 690950, RussiaFar East Geological Institute of the Far Eastern Branch of the Russian Academy of Sciences, Vladivostok 690022, RussiaSchool of Medicine, University of Crete, Heraklion 71003, GreeceFar Eastern Federal University, Vladivostok 690950, RussiaElevated contents of hazardous elements in natural ecosystems are often associated with human activities. Significant quantities of these elements, including heavy metals, are concentrated in tailings. The goal of the study was to assess the mineralogical and geochemical features of the old tailings of the decommissioned Krasnorechenskaya concentrating mill (located in Primorsky Krai, Russian Federation), which was processing complex tin-polymetallic and silver-lead-zinc ores, the chemical features of tailings pond waters, and the extent of environmental impact on the nearby Rudnaya river. In addition to the analysis of rock and water samples, the software modeling of the water-rock-gas system was carried out. In the study area, the minerals and rocks undergo changes that lead to the formation of highly mineralized, acidic waters saturated with various elements. In the tailings ponds, the maximum permissible concentrations were exceeded for Zn, Cd, Cu, Mg, Fetotal, Pb, Mn, Al, As, Co, Be, Sr, Ni, and Ba. The drainage from the tailings pond tripled the total mineralization of the Rudnaya river relative to the background values. However, the intoxication of the ecosystem by tailing products is partially inhibited by the secondary minerals in the tailings ponds. The negative impact is of a local nature, and 500 m downstream the concentration of many of the above elements is reduced. Despite this, the system that forms the chemical composition of highly mineralized waters is far from the equilibrium state. The oxidation of sulfides, dissolution of other minerals, and migration of oxidation and hydrolysis products will continue affecting the environment. In this regard, it is necessary to conduct environmental monitoring and undertake activities aimed at the recovery of mature concentration tailings or at suppressing the activity of hazardous elements by the conservation of tailings ponds.http://dx.doi.org/10.1155/2020/6570126
spellingShingle Irina A. Tarasenko
Alexander V. Zin’kov
Aleksei S. Kholodov
Muhammad Riaz
Valeriy I. Petukhov
Nikita Y. Popov
Aristidis Tsatsakis
Kirill S. Golokhvast
Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian Federation
Journal of Chemistry
title Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian Federation
title_full Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian Federation
title_fullStr Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian Federation
title_full_unstemmed Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian Federation
title_short Concentrating Mill Wastes are the Source of Pollution of Human Environment and Natural Ecosystems with Heavy Metals: A Case Study in Primorsky Krai, Russian Federation
title_sort concentrating mill wastes are the source of pollution of human environment and natural ecosystems with heavy metals a case study in primorsky krai russian federation
url http://dx.doi.org/10.1155/2020/6570126
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