Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors

The performance of organic thin-film transistors (OTFTs) is often strongly dependent on the fabrication procedure. In this study, we fabricate OTFTs of soluble small-molecule organic semiconductors by spray-deposition and explore the effect of processing parameters on film morphology and device mobi...

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Main Authors: Jack W. Owen, Natalia A. Azarova, Marsha A. Loth, Markos Paradinas, Mariona Coll, Carmen Ocal, John E. Anthony, Oana D. Jurchescu
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2011/914510
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author Jack W. Owen
Natalia A. Azarova
Marsha A. Loth
Markos Paradinas
Mariona Coll
Carmen Ocal
John E. Anthony
Oana D. Jurchescu
author_facet Jack W. Owen
Natalia A. Azarova
Marsha A. Loth
Markos Paradinas
Mariona Coll
Carmen Ocal
John E. Anthony
Oana D. Jurchescu
author_sort Jack W. Owen
collection DOAJ
description The performance of organic thin-film transistors (OTFTs) is often strongly dependent on the fabrication procedure. In this study, we fabricate OTFTs of soluble small-molecule organic semiconductors by spray-deposition and explore the effect of processing parameters on film morphology and device mobility. In particular, we report on the effect of the nature of solvent, the pressure of the carrier gas used in deposition, and the spraying distance. We investigate the surface morphology using scanning force microscopy and show that the molecules pack along the π-stacking direction, which is the preferred charge transport direction. Our results demonstrate that we can tune the field-effect mobility of spray-deposited devices two orders of magnitude, from 10−3 cm2/Vs to 10−1 cm2/Vs, by controlling fabrication parameters.
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series Journal of Nanotechnology
spelling doaj-art-2efb0d8b89a7446cb7be19debab4920d2025-02-03T06:12:14ZengWileyJournal of Nanotechnology1687-95031687-95112011-01-01201110.1155/2011/914510914510Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film TransistorsJack W. Owen0Natalia A. Azarova1Marsha A. Loth2Markos Paradinas3Mariona Coll4Carmen Ocal5John E. Anthony6Oana D. Jurchescu7Department of Physics, Wake Forest University, Winston-Salem, NC 27109, USADepartment of Physics, Wake Forest University, Winston-Salem, NC 27109, USADepartment of Chemistry, University of Kentucky, Lexington, KY 40506, USAInstitut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193-Barcelona, SpainInstitut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193-Barcelona, SpainInstitut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193-Barcelona, SpainDepartment of Chemistry, University of Kentucky, Lexington, KY 40506, USADepartment of Physics, Wake Forest University, Winston-Salem, NC 27109, USAThe performance of organic thin-film transistors (OTFTs) is often strongly dependent on the fabrication procedure. In this study, we fabricate OTFTs of soluble small-molecule organic semiconductors by spray-deposition and explore the effect of processing parameters on film morphology and device mobility. In particular, we report on the effect of the nature of solvent, the pressure of the carrier gas used in deposition, and the spraying distance. We investigate the surface morphology using scanning force microscopy and show that the molecules pack along the π-stacking direction, which is the preferred charge transport direction. Our results demonstrate that we can tune the field-effect mobility of spray-deposited devices two orders of magnitude, from 10−3 cm2/Vs to 10−1 cm2/Vs, by controlling fabrication parameters.http://dx.doi.org/10.1155/2011/914510
spellingShingle Jack W. Owen
Natalia A. Azarova
Marsha A. Loth
Markos Paradinas
Mariona Coll
Carmen Ocal
John E. Anthony
Oana D. Jurchescu
Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors
Journal of Nanotechnology
title Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors
title_full Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors
title_fullStr Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors
title_full_unstemmed Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors
title_short Effect of Processing Parameters on Performance of Spray-Deposited Organic Thin-Film Transistors
title_sort effect of processing parameters on performance of spray deposited organic thin film transistors
url http://dx.doi.org/10.1155/2011/914510
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