Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal property

Terephthalate (TA) intercalated layered double hydroxides (LDHs) were synthesized using hydroxides as raw materials, and poly(ethylene terephthalate) (PET)/LDH nanocomposites with different contents of TA intercalated LDHs were prepared by in-situ polymerization. The structure, morphology and therma...

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Main Authors: Q. Jiao, W. Cui, Y. Zhao, H. Li, H. Liu, M. Zhou
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2012-06-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0003156&mi=cd
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author Q. Jiao
W. Cui
Y. Zhao
H. Li
H. Liu
M. Zhou
author_facet Q. Jiao
W. Cui
Y. Zhao
H. Li
H. Liu
M. Zhou
author_sort Q. Jiao
collection DOAJ
description Terephthalate (TA) intercalated layered double hydroxides (LDHs) were synthesized using hydroxides as raw materials, and poly(ethylene terephthalate) (PET)/LDH nanocomposites with different contents of TA intercalated LDHs were prepared by in-situ polymerization. The structure, morphology and thermal property of PET/LDH nanocomposites were investigated. The TA intercalated LDHs were partially exfoliated and well dispersed in PET matrix. The PET/LDH nanocomposites exhibit enhanced thermal stability relative to pure PET, confirmed by the thermogravimetric analysis results. The results of differential scanning calorimetry suggest that LDH nanoparticles could effectively promote the nucleation and crystallization of PET.
format Article
id doaj-art-2e033e15c4904608a707819ce85a2c92
institution DOAJ
issn 1788-618X
language English
publishDate 2012-06-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-2e033e15c4904608a707819ce85a2c922025-08-20T03:15:09ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2012-06-016648549310.3144/expresspolymlett.2012.51Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal propertyQ. JiaoW. CuiY. ZhaoH. LiH. LiuM. ZhouTerephthalate (TA) intercalated layered double hydroxides (LDHs) were synthesized using hydroxides as raw materials, and poly(ethylene terephthalate) (PET)/LDH nanocomposites with different contents of TA intercalated LDHs were prepared by in-situ polymerization. The structure, morphology and thermal property of PET/LDH nanocomposites were investigated. The TA intercalated LDHs were partially exfoliated and well dispersed in PET matrix. The PET/LDH nanocomposites exhibit enhanced thermal stability relative to pure PET, confirmed by the thermogravimetric analysis results. The results of differential scanning calorimetry suggest that LDH nanoparticles could effectively promote the nucleation and crystallization of PET.http://www.expresspolymlett.com/letolt.php?file=EPL-0003156&mi=cdNanocompositespoly(ethylene terephthalate)layered double hydroxidesin situ polymerization
spellingShingle Q. Jiao
W. Cui
Y. Zhao
H. Li
H. Liu
M. Zhou
Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal property
eXPRESS Polymer Letters
Nanocomposites
poly(ethylene terephthalate)
layered double hydroxides
in situ polymerization
title Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal property
title_full Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal property
title_fullStr Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal property
title_full_unstemmed Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal property
title_short Preparation of poly(ethylene terephthalate)/layered double hydroxide nanocomposites by in-situ polymerization and their thermal property
title_sort preparation of poly ethylene terephthalate layered double hydroxide nanocomposites by in situ polymerization and their thermal property
topic Nanocomposites
poly(ethylene terephthalate)
layered double hydroxides
in situ polymerization
url http://www.expresspolymlett.com/letolt.php?file=EPL-0003156&mi=cd
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AT wcui preparationofpolyethyleneterephthalatelayereddoublehydroxidenanocompositesbyinsitupolymerizationandtheirthermalproperty
AT yzhao preparationofpolyethyleneterephthalatelayereddoublehydroxidenanocompositesbyinsitupolymerizationandtheirthermalproperty
AT hli preparationofpolyethyleneterephthalatelayereddoublehydroxidenanocompositesbyinsitupolymerizationandtheirthermalproperty
AT hliu preparationofpolyethyleneterephthalatelayereddoublehydroxidenanocompositesbyinsitupolymerizationandtheirthermalproperty
AT mzhou preparationofpolyethyleneterephthalatelayereddoublehydroxidenanocompositesbyinsitupolymerizationandtheirthermalproperty