Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSX

This research investigates the optimum operating conditions related to the adsorption of nitrogen gas from ambient air on zeolite Li-LSX to produce oxygen gas by the pressure-vacuum swing adsorption process. Experiments were performed using a column (4 cm inside diameter and 17 cm length) packed wit...

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Main Authors: Marwa Al-Yousuf, Raghad F. Almilly, Riyadh Kamil
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2022/7254646
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author Marwa Al-Yousuf
Raghad F. Almilly
Riyadh Kamil
author_facet Marwa Al-Yousuf
Raghad F. Almilly
Riyadh Kamil
author_sort Marwa Al-Yousuf
collection DOAJ
description This research investigates the optimum operating conditions related to the adsorption of nitrogen gas from ambient air on zeolite Li-LSX to produce oxygen gas by the pressure-vacuum swing adsorption process. Experiments were performed using a column (4 cm inside diameter and 17 cm length) packed with different heights of packing (h) of zeolite (9, 12, and 16 cm) from 0.4 to 0.8 mm diameter pellets. At each packing height, different flow rates (f) (2, 4, 6, 8, and 10 L·min−1) for different input pressures (p) (0.5, 1, 1.5, 2, and 2.5 bar) were used to detect their effects on the purity of produced oxygen as percentage volume of the outlet air stream. The results showed that the purity of produced oxygen increased with increasing packing height, pressure, and flowrate to a specific limit. The maximum purity obtained was 73.15% at 16 cm packing height, 2.5 bar input pressure, and 6 L·min−1 inlet flowrate, and the productivity was equal to 18 mmol·(Kg·s)−1 at these conditions. A response surface methodology was used to determine the most influential variables and their interactions. The results confirmed the strong effects of the input pressure, the packing height, and to a lesser extent, the flowrate. A quadratic model was predicted based on the experimental result and assessed statistically. The impacts of quadratic terms in the model were in the order: of p∗p>p∗h>p∗f. The model was applied to predict the operating conditions of 95% purity of oxygen.
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issn 1687-8078
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spelling doaj-art-2dd3acabf83144deb9c09270e3bbfd272025-02-03T01:20:01ZengWileyInternational Journal of Chemical Engineering1687-80782022-01-01202210.1155/2022/7254646Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSXMarwa Al-Yousuf0Raghad F. Almilly1Riyadh Kamil2Chemical Engineering DepartmentChemical Engineering DepartmentPetroleum and Petrochemical Research CenterThis research investigates the optimum operating conditions related to the adsorption of nitrogen gas from ambient air on zeolite Li-LSX to produce oxygen gas by the pressure-vacuum swing adsorption process. Experiments were performed using a column (4 cm inside diameter and 17 cm length) packed with different heights of packing (h) of zeolite (9, 12, and 16 cm) from 0.4 to 0.8 mm diameter pellets. At each packing height, different flow rates (f) (2, 4, 6, 8, and 10 L·min−1) for different input pressures (p) (0.5, 1, 1.5, 2, and 2.5 bar) were used to detect their effects on the purity of produced oxygen as percentage volume of the outlet air stream. The results showed that the purity of produced oxygen increased with increasing packing height, pressure, and flowrate to a specific limit. The maximum purity obtained was 73.15% at 16 cm packing height, 2.5 bar input pressure, and 6 L·min−1 inlet flowrate, and the productivity was equal to 18 mmol·(Kg·s)−1 at these conditions. A response surface methodology was used to determine the most influential variables and their interactions. The results confirmed the strong effects of the input pressure, the packing height, and to a lesser extent, the flowrate. A quadratic model was predicted based on the experimental result and assessed statistically. The impacts of quadratic terms in the model were in the order: of p∗p>p∗h>p∗f. The model was applied to predict the operating conditions of 95% purity of oxygen.http://dx.doi.org/10.1155/2022/7254646
spellingShingle Marwa Al-Yousuf
Raghad F. Almilly
Riyadh Kamil
Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSX
International Journal of Chemical Engineering
title Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSX
title_full Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSX
title_fullStr Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSX
title_full_unstemmed Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSX
title_short Methodological Approach for Optimizing Production of Oxygen by Adsorption of Nitrogen from Air using Zeolite Li-LSX
title_sort methodological approach for optimizing production of oxygen by adsorption of nitrogen from air using zeolite li lsx
url http://dx.doi.org/10.1155/2022/7254646
work_keys_str_mv AT marwaalyousuf methodologicalapproachforoptimizingproductionofoxygenbyadsorptionofnitrogenfromairusingzeolitelilsx
AT raghadfalmilly methodologicalapproachforoptimizingproductionofoxygenbyadsorptionofnitrogenfromairusingzeolitelilsx
AT riyadhkamil methodologicalapproachforoptimizingproductionofoxygenbyadsorptionofnitrogenfromairusingzeolitelilsx