Polyoxometallates as effective photocatalysts in water purification from pesticides
Polyoxometallates (POM), i.e., metal oxide clusters of mainly tungsten are effective homogeneous photocatalysts for the mineralization of organic pollutants. POM are, at least, as effective as the well studied TiO2. OH⋅radicals formed by the reaction of the photo-excited polyoxometallates with H2O,...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2004-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/S1110662X04000297 |
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| Summary: | Polyoxometallates (POM), i.e., metal oxide clusters of mainly tungsten are effective homogeneous
photocatalysts for the mineralization of organic pollutants. POM are, at least, as effective as the well studied
TiO2. OH⋅radicals formed by the reaction of the photo-excited polyoxometallates with H2O, appear to play a key role in the process. In this study, the photocatalytic activity of POM have been tested on some
diversified pesticides of interest such as lindane, bentazone and fenitrothion to determine the feasibility
of decontamination of aqueous solutions from these pollutants. The results show that aqueous solutions
containing the above pesticides, upon photolysis in the presence of polyoxotungstates undergo effective
degradation to CO2, H2O and the corresponding inorganic anions. The intermediates identified give rise to
complicated degradation mechanisms prior to mineralization. The characteristic reactions that take place
consist of hydroxylation, H-abstraction, dehalogenation, denitration, desulfurization, breaking of the C-C
bond etc. |
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| ISSN: | 1110-662X |