Stable Field Emissions from Zirconium Carbide Nanoneedle Electron Source

In this study, a single zirconium carbide (ZrC) nanoneedle structure oriented in the <100> direction was fabricated by a dual-beam focused ion beam (FIB-SEM) system, and its field emission characteristics and emission current stability were evaluated. Benefiting from controlled fabrication wit...

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Main Authors: Yimeng Wu, Jie Tang, Shuai Tang, You-Hu Chen, Ta-Wei Chiu, Masaki Takeguchi, Ayako Hashimoto, Lu-Chang Qin
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/15/2/93
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author Yimeng Wu
Jie Tang
Shuai Tang
You-Hu Chen
Ta-Wei Chiu
Masaki Takeguchi
Ayako Hashimoto
Lu-Chang Qin
author_facet Yimeng Wu
Jie Tang
Shuai Tang
You-Hu Chen
Ta-Wei Chiu
Masaki Takeguchi
Ayako Hashimoto
Lu-Chang Qin
author_sort Yimeng Wu
collection DOAJ
description In this study, a single zirconium carbide (ZrC) nanoneedle structure oriented in the <100> direction was fabricated by a dual-beam focused ion beam (FIB-SEM) system, and its field emission characteristics and emission current stability were evaluated. Benefiting from controlled fabrication with real-time observation, the ZrC nanoneedle has a smooth surface and a tip with a radius of curvature smaller than 20 nm and a length greater than 2 μm. Due to its low work function and well-controlled morphology, the ZrC nanoneedle emitter, positioned in a high-vacuum chamber, was able to generate a single and collimated electron beam with a current of 1.2 nA at a turn-on voltage of 210 V, and the current increased to 100 nA when the applied voltage reached 325 V. After the treatment of the nanoneedle tip, the field emission exhibited a stable emission for 150 min with a fluctuation of 1.4% and an emission current density as high as 1.4 × 10<sup>10</sup> A m<sup>−2</sup>. This work presents an efficient and controllable method for fabricating nanostructures, and this method is applicable to the transition metal compound ZrC as a field emission emitter, demonstrating its potential as an electron source for electron-beam devices.
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spelling doaj-art-2c047f0781f94deaa35b943c3a100a072025-01-24T13:44:06ZengMDPI AGNanomaterials2079-49912025-01-011529310.3390/nano15020093Stable Field Emissions from Zirconium Carbide Nanoneedle Electron SourceYimeng Wu0Jie Tang1Shuai Tang2You-Hu Chen3Ta-Wei Chiu4Masaki Takeguchi5Ayako Hashimoto6Lu-Chang Qin7Research Center for Energy and Environmental Materials, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki, JapanResearch Center for Energy and Environmental Materials, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki, JapanState Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology, Sun Yat-sen University, Guangzhou 510275, ChinaResearch Center for Energy and Environmental Materials, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki, JapanResearch Center for Energy and Environmental Materials, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki, JapanResearch Center for Energy and Environmental Materials, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki, JapanResearch Center for Energy and Environmental Materials, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki, JapanDepartment of Physics and Astronomy, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3255, USAIn this study, a single zirconium carbide (ZrC) nanoneedle structure oriented in the <100> direction was fabricated by a dual-beam focused ion beam (FIB-SEM) system, and its field emission characteristics and emission current stability were evaluated. Benefiting from controlled fabrication with real-time observation, the ZrC nanoneedle has a smooth surface and a tip with a radius of curvature smaller than 20 nm and a length greater than 2 μm. Due to its low work function and well-controlled morphology, the ZrC nanoneedle emitter, positioned in a high-vacuum chamber, was able to generate a single and collimated electron beam with a current of 1.2 nA at a turn-on voltage of 210 V, and the current increased to 100 nA when the applied voltage reached 325 V. After the treatment of the nanoneedle tip, the field emission exhibited a stable emission for 150 min with a fluctuation of 1.4% and an emission current density as high as 1.4 × 10<sup>10</sup> A m<sup>−2</sup>. This work presents an efficient and controllable method for fabricating nanostructures, and this method is applicable to the transition metal compound ZrC as a field emission emitter, demonstrating its potential as an electron source for electron-beam devices.https://www.mdpi.com/2079-4991/15/2/93zirconium carbidenanoneedleelectron sourcestable field emission
spellingShingle Yimeng Wu
Jie Tang
Shuai Tang
You-Hu Chen
Ta-Wei Chiu
Masaki Takeguchi
Ayako Hashimoto
Lu-Chang Qin
Stable Field Emissions from Zirconium Carbide Nanoneedle Electron Source
Nanomaterials
zirconium carbide
nanoneedle
electron source
stable field emission
title Stable Field Emissions from Zirconium Carbide Nanoneedle Electron Source
title_full Stable Field Emissions from Zirconium Carbide Nanoneedle Electron Source
title_fullStr Stable Field Emissions from Zirconium Carbide Nanoneedle Electron Source
title_full_unstemmed Stable Field Emissions from Zirconium Carbide Nanoneedle Electron Source
title_short Stable Field Emissions from Zirconium Carbide Nanoneedle Electron Source
title_sort stable field emissions from zirconium carbide nanoneedle electron source
topic zirconium carbide
nanoneedle
electron source
stable field emission
url https://www.mdpi.com/2079-4991/15/2/93
work_keys_str_mv AT yimengwu stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource
AT jietang stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource
AT shuaitang stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource
AT youhuchen stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource
AT taweichiu stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource
AT masakitakeguchi stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource
AT ayakohashimoto stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource
AT luchangqin stablefieldemissionsfromzirconiumcarbidenanoneedleelectronsource