Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton Process

We evaluated the use of Fenton reactions induced by solar radiation in the treatment of effluent from a factory of paints for buildings, after prior removal of the suspended solids. The increase of H2O2 concentration from 100 to 2500 mg L−1 for a [Fe2+] = 105 mg L−1 contributed to the reduction of D...

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Main Authors: Alam Gustavo Trovó, Oswaldo Gomes, Antonio Eduardo da Hora Machado
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2013/340347
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author Alam Gustavo Trovó
Oswaldo Gomes
Antonio Eduardo da Hora Machado
author_facet Alam Gustavo Trovó
Oswaldo Gomes
Antonio Eduardo da Hora Machado
author_sort Alam Gustavo Trovó
collection DOAJ
description We evaluated the use of Fenton reactions induced by solar radiation in the treatment of effluent from a factory of paints for buildings, after prior removal of the suspended solids. The increase of H2O2 concentration from 100 to 2500 mg L−1 for a [Fe2+] = 105 mg L−1 contributed to the reduction of DOC, COD, and toxicity. Our best results were achieved using 1600 mg L−1 H2O2, with 90% of DOC and COD removal and a complete removal of the toxicity with respect to Artemia salina. Additionally, through increasing Fe2+ concentration from 15 to 45 mg L−1, the DOC removal rate increased 11 times, remaining almost constant in the range above 45 until 105 mg L−1. Under our best experimental conditions, 80% of DOC removal was achieved after an accumulated dose of 130 kJ m−2 of UVA radiation (82±17 min of solar irradiation under an average UVA irradiance of 34.1±7.3 W m−2), while 40% of DOC removal was reached after 150 min under only thermal Fenton reactions. The results suggest the effectiveness of implementation of solar photo-Fenton process in the decontamination and detoxification of effluents from factories of paints for buildings.
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spelling doaj-art-2be8dd04a76842d89fd43ee91eedf68b2025-02-03T01:31:31ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2013-01-01201310.1155/2013/340347340347Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton ProcessAlam Gustavo Trovó0Oswaldo Gomes1Antonio Eduardo da Hora Machado2Instituto de Química, Universidade Federal de Uberlândia, 38400-902 Uberlândia, MG, BrazilInstituto de Química, Universidade Federal de Uberlândia, 38400-902 Uberlândia, MG, BrazilInstituto de Química, Universidade Federal de Uberlândia, 38400-902 Uberlândia, MG, BrazilWe evaluated the use of Fenton reactions induced by solar radiation in the treatment of effluent from a factory of paints for buildings, after prior removal of the suspended solids. The increase of H2O2 concentration from 100 to 2500 mg L−1 for a [Fe2+] = 105 mg L−1 contributed to the reduction of DOC, COD, and toxicity. Our best results were achieved using 1600 mg L−1 H2O2, with 90% of DOC and COD removal and a complete removal of the toxicity with respect to Artemia salina. Additionally, through increasing Fe2+ concentration from 15 to 45 mg L−1, the DOC removal rate increased 11 times, remaining almost constant in the range above 45 until 105 mg L−1. Under our best experimental conditions, 80% of DOC removal was achieved after an accumulated dose of 130 kJ m−2 of UVA radiation (82±17 min of solar irradiation under an average UVA irradiance of 34.1±7.3 W m−2), while 40% of DOC removal was reached after 150 min under only thermal Fenton reactions. The results suggest the effectiveness of implementation of solar photo-Fenton process in the decontamination and detoxification of effluents from factories of paints for buildings.http://dx.doi.org/10.1155/2013/340347
spellingShingle Alam Gustavo Trovó
Oswaldo Gomes
Antonio Eduardo da Hora Machado
Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton Process
International Journal of Photoenergy
title Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton Process
title_full Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton Process
title_fullStr Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton Process
title_full_unstemmed Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton Process
title_short Treatment of Effluent from a Factory of Paints Using Solar Photo-Fenton Process
title_sort treatment of effluent from a factory of paints using solar photo fenton process
url http://dx.doi.org/10.1155/2013/340347
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