Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl Bromides
Four air and moisture-stable palladium(II)-Schiff base complexes, N,N′-bis(α-methylsalicylidene)propane-1,3-diamine palladium(II) (2a), N,N′-bis(4-methyl-α-methylsalicylidene)propane-1,3-diamine palladium(II) (2b), N,N′-bis(3,5-di-tert-butylsalicylidene)propane-1,3-diamine palladium(II) (2c), and N,...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/632315 |
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| author | Siti Kamilah Che Soh Mustaffa Shamsuddin |
| author_facet | Siti Kamilah Che Soh Mustaffa Shamsuddin |
| author_sort | Siti Kamilah Che Soh |
| collection | DOAJ |
| description | Four air and moisture-stable palladium(II)-Schiff base complexes, N,N′-bis(α-methylsalicylidene)propane-1,3-diamine palladium(II) (2a), N,N′-bis(4-methyl-α-methylsalicylidene)propane-1,3-diamine palladium(II) (2b), N,N′-bis(3,5-di-tert-butylsalicylidene)propane-1,3-diamine palladium(II) (2c), and N,N′-bis(4-methoxy-salicylidene)propane-1,3-diamine palladium(II) (2d), have been successfully synthesised and characterised by CHN elemental analyses and conventional spectroscopic methods. These complexes were investigated as catalysts in the phosphine-free Mizoroki-Heck cross-coupling reactions of aryl bromides with methyl acrylate. |
| format | Article |
| id | doaj-art-29d7c91f56cd423fab33ac36c0e4ff84 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-29d7c91f56cd423fab33ac36c0e4ff842025-02-03T01:00:04ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/632315632315Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl BromidesSiti Kamilah Che Soh0Mustaffa Shamsuddin1Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Johor, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Johor, MalaysiaFour air and moisture-stable palladium(II)-Schiff base complexes, N,N′-bis(α-methylsalicylidene)propane-1,3-diamine palladium(II) (2a), N,N′-bis(4-methyl-α-methylsalicylidene)propane-1,3-diamine palladium(II) (2b), N,N′-bis(3,5-di-tert-butylsalicylidene)propane-1,3-diamine palladium(II) (2c), and N,N′-bis(4-methoxy-salicylidene)propane-1,3-diamine palladium(II) (2d), have been successfully synthesised and characterised by CHN elemental analyses and conventional spectroscopic methods. These complexes were investigated as catalysts in the phosphine-free Mizoroki-Heck cross-coupling reactions of aryl bromides with methyl acrylate.http://dx.doi.org/10.1155/2013/632315 |
| spellingShingle | Siti Kamilah Che Soh Mustaffa Shamsuddin Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl Bromides Journal of Chemistry |
| title | Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl Bromides |
| title_full | Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl Bromides |
| title_fullStr | Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl Bromides |
| title_full_unstemmed | Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl Bromides |
| title_short | Tetradentate N2O2 Chelated Palladium(II) Complexes: Synthesis, Characterization, and Catalytic Activity towards Mizoroki-Heck Reaction of Aryl Bromides |
| title_sort | tetradentate n2o2 chelated palladium ii complexes synthesis characterization and catalytic activity towards mizoroki heck reaction of aryl bromides |
| url | http://dx.doi.org/10.1155/2013/632315 |
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