Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone)
A series of metal complexes of Cu(II) and Ni(II) having the general composition [M(L)X2] with benzil bis(thiosemicarbazone) has been prepared and characterized by element chemical analysis, molar conductance, magnetic susceptibility measurements, and spectral (electronic, IR, EPR, mass) studies. The...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2007-01-01
|
| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2007/51483 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832558987407523840 |
|---|---|
| author | Sulekh Chandra Smriti Raizada Monika Tyagi Archana Gautam |
| author_facet | Sulekh Chandra Smriti Raizada Monika Tyagi Archana Gautam |
| author_sort | Sulekh Chandra |
| collection | DOAJ |
| description | A series of metal complexes of Cu(II) and Ni(II) having the general composition [M(L)X2]
with benzil bis(thiosemicarbazone) has been prepared and characterized by
element chemical analysis, molar conductance, magnetic susceptibility measurements,
and spectral (electronic, IR, EPR, mass) studies. The IR spectral data suggest the
involvement of sulphur and azomethane nitrogen in coordination to the central metal ion.
On the basis of spectral studies, an octahedral geometry has been assigned for Ni(II)
complexes but a tetragonal geometry for Cu(II) complexes. The free ligand and its
metal complexes have been tested in vitro against a number of microorganisms in order
to assess their antimicrobial properties. |
| format | Article |
| id | doaj-art-2913610516114de789ab52f1a2247f3a |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2007-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-2913610516114de789ab52f1a2247f3a2025-02-03T01:31:02ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2007-01-01200710.1155/2007/5148351483Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone)Sulekh Chandra0Smriti Raizada1Monika Tyagi2Archana Gautam3Department of Chemistry, Zakir Husain College, University of Delhi, Jawaharlal Nehru Marg, New Delhi 110002, IndiaDepartment of Chemistry, MMH College Ghaziabad, 201001, IndiaDepartment of Chemistry, Zakir Husain College, University of Delhi, Jawaharlal Nehru Marg, New Delhi 110002, IndiaDepartment of Chemistry, Zakir Husain College, University of Delhi, Jawaharlal Nehru Marg, New Delhi 110002, IndiaA series of metal complexes of Cu(II) and Ni(II) having the general composition [M(L)X2] with benzil bis(thiosemicarbazone) has been prepared and characterized by element chemical analysis, molar conductance, magnetic susceptibility measurements, and spectral (electronic, IR, EPR, mass) studies. The IR spectral data suggest the involvement of sulphur and azomethane nitrogen in coordination to the central metal ion. On the basis of spectral studies, an octahedral geometry has been assigned for Ni(II) complexes but a tetragonal geometry for Cu(II) complexes. The free ligand and its metal complexes have been tested in vitro against a number of microorganisms in order to assess their antimicrobial properties.http://dx.doi.org/10.1155/2007/51483 |
| spellingShingle | Sulekh Chandra Smriti Raizada Monika Tyagi Archana Gautam Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone) Bioinorganic Chemistry and Applications |
| title | Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone) |
| title_full | Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone) |
| title_fullStr | Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone) |
| title_full_unstemmed | Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone) |
| title_short | Synthesis, Spectroscopic, and Antimicrobial Studies on Bivalent Nickel and Copper Complexes of Bis(thiosemicrbazone) |
| title_sort | synthesis spectroscopic and antimicrobial studies on bivalent nickel and copper complexes of bis thiosemicrbazone |
| url | http://dx.doi.org/10.1155/2007/51483 |
| work_keys_str_mv | AT sulekhchandra synthesisspectroscopicandantimicrobialstudiesonbivalentnickelandcoppercomplexesofbisthiosemicrbazone AT smritiraizada synthesisspectroscopicandantimicrobialstudiesonbivalentnickelandcoppercomplexesofbisthiosemicrbazone AT monikatyagi synthesisspectroscopicandantimicrobialstudiesonbivalentnickelandcoppercomplexesofbisthiosemicrbazone AT archanagautam synthesisspectroscopicandantimicrobialstudiesonbivalentnickelandcoppercomplexesofbisthiosemicrbazone |