Thermal decomposition of zinc hexacyanometalates in various gas media
Prussian blue analogues with formulae Zn3[Co(CN)6]2·10H2O and Zn3[Fe(CN)6]2·4H2O have been synthesized. Their thermal decomposition was studied in oxidizing (air), reducing (hydrogen) and inert (argon) atmospheres in the temperature range from 20 to 1000°C. TG-DSC curves were obtained and solid prod...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-06-01
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| Series: | Chemical Thermodynamics and Thermal Analysis |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2667312625000082 |
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| Summary: | Prussian blue analogues with formulae Zn3[Co(CN)6]2·10H2O and Zn3[Fe(CN)6]2·4H2O have been synthesized. Their thermal decomposition was studied in oxidizing (air), reducing (hydrogen) and inert (argon) atmospheres in the temperature range from 20 to 1000°C. TG-DSC curves were obtained and solid products of thermolysis were analyzed. It was found that metal-carbon compositions are formed in argon atmosphere, and the sizes of metal particles are 6-26 nm. This study allows us to consider thermolysis of complex compounds as a way to obtain new materials, which may be useful in the field of materials science. |
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| ISSN: | 2667-3126 |